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Preparation and investigation of Pd doped Cu catalysts for selective hydrogenation of acetylene 被引量:5
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作者 Xinxiang Cao Tengteng Lyu +8 位作者 Wentao Xie Arash Mirjalili Adelaide Bradicich Ricky Huitema Ben W.-L.Jang Jong K.Keum Karren More Changjun Liu Xiaoliang Yan 《Frontiers of Chemical Science and Engineering》 SCIE EI CAS CSCD 2020年第4期522-533,共12页
A series of PdCu bimetallic catalysts with low Cu and Pd loadings and different Cu:Pd atomic ratios were prepared by conventionally sequential impregnation(CSD)and modified sequential impregnation(MSI)of Cu and Pd for... A series of PdCu bimetallic catalysts with low Cu and Pd loadings and different Cu:Pd atomic ratios were prepared by conventionally sequential impregnation(CSD)and modified sequential impregnation(MSI)of Cu and Pd for selective hydrogenation of acetylene.Characterization indicates that the supported copper(I)nitrate in the PdCu bimetallic catalysts prepared by MSI can be directly reduced to Cu metal particles due to the hydrogen spillover from Pd to Cu(NO3)2 crystals.In addition,for the catalysts prepared by MSI,Pd atoms can form PdCu alloy on the surface of metal particles,however,for the catalysts prepared by CSI,Pd tends to migrate and exist below the surface layer of Cu.Reaction results indicate that compared with CSI,the MSI method enables samples to possess preferable stability as well as comparable reaction activity.This should be due to the MSI method in favor of the formation of PdCu alloy on the surface of metal particles.Moreover,even Pd loading is super low,<0.045 wt-%in this study,by through adjusting Cu loading to an appropriate value,attractive reactivity and selectivity still can be achieved. 展开更多
关键词 COPPER PALLADIUM CATALYSTS ACETYLENE selec-tive hydrogenation
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核物质对称能的高密行为研究 被引量:6
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作者 雍高产 李宝安 陈列文 《原子核物理评论》 CAS CSCD 北大核心 2009年第2期85-92,共8页
同位旋物理的主要任务之一是通过放射性核束引起的核反应来探索介质中有效核子-核子相互作用的同位旋依赖性,尤其是同位旋相关的核物质状态方程,即,密度依赖的核物质对称能。由于对称能,尤其是其高密行为,对核物理学和天体物理学具有重... 同位旋物理的主要任务之一是通过放射性核束引起的核反应来探索介质中有效核子-核子相互作用的同位旋依赖性,尤其是同位旋相关的核物质状态方程,即,密度依赖的核物质对称能。由于对称能,尤其是其高密行为,对核物理学和天体物理学具有重要意义,密度依赖的对称能在过去10年一直是中能重离子物理研究领域的主要焦点之一。近年来,低密对称能的研究已经取得了重要进展,而对称能的高密行为仍然很不确定。在理论方面,人们提出了许多对高密对称能敏感的观测量。实验方面,关于对称能高密行为研究的实验计划已经展开,世界各地正在建造的放射性核束装置为对称能的高密行为研究提供了新的机遇。基于IBUU输运模型综述了研究对称能高密行为的一些敏感观测量及其最新进展,以及所面临的挑战与机遇。 展开更多
关键词 核物质 对称能 高密行为
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Astrophysical constraints on a parametric equation of state for neutron-rich nucleonic matter 被引量:5
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作者 Nai-Bo Zhang Bao-An Li 《Nuclear Science and Techniques》 SCIE CAS CSCD 2018年第12期62-70,共9页
Extracting the equation of state(EOS) and symmetry energy of dense neutron-rich matter from astrophysical observations is a long-standing goal of nuclear astrophysics. To facilitate the realization of this goal, the f... Extracting the equation of state(EOS) and symmetry energy of dense neutron-rich matter from astrophysical observations is a long-standing goal of nuclear astrophysics. To facilitate the realization of this goal, the feasibility of using an explicitly isospin-dependent parametric EOS for neutron star matter was investigated recently in [1–3]. In this contribution, in addition to outlining the model framework and summarizing the most important findings from [1–3], we report a few new results regarding constraining parameters characterizing the highdensity behavior of nuclear symmetry energy. In particular,the constraints on the pressure of neutron star matter extracted from combining the X-ray observations of the neutron star radius, the minimum–maximum mass M=2:01 M_⊙, and causality condition agree very well with those extracted from analyzing the tidal deformability data by the LIGO ? Virgo Collaborations. The limitations of using the radius and/or tidal deformability of neutron stars to constrain the high-density nuclear symmetry energy are discussed. 展开更多
关键词 中子星物质 天体物理学 方程 状态 核子 数据提取 调查结果 模型框架
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How tightly is the nuclear symmetry energy constrained by a unitary Fermi gas? 被引量:4
