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OXIDATIVE POLYMERIZATION BEHAVIOR OF 2,6-DIMETHYLPHENOL IN AQUEOUS MEDIA WITH POTASSIUM FERRICYANIDE

OXIDATIVE POLYMERIZATION BEHAVIOR OF 2,6-DIMETHYLPHENOL IN AQUEOUS MEDIA WITH POTASSIUM FERRICYANIDE
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摘要 The effects of potassium ferricyanide,sodium n-dodecyl sulfate,sodium hydroxide and temperature on the molecular weight and the yield of poly(2,6-dimethyl-1,4-phenylene oxide)(PPO) synthesized in an aqueous medium were studied.It was found that oxygen in air had little influence on the oxidative polymerization of 2,6-dimethylphenol(DMP) in the aqueous medium,and potassium ferricyanide was only an oxidant during the oxidative polymerization of DMP.Sodium n-dodecyl sulfate could stabilize polymer particles an... The effects of potassium ferricyanide,sodium n-dodecyl sulfate,sodium hydroxide and temperature on the molecular weight and the yield of poly(2,6-dimethyl-1,4-phenylene oxide)(PPO) synthesized in an aqueous medium were studied.It was found that oxygen in air had little influence on the oxidative polymerization of 2,6-dimethylphenol(DMP) in the aqueous medium,and potassium ferricyanide was only an oxidant during the oxidative polymerization of DMP.Sodium n-dodecyl sulfate could stabilize polymer particles an...
作者 申屠宝卿
出处 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2009年第4期543-549,共7页 高分子科学(英文版)
基金 supported by the National Natural Science Foundation of China(No.20674075) Natural ScienceFoundation of Zhejiang Province(No.Y404299) Young Talents Project of Zhejiang Province(No.2008R40G2010065).
关键词 2 6-Dimethylphenol(DMP) Oxidative polymerization Poly(2 6-dimethyl-l 4-phenylene oxide)(PPO) Aqueous medium 2 6-Dimethylphenol(DMP) Oxidative polymerization Poly(2 6-dimethyl-l 4-phenylene oxide)(PPO) Aqueous medium
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