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Linear dependence of the degree of aggregation on the solvent aggregating power (SAgP)

Linear dependence of the degree of aggregation on the solvent aggregating power (SAgP)
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摘要 With k_8/k_(16), the ratio of the hydrolytic rate-constants of p-nitrophenyl octanoate (C8) to hexadecanoate (C16), as the indicator of the degree of aggregation, the linear dependence of the deg- ree of aggregation on solvent aggregating power (SAgP) has been established in five aquiorgano sol- vents, each within a certain range of volume fraction ( values) of the organic cosolvent. The mea- ning of this linearity has been discussed. With k_8/k_(16), the ratio of the hydrolytic rate-constants of p-nitrophenyl octanoate (C8) to hexadecanoate (C16), as the indicator of the degree of aggregation, the linear dependence of the deg- ree of aggregation on solvent aggregating power (SAgP) has been established in five aquiorgano sol- vents, each within a certain range of volume fraction ( values) of the organic cosolvent. The mea- ning of this linearity has been discussed.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1991年第5期453-457,共0页 中国化学(英文版)
基金 Project supported by the National Natural Science Foundation of China.
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