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作者 Nai-Bo Zhang Bao-Jun Cai +2 位作者 Bao-An Li William G.Newton Jun Xu 《Nuclear Science and Techniques》 SCIE CAS CSCD 2017年第12期248-254,共7页
We examine critically how tightly the density dependence of nuclear symmetry energy E_(sym)(q) is constrained by the universal equation of state of the unitary Fermi gas EUG(q) considering currently known uncertaintie... We examine critically how tightly the density dependence of nuclear symmetry energy E_(sym)(q) is constrained by the universal equation of state of the unitary Fermi gas EUG(q) considering currently known uncertainties of higher order parameters describing the density dependence of the equation of state of isospin asymmetric nuclear matter. We found that E_(UG)(q) does provide a useful lower boundary for the E_(sym)(q). However, it doesnot tightly constrain the correlation between the magnitude E_(sym)(q_0) and slope L unless the curvature K_(sym)of the symmetry energy at saturation density q_0 is more precisely known. The large uncertainty in the skewness parameters affects the E_(sym)(q_0) versus L correlation by the same almost as significantly as the uncertainty in K_(sym). 展开更多
关键词 SYMMETRY energy UNITARY gas EQUATION of state NUCLEAR MATTER
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Investigation of the preparation methodologies of Pd-Cu single atom alloy catalysts for selective hydrogenation of acetylene 被引量:4
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作者 Xinxiang Cao Arash Mirjalili +2 位作者 James Wheeler Wentao Xie Ben W.-L. Jang 《Frontiers of Chemical Science and Engineering》 SCIE EI CAS CSCD 2015年第4期442-449,共8页
Galvanic replacement, co-impregnation and sequential impregnation have been employed to prepare Pd-Cu bimetallic catalysts with less than 1 wt-% Cu and ca. 0.03 wt-% Pd for selective hydrogenation of acetylene in exce... Galvanic replacement, co-impregnation and sequential impregnation have been employed to prepare Pd-Cu bimetallic catalysts with less than 1 wt-% Cu and ca. 0.03 wt-% Pd for selective hydrogenation of acetylene in excess ethylene. High angle annular dark field-scanning transmission electron microscopy (HAADF-STEM) and H2 chemisorption results confirmed that Pd-Cu singleatom alloy structures were constructed in all three bimetallic catalysts. Catalytic tests indicated that when the conversion of acetylene was above 99%, the selectivity of ethylene of these three single atom alloy catalysts was still more than 73%. Furthermore, the single atom alloy catalyst prepared by sequential incipient wetness impregnation was found to have the best stability among the three procedures used. 展开更多
关键词 palladium-copper bimetallic catalyst singleatom alloy acetylene hydrogenation HAADF-STEM H2pulse chemisorption
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Nucleon Emission Number as a Probe of Isospin-Dependent N-N Cross Section in Photonuclear Reactions 被引量:2
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作者 郭文军 黄江伟 +2 位作者 雍高产 张霄吉 张傲 《Chinese Physics Letters》 SCIE CAS CSCD 2014年第10期42-45,共4页
Based on the modified isospin-dependent quantum molecular dynamics model, the number of emitted nucleons in a photonuclear reaction is studied with different symmetry potentials and different isospin-dependent nucleon... Based on the modified isospin-dependent quantum molecular dynamics model, the number of emitted nucleons in a photonuclear reaction is studied with different symmetry potentials and different isospin-dependent nucleonnucleon (N N) collision cross sections. It is found that the number of emitted nucleons is sensitive to the isospin-dependent nucleon-nucleon cross section when the photon's energy is higher than 150 MeV, while it is insensitive to symmetry potential. The number of emitted neutrons is more sensitive to N N collision cross sections than that of protons. It is realized that the number of emitted neutrons can be used as a sensitive probe to extract the information of the isospin-dependent N N cross section at high energy photonuclear reactions. 展开更多
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中能重离子碰撞中的自旋轨道耦合 被引量:2
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作者 徐骏 夏银 +1 位作者 李宝安 沈文庆 《核技术》 CAS CSCD 北大核心 2014年第10期65-69,共5页
