期刊文献+

二氧化硫与大气颗粒物的复相反应研究 被引量:5

Heterogeneous Reaction of Sulfur Dioxide with Atmospheric Particles
下载PDF
导出
摘要 利用原位FTIR,XPS等手段研究了SO2与大气颗粒物及部分氧化物的复相反应,确认了表面反应产物,讨论了复相反应历程和表面反应机理.结果表明,SO2在大气颗粒物和氧化物表面发生吸收和氧化反应,表面产物为SO32-和SO42-.表面酸碱性是不同氧化物对SO2吸收和氧化能力有较大差异的主要原因,本实验条件下氧化物和大气颗粒物样品复相反应能力顺序为:Al2O3>CaO>>SiO2,Fe2O3,大气颗粒物样品.
出处 《过程工程学报》 CAS CSCD 北大核心 2004年第z1期818-822,共5页 The Chinese Journal of Process Engineering
基金 国家自然科学基金(NO 20377008)和上海同济高廷耀环保科技发展基金会资助项目
  • 相关文献

参考文献15

  • 1[1]Charlson R. J. and Langner J. Climate Forcing by Anthropogenic Aerosols. Science, 1992, 255: 423-430. 被引量:1
  • 2[2]Kiehl J. T. and Briegleb B. P. The Relative Role of Sulfate Aerosols and Greenhouse Gases in Climate Forcing. Science, 1993,260:311-314. 被引量:1
  • 3[3]Charlson R. J., Schuartz S. E., Rodhe H. et al. Perturbation of the Northern Hemisphere Radiative Balance by Backscattering from Anthropogenic Sulfate Aerosols. Tellus, 1991, 43 AB: 152-163. 被引量:1
  • 4[4]Dentener F. J., Carmichael G. R., zhang Y. et al. Role of Mineral Aerosol as a Reactive Surface in the Global Troposphere J.Geophys. Res., 1996, 101: 22869-22889. 被引量:1
  • 5[6]Georgii H. W. and Warneck P. Global Aspects of Atmospheric Chemistry. Part 3. Chemistry of the Tropospheric Aerosol and of Clouds, Topics in Physical Chemistry. 1999, 6:111-179. 被引量:1
  • 6[7]Wang L., Zhang F. and Chen J. M. Carbonyl Sulfide Derived from Catalytic Oxidation of Carbon Disulfide over Atmospheric particles. Environ Sci. & Tech., 2001, 35(12): 2534-547. 被引量:1
  • 7[8]Wigley T. Possible Climate Change Due to SO2-Derived Cloud Condensation Nuclei. Nature, 1989, 339: 365-367. 被引量:1
  • 8[9]Chuang C. C. and Penner J. E. A Study of the Relationship between Anthropogenic Sulphate and Cloud Droplet Nucleation.AMS conf. on Cloud Physics, Dallas, 1995, 493-497. 被引量:1
  • 9[10]Martin L. R. and Good T. W. Catalyzed Oxidation of Sulfur Dioxide in Solution: The Iron-Manganese Synergism. Atmos.Environ., 1991, 25A: 2395-2399. 被引量:1
  • 10[11]Levin Z., Ganor, E. and Gladstein, V. The Effect of Desert Particles Coated with Sulfate on Rain Formation in the Eastern Mediterranean. J. Appl. Meteorol., 1996, 35:1511-1523. 被引量:1

同被引文献57

引证文献5

二级引证文献25

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部