In this paper, a new triangular element （Quasi-Carey element） is constructed by the idea of Specht element. It is shown that this Quasi-Carey element possesses a very special property, i.e., the consistency error is...In this paper, a new triangular element （Quasi-Carey element） is constructed by the idea of Specht element. It is shown that this Quasi-Carey element possesses a very special property, i.e., the consistency error is of order O（h^2）, one order higher than its interpolation error when the exact solution belongs to H^3（Ω）. However, the interpolation error and consistency error of Carey element are of order O（h）. It seems that the above special property has never been seen for other triangular elements for the second order problems.展开更多
The genetic diversity of the 34 populations of wild rice Oryza meyeriana Baill. distributed in Yunnan Province, China was analyzed using 13 inter-simple sequence repeat （ISSR） markers. A total of 168 bands were ampl...The genetic diversity of the 34 populations of wild rice Oryza meyeriana Baill. distributed in Yunnan Province, China was analyzed using 13 inter-simple sequence repeat （ISSR） markers. A total of 168 bands were amplified, of which 135 polymorphic bands were discovered and the percentage of polymorphic bands （PPB） was 80.36%. A genetic diversity was revealed as Nei＇s gene diversity （H） = 0.2666 and Shannon information index （I） = 0.4028 at population level. The 34 populations were divided into different groups based on administrative regions, latitude and longitudes, river areas, altitudes of their origins, and their indexes such as Na （number of alleles）, Ne （effective number of alleles）, H, I and PPB were calculated. Richer genetic diversity was found in the wild rice populations distributed in Simao Prefecture than that in Lingcang Prefecture or Xishuangbanna Prefecture whereas the least genetic diversity was in Baoshan Prefecture or Dehong Prefecture. Rich genetic diversity was also discovered in the wild rice populations originated from higher than 710 m altitude around the middle and lower reaches of the Lancang River belonging to the Pacific Ocean drainage system. The 34 populations could be classified into two groups, one group covered the wild rice distributing in Simao Prefecture only while the other group covered ones in Lingcang, Xishuangbanna and Dehong Prefectures. The issue on how to effectively conserve the wild rice germplasm was discussed.展开更多
Due to their low cost,environmental friendliness and high energy density,the lithium-sulfur batteries(LSB)have been regarded as a promising alternative for the next generation of rechargeable battery systems.However,t...Due to their low cost,environmental friendliness and high energy density,the lithium-sulfur batteries(LSB)have been regarded as a promising alternative for the next generation of rechargeable battery systems.However,the practical application of LSB is seriously hampered by its short cycle life and high self-charge owing to the apparent shuttle effect of soluble lithium polysulfides.Using MgSO_(4)@MgO composite as both template and dopant,template-guided S-doped mesoporous graphene(SMG)is prepared via the fluidized-bed chemical vapor deposition method.As the polypropylene(PP)modifier,SMG with high specific surface area,abundant mesoporous structures and moderate S doping content offers a wealth of physical and chemical adsorptive sites and reduced interfacial contact resistance,thereby restraining the serious shuttle effects of lithium polysulfides.Consequently,the LSB configured with mesoporous graphene(MG)as S host material and SMG as a separator modifier exhibits an enhanced electrochemical performance with a high average capacity of 955.64 mA h g^(-1) at 1C and a small capacity decay rate of 0.109%per cycle.Additionally,the density functional theory(DFT)calculation models have been rationally constructed and demonstrated that the doped S atoms in SMG possess higher binding energy to lithium polysulfides than that in MG,indicating that the SMG/PP separator can effectively capture soluble lithium polysulfides via chemical binding forces.This work would provide valuable insight into developing a versatile carbon-based separator modifier for LSB.展开更多
Porous silica nano-flowers(KCC-1)immobilized Pt-Pd alloy NPs(Pt-Pd/KCC-1)with different mass ratios of Pd and Pt were successfully prepared by a facile in situ one-step reduction,using hydrazinium hydroxide as a reduc...Porous silica nano-flowers(KCC-1)immobilized Pt-Pd alloy NPs(Pt-Pd/KCC-1)with different mass ratios of Pd and Pt were successfully prepared by a facile in situ one-step reduction,using hydrazinium hydroxide as a reducing agent.The as-synthesized silica nanospheres possess radial fibers with a distance of 15 nm,exhibiting a high specific surface area(443.56 m^(2)·g^(-1)).Meanwhile,the obtained Pt-Pd alloy NPs are uniformly dispersed on the silica surface with a metallic particle size of 4-6 nm,which exist as metallic Pd and Pt on the surface of monodisperse KCC-1,showing the transfer of electrons from Pd to Pt.The as-synthesized 2.5%Pt-2.5%Pd/KCC-1 exhibited excellent catalytic activity and stability for the continuous dehydrogenation of 2-methoxycyclohexanol to prepare guaiacol.Compared with