核的自旋轨道相互作用对解释原子核的幻数和壳结构十分重要。然而,一直以来,它只在核结构领域被广泛研究,在核反应过程中的效应通常被忽略。本文总结了近期第一次在描述中能重离子碰撞的IBUU(Isospin-dependent Boltzmann-Uehling-Uhlen... 核的自旋轨道相互作用对解释原子核的幻数和壳结构十分重要。然而,一直以来,它只在核结构领域被广泛研究,在核反应过程中的效应通常被忽略。本文总结了近期第一次在描述中能重离子碰撞的IBUU(Isospin-dependent Boltzmann-Uehling-Uhlenbeck)输运模型中引入核子的自旋自由度和核自旋轨道相互作用所产生的自旋相关平均场势的研究工作。我们发现,可以利用横向自旋差分流来研究核自旋轨道耦合,中质子的自旋差分流之差可以用来研究自旋轨道耦合的同位旋依赖性,而不同束流能量下高横向动量的自旋差分流则可以用来提取自旋轨道耦合的密度依赖性。中能重离子碰撞在不久的将来有望成为研究核自旋轨道相互作用的另一条有效途径。 展开更多
关键词 重离子碰撞 自旋轨道耦合 IBUU输运模型
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Shear viscosity of nuclear matter 被引量:2
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作者 XU Jun 《Nuclear Science and Techniques》 SCIE CAS CSCD 2013年第5期71-75,共5页
This paper reports my recent study[1]on the shear viscosity of neutron-rich nuclear matter from a relaxation time approach.An isospin- and momentum-dependent interaction is used in the study.Dependence of density,temp... This paper reports my recent study[1]on the shear viscosity of neutron-rich nuclear matter from a relaxation time approach.An isospin- and momentum-dependent interaction is used in the study.Dependence of density,temperature,and isospin asymmetry of nuclear matter on its shear viscosity have been discussed.Similar to the symmetry energy,the symmetry shear viscosity is defined and its density and temperature dependence are studied. 展开更多
关键词 剪切粘度 核物质 不对称 弛豫时间 相互作用 同位旋 依赖性 丰中子
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Impact Parameter Dependence of the Double Neutron/Proton Ratio of Nucleon Emissions in Isotopic Reaction Systems 被引量:1
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作者 张勋超 李宝安 +1 位作者 陈列文 雍高产 《Chinese Physics Letters》 SCIE CAS CSCD 2009年第5期60-63,共4页
Within the transport model IBUU04, we investigate the double neutron/proton ratio of free nucleons taken from two reaction systems using two Sn isotopes at a beam energy of 50 MeV/nucleon and with impact parameters 2f... Within the transport model IBUU04, we investigate the double neutron/proton ratio of free nucleons taken from two reaction systems using two Sn isotopes at a beam energy of 50 MeV/nucleon and with impact parameters 2fm, 4fm and 8fm, respectively. It is found that the double neutron/proton ratio from peripheral collisions is more sensitive to the density dependence of the symmetry energy than those from mid-central and central collisions. 展开更多
关键词 gamma-ray bursts GAMMA-RAYS RELATIVITY
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Physical Activity in Pre-school Children:Role of the Teacher during Free Play
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作者 Dean Culpepper Lorraine Killion 《Journal of Sports Science》 2018年第3期144-148,共5页
It has become evident over the past decade that the lack of PA(physical activity)is a major concern for the population at large CDC(Center for Disease Control).This lack is a major reason for the increase in overweigh... It has become evident over the past decade that the lack of PA(physical activity)is a major concern for the population at large CDC(Center for Disease Control).This lack is a major reason for the increase in overweight and obese children(USDHHS,2014).The CDC and the American Heart Association recommend children need at least 60 minutes of play time that is not scheduled PA.The purpose of this research was to examine whether children’s PA will increase if teacher activity increases during unstructured free play time.Students’PA was determined by using the SOPLAY(system for observing play and leisure activity in youth-children).SOPLAY is a validated tool for directly observing PA and associated environmental characteristics in free play settings(e.g.,recess and lunch at school).SOPLAY provides objective data on the number of participants and their PA levels during play and leisure opportunities in targeted areas.Children and teachers in a West Texas Lab School(mean age=4.3 years)on a university campus were studied.Control group data(males=13,female=15)were analyzed and MVPA(moderate to vigorous physical activity)was calculated.Data showed that children spent only 30%of their free-time in the recommended intensity levels.Teachers’(n=5)overall metabolic equivalents(METs)were recorded at 1.13.The experimental group(males=11,female=13)recorded teachers’(n=6)METs at 2.47 and children MVPA at 44%.Both the MVPA and METs were significantly different(p<0.001).The value and importance of unstructured play time are important for children as well as the teachers.Children need time to be creative and explore during play and teachers use this free time for various activities including cognitive breaks or administrative work.A stronger push to get teachers moving should be made as this slight increase in METs produces a significant increase in children’s PA. 展开更多
