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Synthesis of Novel Tailed Porphyrins with Covalently Linked Saccharide

Synthesis of Novel Tailed Porphyrins with Covalently Linked Saccharide
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摘要 The reaction of 5-(p-hydroxyphenyl)-10, 15, 20- (p-methoxy phenyl) porphyrin with Br(CH2)4 Br produced monobromo substituted porphyrin 1. The tailed porphyrins 2–4 were synthesized by the reactions of 1 with small molecular offering biological activities such as D-glucose, D-glucuronic acid. These new compounds were confirmed by1H NMR, IR, UV-vis and element analyses. The reaction of 5-(p-hydroxyphenyl)-10, 15, 20- (p-methoxy phenyl) porphyrin with Br(CH2)4 Br produced monobromo substituted porphyrin 1. The tailed porphyrins 2–4 were synthesized by the reactions of 1 with small molecular offering biological activities such as D-glucose, D-glucuronic acid. These new compounds were confirmed by1H NMR, IR, UV-vis and element analyses.
出处 《Wuhan University Journal of Natural Sciences》 CAS 2002年第3期350-352,共3页 武汉大学学报(自然科学英文版)
基金 SupportedbytheNationalNaturalscienceFoundationofChina (2 9972 0 3 5 ) theZi QiangScienceFoundationofWuhanUniversity ,2 0 0 0
关键词 Key words carbohydrate substituted porphyrins SYNTHESIS CHARACTERIZATION Key words carbohydrate substituted porphyrins synthesis characterization
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