Pt or Pd single metal supported catalysts,the obtained 2.5%Pt-2.5%Pd/KCC-1 shows 97.2%conversion rate of 2-methoxycyclohexanol and 76.8%selectivity for guaiacol,which attributed to the significant synergistic effect of bimetallic Pt-Pd alloy NPs.Furthermore,turn over frequency value of the obtained 2.5%Pt-2.5%Pd/KCC-1 NPs achieved 4.36 s^(-1),showing higher catalytic efficiency than other two monometallic catalysts.Reaction pathways of dehydro-aromatization of 2-methoxycyclohexanol over the obtained catalyst are proposed.Consequently,the obtained 2.5%Pt-2.5%Pd/KCC-1 NPs prove their potential in the dehydrogenation of 2-methoxycyclohexanol,while the kinetics and mechanistic study of the dehydrogenation reaction over the catalyst in a continuous fixed-bed reactor may provide valuable information for the development of green,outstanding and powerful synthetic pathway of guaiacol.展开更多
With the continuous development of deep oil and gas,minerals,geothermal resources,and other resources,there are increasingly more stringent requirements for equipment.In particular,the ultra-highpressure dynamic seals...With the continuous development of deep oil and gas,minerals,geothermal resources,and other resources,there are increasingly more stringent requirements for equipment.In particular,the ultra-highpressure dynamic seals of deep mining device need to be developed.Therefore,considering the use of dynamic seals in unique deep mining environments,an ultra-high-pressure rotating combined dynamic seal was designed and developed and its sealing performance was experimentally measured and analyzed.The results show that the experimental device can operate stably under a pressure of up to150 MPa and a rotating speed of 76 r/min,and can also operate normally under a rotating speed of up to 140 r/min and a sealing pressure of 120 MPa.During the operation of the ultra-high-pressure rotating combined dynamic seal,the sealing ring does not show obvious damage,which vouches for its sealing performance.No leakage of flow and pressure was detected in the all seal structures within the sealing pressure range of 0-150 MPa.Therefore,the dynamic sealing performance of the device is intact under ultra-high-pressure conditions and can be applied in deep mining environments at a certain depth.The research and development of this device can aid future deep energy exploration and exploitation.展开更多
Deep petroleum resources are in a high-temperature environment.However,the traditional deep rock coring method has no temperature preserved measures and ignores the effect of temperature on rock porosity and permeabil...Deep petroleum resources are in a high-temperature environment.However,the traditional deep rock coring method has no temperature preserved measures and ignores the effect of temperature on rock porosity and permeability,which will lead to the distortion of the petroleum resources reserves assessment.Therefore,the hollow glass microspheres/epoxy resin(HGM/EP)composites were innovatively proposed as temperature preserved materials for in-situ temperature-preserved coring(ITP-Coring),and the physical,mechanical,and temperature preserved properties were evaluated.The results indicated that:As the HGM content increased,the density and mechanical properties of the composites gradually decreased,while the water absorption was deficient without hydrostatic pressure.For composites with 50 vol%HGM,when the hydrostatic pressure reached 60 MPa,the water absorption was above 30.19%,and the physical and mechanical properties of composites were weakened.When the hydrostatic pressure was lower than 40 MPa,the mechanical properties and thermal conductivity of composites were almost unchanged.Therefore,the composites with 50 vol%HGM can be used for ITPCoring operations in deep environments with the highest hydrostatic pressure of 40 MPa.Finally,to further understand the temperature preserved performance of composites in practical applications,the temperature preserved properties were measured.An unsteady-state heat transfer model was established based on the test results,then the theoretical change of the core temperature during the coring process was obtained.The above tests results can provide a research basis for deep rock in-situ temperature preserved corer and support accurate assessment of deep petroleum reserves.展开更多
In situ pressure-preserved coring(IPP-Coring)technology is considered one of the most efficient methods for assessing resources.However,seal failure caused by the rotation of pressure controllers greatly affects the s...In situ pressure-preserved coring(IPP-Coring)technology is considered one of the most efficient methods for assessing resources.However,seal failure caused by the rotation of pressure controllers greatly affects the success of pressure coring.In this paper,a novel spherical-cylindrical shell pressure controller was proposed.The finite element analysis model was used to analyze the stress distribution and deformation characteristics of the pressure controller at different rotation angles.The seal failure mechanism caused by the rotation of the pressure controller was discussed.The stress deviation rate was defined to quantitatively characterize the stress concentration.Based on the test