关键词 PA free PLAY CHILDREN SCHOOL TEACHER
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核物质热力学性质的同位旋和动量相关性 被引量:1
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作者 徐骏 陈列文 +1 位作者 李宝安 马红孺 《原子核物理评论》 CAS CSCD 北大核心 2009年第2期93-101,共9页
利用3个具有不同的同位旋和动量相关性的热力学模型研究了非对称核物质的热力学性质,它们是重离子碰撞中同位旋弥散数据约束下的、同位旋和动量相关的MDI模型,完全动量无关的MID模型,以及同位旋标量动量相关的extended MDYI(eMDYI)模型... 利用3个具有不同的同位旋和动量相关性的热力学模型研究了非对称核物质的热力学性质,它们是重离子碰撞中同位旋弥散数据约束下的、同位旋和动量相关的MDI模型,完全动量无关的MID模型,以及同位旋标量动量相关的extended MDYI(eMDYI)模型。主要研究了同位旋非对称热核物质的对称能和系统力、化学不稳定性以及液气相变的温度效应。MDI模型对称能的温度效应来源于动能和势能两部分贡献,而MID和eMDYI模型只有势能部分对对称能的温度效应有贡献。研究结果还表明,力学不稳定性区域、化学不稳定性区域和液气共存区都依赖于模型的同位旋和动量相关性,以及对称能的密度依赖关系。 展开更多
关键词 同位旋 动量相关 对称能 不稳定性 液气相变
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Topology of nuclear reaction networks of interest for astrophysics 被引量:1
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作者 Carlos ABertulani 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2020年第11期10-11,共2页
Our understanding of the observed elemental abundance in the universe,stemming from nuclear reactions during the big bang or from nucleosynthesis within stellar environments,requires theoretical analyses based on mult... Our understanding of the observed elemental abundance in the universe,stemming from nuclear reactions during the big bang or from nucleosynthesis within stellar environments,requires theoretical analyses based on multidimensional nucleosynthesis calculations involving hundreds of nuclei connected via thousands of nuclear processes.Up to recently,full nucleosynthesis network calculations remained computationally expensive and prohibitive. 展开更多
关键词 NUCLEOSYNTHESIS UNIVERSE environments
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Probing the symmetry potential with neutron-proton bremsstrahlung in heavy-ion collisions
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作者 杨林孟 郭文军 +1 位作者 张云鹏 张霄吉 《Chinese Physics C》 SCIE CAS CSCD 2014年第7期59-62,共4页
In the framework of the isospin-dependent quantum molecular dynamics transport model (QMD), the effects of symmetry potential on the collision number and the neutron-proton bremsstrahlung photon in the reactions of ... In the framework of the isospin-dependent quantum molecular dynamics transport model (QMD), the effects of symmetry potential on the collision number and the neutron-proton bremsstrahlung photon in the reactions of 40Ca+40Ca, 124Sn+124Sn, 40Ca+64Zn, 40Ca+124Sn at different incident beam energies are studied. It is found that the collision number shows moderate sensitivity to the stiffness of the symmetry potential and the number of hard photons calculated with stiff symmetry potential is obviously smaller than that with soft symmetry potential. Thus, the neutron-proton bremsstrahlung photons produced in heavy-ion collisions may be a useful probe for the high-density behavior of the nuclear symmetry potential. 展开更多
关键词 symmetry potential neutron-proton bremsstrahlung heavy-ion collisions quantum molecular dynamics model
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Improving signature quality for network application identification
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作者 Justin Tharp Sang C·Suh +1 位作者 Hyeonkoo Cho Jinoh Kim 《Digital Communications and Networks》 SCIE 2019年第3期139-146,共8页
Network application identification is one of the core elements in network operations and management to provide enhanced network service and security. For accurate identification, an approach using common patterns call... Network application identification is one of the core elements in network operations and management to provide enhanced network service and security. For accurate identification, an approach using common patterns called "signatures" is widely used to compensate the limitations of the traditional transport-layer port-based classification. However, our simulation results indicate that using the signatures generated from a set of well known algorithms