Lipases catalyzed acetylation of meso-2,4-dimethyl-1,5-pentanediol and the synthesis of Prelog-Djerassi lactone
Lipases catalyzed acetylation of meso-2,4-dimethyl-1,5-pentanediol and the synthesis of Prelog-Djerassi lactone
摘要
Lipase catalyzed acetylation of 2 afforded 3 with the e.e. up to 98%. Utility of 3 was illustrated by the preparation of Prelog-Djerassi lactones 7a and 7b.
基金
Project supported by the National Natural Science Foundation of China.
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