摘要
本文介绍了以二氧化碳和甲醇为原料合成碳酸二甲酯(DMC)催化剂的研究进展,着重从非均相催化体系和均相催化体系两方面阐述了负载型催化剂、有机与无机相结合的催化剂、金属及其相应化合物的催化剂、杂多酸催化剂、超临界二氧化碳条件下的酸性和碱性催化剂等多种催化剂体系在合成碳酸二甲酯上的应用。
The recent progress in the synthesis of dimethyl carbonate(DMC)with carbon dioxide and methanol as raw material was reviewed.The applications of the heterogeneous catalysts system and homogeneous catalysts system in the direct synthesis reaction of dimethyl carbonate is described,including laden catalyst,combination of organic and inorganic catalyst,metal and the corresponding compounds of catalysts,heteropoly acid catalyst,under the conditions of supercritical CO2acid and alkali catalyst.
关键词
二氧化碳
甲醇
碳酸二甲酯
催化剂
carbon dioxide
methanol
dimethyl carbonate
catalyst