may lead to very poor identification performance, with less than 60% of true positives even in an optimal case. To improve the quality of signatures, we present a technique in this paper, which consists of two steps:(i) pairwise merging to consider every possible combination of the initially collected signatures to reduce their specificity that causes the signatures to be less common;and (ii) signature reduction to identify effective signatures with greater importance from a large set of signatures produced in the merging step, so as to manage the space/time complexity in the identification process for greater scalability. Our experimental results show that the proposed technique can dramatically improve the performance, even with a small number of signatures (e.g., 95% true positives rate with 30 signatures per application) which is more compact than the initial signature set. 展开更多
关键词 Network APPLICATION IDENTIFICATION APPLICATION signatures Pairwise MERGING SIGNATURE reduction EXPLICIT STRING patterns
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Long-Memory and Spurious Breaks in Ecological Experiments
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作者 Thomas R. Boucher 《Open Journal of Statistics》 2017年第5期768-779,共12页
The impact of long-memory on the Before-After-Control-Impact (BACI) design and a commonly used nonparametric alternative, Randomized Intervention Analysis (RIA), is examined. It is shown the corrections used based on ... The impact of long-memory on the Before-After-Control-Impact (BACI) design and a commonly used nonparametric alternative, Randomized Intervention Analysis (RIA), is examined. It is shown the corrections used based on short-memory processes are not adequate. Long-memory series are also known to exhibit spurious structural breaks that can be mistakenly attributed to an intervention. Two examples from the literature are used as illustrations. 展开更多
关键词 BACI LONG-MEMORY RIA Short-Memory Variance CORRECTIONS
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Isospin dependence of nucleon effective masses in neutron-rich matter
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作者 Bao-An Li Bao-Jun Cai +1 位作者 Lie-Wen Chen Xiao-Hua Li 《Nuclear Science and Techniques》 SCIE CAS CSCD 2016年第6期25-32,共8页
In this talk,we first briefly review the isospin dependence of the total nucleon effective mass M Jinferred from analyzing nucleon-nucleus scattering data within an isospin-dependent non-relativistic optical potential... In this talk,we first briefly review the isospin dependence of the total nucleon effective mass M Jinferred from analyzing nucleon-nucleus scattering data within an isospin-dependent non-relativistic optical potential model,and the isospin dependence of the nucleon E-mass M;E J obtained from applying the Migdal–Luttinger theorem to a phenomenological single-nucleon momentum distribution in nuclei constrained by recent electron-nucleus scatteringexperiments.Combining information about the isospin dependence of both the nucleon total effective mass and E-mass,we then infer the isospin dependence of nucleon k-mass using the well-known relation M_J~*=M_ J^(*1E).Implications of the results on the nucleon mean free path in neutron-rich matter are discussed. 展开更多
关键词 同位旋相关 有效质量 单核子 核物质 丰中子 平均自由程 非相对论 分析数据
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Biharmonic Maps from Tori into a 2-Sphere
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作者 Zeping WANG Ye-Lin OU Hanchun YANG 《Chinese Annals of Mathematics,Series B》 SCIE CSCD 2018年第5期861-878,共18页
Biharmonic maps are generalizations of harmonic maps. A well-known result on harmonic maps between surfaces shows that there exists no harmonic map from a torus into a sphere(whatever the metrics chosen) in the homoto... Biharmonic maps are generalizations of harmonic maps. A well-known result on harmonic maps between surfaces shows that there exists no harmonic map from a torus into a sphere(whatever the metrics chosen) in the homotopy class of maps of Brower degree±1. It would be interesting to know if there exists any biharmonic map in that homotopy class of maps. The authors obtain some classifications on biharmonic maps from a torus into a sphere, where the torus is provided with a flat or a class of non-flat metrics whilst the sphere is provided with the standard metric. The results in this paper show that there exists no proper biharmonic maps of degree±1 in a large family of maps from a torus into a sphere. 展开更多
