摘要
Reaction of Cu powder with 2-thenoyltrifluoroacetone and 2, 2-bipygave a complex [Cu(C8H4SO2F3) (2, 2' -bipy)]. The title compound is monoclinic sys-tem, sapce grop C2/c, a= 17. 892(5), b= 18. 495(4), c= 16. 242(6) A, β=121. 02(2)°, Z=8, V=4606. 2 A3, Dc= 1. 512 g/cm3, μ= 12. 724 cm-1, F(000) = 1766,Mr = 440. 6, Final R = 0. 061 and R. = 0. 071. X-ray crystal structure analysis revealedthat copper(I) is coordinated by two O and two N atoms. The Cu(I) atom displays anearly square planar coordination geometry.
Reaction of Cu powder with 2-thenoyltrifluoroacetone and 2, 2-bipygave a complex [Cu(C8H4SO2F3) (2, 2' -bipy)]. The title compound is monoclinic sys-tem, sapce grop C2/c, a= 17. 892(5), b= 18. 495(4), c= 16. 242(6) A, β=121. 02(2)°, Z=8, V=4606. 2 A3, Dc= 1. 512 g/cm3, μ= 12. 724 cm-1, F(000) = 1766,Mr = 440. 6, Final R = 0. 061 and R. = 0. 071. X-ray crystal structure analysis revealedthat copper(I) is coordinated by two O and two N atoms. The Cu(I) atom displays anearly square planar coordination geometry.