equipment designed in this laboratory,the ultimate bearing strength of the pressure controller was tested.The results show that the rotation of the valve cover causes an increase in the deformation on its lower side.Furthermore,the specific sealing pressure in the weak zone is greatly reduced by a statistically significant amount,resulting in seal failure.When the valve cover rotates 5°around the major axis,the stress deviation rate is-92.6%.To prevent rotating failure of the pressure controller,it is necessary to control the rotation angle of the valve cover within 1°around the major axis.The results of this research can help engineers reduce failure-related accidents,provide countermeasures for pressure coring,and contribute to the exploration and evaluation of deep oil and gas resources.展开更多
The sealing performance of contact interfaces plays the most important role in the design and operation of the in-situ pressure-preserved coring system.To meet the demand of ultra-high pressure-retained coring for oil...The sealing performance of contact interfaces plays the most important role in the design and operation of the in-situ pressure-preserved coring system.To meet the demand of ultra-high pressure-retained coring for oil and gas exploration in deep reservoirs,a quantitative analysis of the contact mechanical behavior of the pressure controller was performed.Based on the micro-contact theory of rough surfaces,a three-dimensional numerical model of the rough contact interface between the valve cover and the valve seat was constructed,and the micro-contact behavior of the metal contact surfaces was comprehensively studied.The results show that the actual contact area of the valve interface increases with the increase of surface roughness before the critical contact point,but decreases after that.Compared with the real contact model with double rough surfaces,although the simplified hard-contact model with a single rough surface can reflect the micro-contact behavior of the rough surface to a certain extent,it cannot truly reveal the microchannel morphology between the sealing interfaces under pressure.Therefore,the realistic double-rough-surface model should be recommended to evaluate the sealing performance of coring tools,particularly for high pressure conditions.The material properties of valves have a significant effect on the contact characteristics of rough surfaces,which suggested that the actual contact area decreases with the increase of the elastic modulus of the contact material under the same loading conditions.The knowledge of this work could help to enhance the seal design of pressure controllers for in-situ pressure-preserved coring.展开更多
The influences of thermal stabilization of austenitic on the onset temperature for a martensite transformation in T91 ferritic heat-resistant steel were studied by high-resolution differential dilatometer. The phase t...The influences of thermal stabilization of austenitic on the onset temperature for a martensite transformation in T91 ferritic heat-resistant steel were studied by high-resolution differential dilatometer. The phase transformation kinetic information was obtained by adopting lever rule from the recorded dilatometric curves. The results show that an inverse stabilization, featured by the damage of ＂the atmosphere of carbon atoms＂ and the increase of the starting temperature for martensite transformation takes place when the T91 ferritic steel is isothermally treated above the Ms point, and it becomes strong with increasing the holding time. While the continued temperature for martensite transformation decreases gradually when isothermally holding at a temperature below Ms point. The observed inverse stabilization behavior could be attributed to the relatively high temperature of Ms point in the explored T91 ferritic heat-resistant steel.展开更多
A Roman dominating function on a graph G = （V, E） is a function f ： V→{0, 1, 2} satisfying the condition that every vertex u for which f（u） = 0 is adjacent to at least one vertex v for which f（v） = 2. The weig...A Roman dominating function on a graph G = （V, E） is a function f ： V→{0, 1, 2} satisfying the condition that every vertex u for which f（u） = 0 is adjacent to at least one vertex v for which f（v） = 2. The weight of a Roman dominating function is the value f（V） = Σu∈Vf（u）. The minimum weight of a Roman dominating function on a graph G, denoted by γR（G）, is called the Roman dominating number of G. In this paper, we will characterize a tree T with γR（T） = γ（T） ＋ 3.展开更多
This paper considers the scalar differential delay equation x（t） -μ x（t）-f（x（t-τ））, where f（x） is a decreasing continuous function. By proving that all solutions will beultimately in some interval, we give...This paper considers the scalar differential delay equation x（t） -μ x（t）-f（x（t-τ））, where f（x） is a decreasing continuous function. By proving that all solutions will beultimately in some interval, we give tile conditions under which the unique equilibrium pointof the differential delay equation is globally attractive.展开更多