关键词 Biharmonic maps Biharmonic tori Harmonic maps Gauss maps Mapsinto a sphere
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Isospin effect of the in-medium nucleon-nucleon cross section in excited nuclear reactions
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作者 张傲 郭文军 +1 位作者 黄江伟 杨林孟 《Chinese Physics C》 SCIE CAS CSCD 2014年第5期33-37,共5页
Using relativistic mean field theory, the neutron and the proton density distribution of 56Ni nuclei could be obtained in the ground state and the excited state. Based on the framework of the quantum molecular dynamic... Using relativistic mean field theory, the neutron and the proton density distribution of 56Ni nuclei could be obtained in the ground state and the excited state. Based on the framework of the quantum molecular dynamics model, the 56Ni nuclei have been simulated in ground state and in the neutron or proton excited state. We then used the three different states of 56Ni to collide with the 56Ni in the ground state. To discuss the evolution of the nuclear stopping in different reactions, two kinds of different excited nuclear reactions were studied at different reaction energies and at different impact parameters. Studies have shown that the nuclear stopping of an excited nuclear reaction is sensitive to the isospin-dependent in-medium nucleon-nucleon cross section, compared with the response value of the ground state nuclear reaction. So, it is better for the excited nuclei to extract the isospin dependence of nucleon-nucleon cross section information. 展开更多
关键词 quantum molecular dynamics excited state nuclear stopping isospin effect
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Tasting nuclear pasta made with classical molecuar dynamics simulations
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作者 Bao-An Li 《Frontiers of physics》 SCIE CSCD 2021年第2期115-117,共3页
Nuclear clusters or voids in the inner crust of neutron stars were predicted to have various shapes collectively nicknamed nuclear pasta.The recent review in Ref.[1]by Lopez,Dorso and Frank summarized their systematic... Nuclear clusters or voids in the inner crust of neutron stars were predicted to have various shapes collectively nicknamed nuclear pasta.The recent review in Ref.[1]by Lopez,Dorso and Frank summarized their systematic investigations into properties especially the mor-phological and thermodynamical phase transitions of the nuclear pasta within a Classical Molecular Dynamics model,providing further stimuli to find more observational evidences of the predicted nuclear pasta in neutron stars. 展开更多
关键词 COLLECTIVE summarized TRANSITIONS
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Turkey and the Kurdistan Regional Government:Unlikely Allies?
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作者 Ozum Yesiltas 《土耳其研究》 2018年第1期188-215,共28页
Turkey and the Kurdistan Regional Government (KRG) of Iraq built a strategic partnership since 2007 based on shared economic and political interests which included energy deals that bypassed Bagdad. Why does Turkey en... Turkey and the Kurdistan Regional Government (KRG) of Iraq built a strategic partnership since 2007 based on shared economic and political interests which included energy deals that bypassed Bagdad. Why does Turkey engage in economic cooperation with the KRG that facilitates Iraqi Kurds’secession from Iraq, when the Turkish preference is against an independent Kurdish state? The chapter focuses on three key factors to explain the enduring Ankara-Erbil relationship:mutual economic interests, containment of the Kurdistan Workers’Party, and regional power politics. The chapter also investigates the question'How will the recent Kurdish referendum for independence impact the strategic partnership between Turkey and the KRG?'Despite Ankara’s harsh reaction towards the referendum, the chapter argues that the recent crisis will not derail the Turkey-KRG ties. Rather, economic, realpolitik and geographical considerations will continue to push the two actors together in the foreseeable future. 展开更多
关键词 TURKEY KRG REFERENDUM PKK PARTNERSHIP
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