摘要
Catalytic asymmetric synthesis of tertiary cyanohydrins by the addition of cyanide to a wide range of ketones has important synthetic utility, since the resulting optically active cyanohydrins are important intermediates for the synthesis of a variety of valuable classes of chiral compounds. The application of oxazoline in asymmetric cyanosilylation has seldom reported in comparation with other reactions.[1] Recently, polymer-supported pyridine-bis(oxazoline) ytterbium complex was reported to catalyze cyanosilylation of benzaldehyde.……
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2004年第z1期3-,共1页
Chinese Journal of Organic Chemistry
基金
Project supported by the National Natural Science Foundation of China (Nos. 20372001, 20172001).