Three polychlorinated biphenyls （PCBs） congeners and their corresponding haptens bearing four carbon length carboxylic groups that can be linked to a protein for raising antibodies were synthesized. The three result...Three polychlorinated biphenyls （PCBs） congeners and their corresponding haptens bearing four carbon length carboxylic groups that can be linked to a protein for raising antibodies were synthesized. The three resultant immunogens were fabricated and used to stimulate immune responses in rabbits to survey the characteristics of the haptens. Three of the resultant polyclonal antibodies （Pabs） were obtained. The antiserum exhibited relatively high antibody titres （1：32-64） in double agar diffusion.展开更多
Active attapulbgite as adsorptive reagent, the adsorptive behavior of Mn(II) and Zn(II) was studied with Flame atomic absorption spectroscopy (FAAS) method. The mainly factors of influencing the adsorption and desorpt...Active attapulbgite as adsorptive reagent, the adsorptive behavior of Mn(II) and Zn(II) was studied with Flame atomic absorption spectroscopy (FAAS) method. The mainly factors of influencing the adsorption and desorption of Mn(II) and Zn(II) were discussed. The interference of coexisting ions was investigated, and the actual sample determination from adzuki beans, mung beans and phosphating waste water was conducted with good result.展开更多
Dynamic tests of three bonded and two unbonded full-prestressed concrete beams were carried out.The purpose was to seek the relation between prestressing force and natural frequency.Test results indicate that the freq...Dynamic tests of three bonded and two unbonded full-prestressed concrete beams were carried out.The purpose was to seek the relation between prestressing force and natural frequency.Test results indicate that the frequency of prestressed concrete(PSC)beam increases with the increase in prestressing force approximately.The results are different from the dynamic characteristics of isotropic material beam subjected to compressive axial force which were put forward by Clough et al.The reason is that the beams were considered as isotropic,homogeneous,linear elastic material in the traditional analysis method.However,more accurate results are required in the analysis of frequency of PSC beam.The constitutive mode of PSC member is analyzed based on microstructure of concrete in this paper.The orthotropic linear elastic mode is used to analyze the relation between dynamic frequency and prestressing force of concrete beam,at the same time the equivalent stiffness of prestressed tendon relating to the prestressing force is added to the bending deformation stiffness of the beam.The analytical value agrees well with the test result,indicating that the current analysis method in this paper is feasible to full-prestressed concrete beam.展开更多
This paper presents a new size effect model for normal strength concrete subjected to uniaxial tension. The model is based on two extremes, sand cement paste in uniaxial tension and a sand-cement-paste/rock interface ...This paper presents a new size effect model for normal strength concrete subjected to uniaxial tension. The model is based on two extremes, sand cement paste in uniaxial tension and a sand-cement-paste/rock interface in uniaxial tension. Uniaxial tension tests with normal strength concrete measuring the tensile strength of normal strength concrete specimens with different geometrical shapes and different ratios of the aggregate size to the characteristic dimension of the concrete specimen show a significant size effect. The theoretical size effect law prediction agrees well with the experimental data.展开更多
High voltage pulse natural organic matter （NOM） toxic by-products. Fulvic acid discharge plasma can remove and produce no production of solution was treated by high voltage pulse discharge plasma in this paper. It w...High voltage pulse natural organic matter （NOM） toxic by-products. Fulvic acid discharge plasma can remove and produce no production of solution was treated by high voltage pulse discharge plasma in this paper. It was shown that： for the reason of thermolysis and oxidation, the pH and Oxidation Reduction Potential （ORP） of solution decreased gradually with the increase of peak voltage and fulvic acid solution concentration, meanwhile the temperature and turbidity of solution increased gradually. Adding hydrochlorid acid in the treatment could amplify the effect of plasma. When the concentration of NOM as the surrogate parameter, Ultraviolet Absorbancy Degree （UV254） increased slowly by the effect of plasma, while the degradation of Total Organic Carbon （TOC） was first-order reaction. The removal rate of TOC increased from 22.6% to 33.4% by high voltage pulse electrical field of 35 kv, and from 25.6% to 36.7% with the addition of hydrochlorid acid. This paper may provide some basis for the scale-up design of water treatment process by high voltage pulse discharge plasma with other technologies.展开更多
