摘要
氟离子与人的生命活动密切相关,人体内氟离子含量过多或过少都会引起病变.因此,开发合适的手段检测人体内和环境中的氟离子含量是必要的.比色法和荧光检测法由于具有选择性高、灵敏度高以及响应快速的特点而备受关注.围绕反应型氟离子探针进行了综述,根据反应类型分为氟离子与有机硼化物结合型探针、氟离子诱导Si—C键断裂型探针、氟离子诱导Si—O键断裂型探针、氟离子诱导脱氢型探针和氟离子诱导P—O键断裂型探针5种.不仅对探针的检测方法进行了介绍,而且对于某些示例的作用机理也进行了阐述.
Fluoride ion is closely related to human life activities.Excessive or too little fluoride ions in human body will cause pathological changes.Therefore,it is necessary to develop appropriate measures to detect the fluoride ion content in human body and environment.Colorimetry and fluorescence detection have attracted much attention due to their high selectivity,high sensitivity and fast response.Herein,reaction-based fluoride ion probes are introduced.According to the reaction mechanisms,these probes can be divided into five types:interactions between fluoride ion and boronic acid derivatives,fluoride ion-promoted cleavage of Si—C bond,fluoride ion-promoted cleavage of Si—O bond,fluoride ion-induced dehydrogenation,fluoride ion-promoted cleavage of P—O bond.Not only the detection method of the probe is introduced,but also the action mechanism of some examples is described.
作者
曲衍杰
李亚军
鲍红丽
Qu Yanjie;Li Yajun;Bao Hongli(College of Chemistry and Material Science,Fujian Normal University,Fuzhou 350117;Key Laboratory of Coal to Ethylene Glycol and Its Related Technology,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2023年第3期809-825,共17页
Chinese Journal of Organic Chemistry
基金
国家杰出青年科学基金(No.22225107)
国家自然科学基金(Nos.21871258,21922112)资助项目
关键词
氟离子
比色和荧光检测法
反应型探针
生物成像
环境检测
fluoride ion
colorimetric and fluorescent detection
reaction-based probe
bio-imaging
environmental detection
