摘要
用3-硝基-1,2,4-三唑-5-酮(NTO)的锂盐水溶液和硫酸锰水溶液反应制得[Mn(H_2O)_6](NTO)_2·2H_2O,对它进行了元素分析与红外表征。[Mn(H-2O)_6](NTO)_2·2H_2O的结构用单晶分析法测定,其空间群为 C2/C,晶胞参数 a=23.423(3),b=6.5262(9),c=19.412(3),a=90.00(0)°,β=142.713(7)°,γ=90.00(0)°,V=1797.6(4)~3,Z=4,D_c=1.70 g·cm^(-3),μ=7.87cm^(-1),F(000)=947.75。
The salt of[Mn(H_O)_6](NTO)_2·2H_2O was prepared by mixing the ac- queous solution of lithium 3-nitro-1,2,4-triazol-5-onate and manganese(Ⅱ)sulfate.It was characterized by thermal analysis,elemental analysis and IR measurement.The crystal structure of[Mn(H_2O)_6](NTO)_2·2H_2O was determined by a single crystal diffraction analysis.The crystal belongs to space group C2/C with crystal parameters of α=23.423(3),b=6.5262(9),c=19.412(3),α=90.00(0)°,β=142.713(7)°,γ =90.00(0)°,V=1797.6(4),Z=4,D_c=1.70 g.cm^(-3),μ=7.87 cm^(-1),F(000)= 947.75。
出处
《含能材料》
EI
CAS
CSCD
1993年第1期37-42,共6页
Chinese Journal of Energetic Materials
