THE STEREO-, REGIO-, AND CHEMO-SELECTIVE CONVERSION OF DITERPENOIDS, Kamebakaurin TO Oriaonin 被引量：1

THE STEREO-, REGIO-, AND CHEMO-SELECTIVE CONVERSION OF DITERPENOIDS, Kamebakaurin TO Oriaonin

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摘要 In this paper, we report the first stereo-, regio-, and chemo-selective conversion of oridonin (1) from kamebakaurin (3). The overall yield in 7 steps is 9%. In this paper, we report the first stereo-, regio-, and chemo-selective conversion of oridonin (1) from kamebakaurin (3). The overall yield in 7 steps is 9%.

作者周维善程云行

机构地区 Shanghai Instiute of Organic Chemistry

出处《Science China Chemistry》 SCIE EI CAS 1992年第2期194-199,共6页 中国科学（化学英文版）

关键词 kamebakaurin ORIDONIN trimethylsilyltriflate silylenolyzation. kamebakaurin, oridonin, trimethylsilyltriflate, silylenolyzation.

分类号 O6 [理学—化学]

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1Wu, Haisheng,Yang, Jin,Wang, Lei.An Efficient and Practical Synthesis of Dibenzo[d,f][1,3]- dioxepines from 2,2＇-Dihydroxybiphenyl with Terminal Alkynes Catalyzed by Lewis Acid TiCl4[J].Chinese Journal of Chemistry,2011,29(6):1211-1215.
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THE STEREO-, REGIO-, AND CHEMO-SELECTIVE CONVERSION OF DITERPENOIDS, Kamebakaurin TO Oriaonin 被引量：1

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