摘要
本文介绍了用硫酸铁-硫酸作浸取剂,从闪锌矿制备七水硫酸锌的工艺过程。用铁屑作中和剂和还原剂除去浸取液中的酸和未反应的Fe ̄(3+),从溶液中结晶出大部分FeSO_4·7H_2O后,用“针铁矿”法除去剩余的Fe ̄(2+),用四氯乙烯作萃取剂回收渣中的硫。
Zinc sulfate heptahydrate was prepared by extraction of blende with ferricsulfate and sulfuric acid as extractant.First the excess acid and unreacted Fe ̄(3+)were trans-ferred to Fe ̄(2+) by iron finngs,then Fe ̄(2+)was removed by“goethite”method after most ofgreen vitriol was crystallized from the solution。For recovery of sulfur in the dregs ethylenetetrachloride was used as extractant.
出处
《河北大学学报(自然科学版)》
CAS
1994年第4期78-82,共5页
Journal of Hebei University(Natural Science Edition)
关键词
七水硫酸锌
制备
针铁矿
四氯乙烯
Zinc sulfate heptahydrate Preparation GoethiteEthylene tetrach lo ride