The polystyrene supported glutamic acid Schiff base complex of Mn （ Ⅱ ） （PS-Sal-Glue-Mn） was prepared with chloromethylated styrene polymer beads, 2,4-dihydroxybenzaldehyde, L-glutamic acid and manganese （ Ⅱ ）...The polystyrene supported glutamic acid Schiff base complex of Mn （ Ⅱ ） （PS-Sal-Glue-Mn） was prepared with chloromethylated styrene polymer beads, 2,4-dihydroxybenzaldehyde, L-glutamic acid and manganese （ Ⅱ ） acetate tetrahyrate. The polymeric ligand and the complex were characterized by FT-IR, small area X-ray photoelectron spectroscopy （XPS） and 1CP-AES. In the presence of the manganese complex, cyclohexene （1） was effectively oxidized by molecular oxygen without reductant. The major products of the reaction were 2-cyclohexen-l-ol （2）, 2-cyclohexen-l-one （3） and 2-cyclohexen-1- hydroperoxide （4）, which was different with typical oxidation of cyclohexene. The influence of reaction temperature and additive for oxidation had been studied. The selectivity of 2-cyclohexen-1-hydroperoxide varied with reaction time and different additives. The mechanism of cyclohexene oxidation had also been discussed.展开更多
Firstly, according to the regulation of growth and decay of radioactive nuclides produced in reactions, a formula used to calculate the total activation cross section of all possible reactions producing the same radio...Firstly, according to the regulation of growth and decay of radioactive nuclides produced in reactions, a formula used to calculate the total activation cross section of all possible reactions producing the same radioactive nuclide for the same element is deduced, and it is pointed out that the activation formula given in two references is incorrect. Then, as an example, the so-called total activation cross section in one of the two references is analyzed and the correct results of the cross sections of ^182W（n,p）^182（m＋g）Ta, ^183W（n,p）^183Ta and ^206Pb（n,α）^203Hg induced by neutrons around 14 MeV calculated with the data given in the literature, the nuclear parameters and some evaluated values are given. Finally, the correct results are compared with other values collected in the literature.展开更多
基金This research is supported by the National Natural Science Foundation of China under Grant No.10671184
文摘In this paper, a new triangular element （Quasi-Carey element） is constructed by the idea of Specht element. It is shown that this Quasi-Carey element possesses a very special property, i.e., the consistency error is of order O（h^2）, one order higher than its interpolation error when the exact solution belongs to H^3（Ω）. However, the interpolation error and consistency error of Carey element are of order O（h）. It seems that the above special property has never been seen for other triangular elements for the second order problems.
基金This work was supported by the National Natural Science Foundation of China(Grant No.30460065)Yunnan Provincial Foundation for Science.
文摘The genetic diversity of the 34 populations of wild rice Oryza meyeriana Baill. distributed in Yunnan Province, China was analyzed using 13 inter-simple sequence repeat （ISSR） markers. A total of 168 bands were amplified, of which 135 polymorphic bands were discovered and the percentage of polymorphic bands （PPB） was 80.36%. A genetic diversity was revealed as Nei＇s gene diversity （H） = 0.2666 and Shannon information index （I） = 0.4028 at population level. The 34 populations were divided into different groups based on administrative regions, latitude and longitudes, river areas, altitudes of their origins, and their indexes such as Na （number of alleles）, Ne （effective number of alleles）, H, I and PPB were calculated. Richer genetic diversity was found in the wild rice populations distributed in Simao Prefecture than that in Lingcang Prefecture or Xishuangbanna Prefecture whereas the least genetic diversity was in Baoshan Prefecture or Dehong Prefecture. Rich genetic diversity was also discovered in the wild rice populations originated from higher than 710 m altitude around the middle and lower reaches of the Lancang River belonging to the Pacific Ocean drainage system. The 34 populations could be classified into two groups, one group covered the wild rice distributing in Simao Prefecture only while the other group covered ones in Lingcang, Xishuangbanna and Dehong Prefectures. The issue on how to effectively conserve the wild rice germplasm was discussed.
基金supported by the Science Foundation of China University of Petroleum,Beijing(No.ZX20230047)Open Research Fund of State Key Laboratory of Coking Coal Exploitation and Comprehensive Utilization,China Pingmei Shenma Group(No.41040220201308).
文摘Due to their low cost,environmental friendliness and high energy density,the lithium-sulfur batteries(LSB)have been regarded as a promising alternative for the next generation of rechargeable battery systems.However,the practical application of LSB is seriously hampered by its short cycle life and high self-charge owing to the apparent shuttle effect of soluble lithium polysulfides.Using MgSO_(4)@MgO composite as both template and dopant,template-guided S-doped mesoporous graphene(SMG)is prepared via the fluidized-bed chemical vapor deposition method.As the polypropylene(PP)modifier,SMG with high specific surface area,abundant mesoporous structures and moderate S doping content offers a wealth of physical and chemical adsorptive sites and reduced interfacial contact resistance,thereby restraining the serious shuttle effects of lithium polysulfides.Consequently,the LSB configured with mesoporous graphene(MG)as S host material and SMG as a separator modifier exhibits an enhanced electrochemical performance with a high average capacity of 955.64 mA h g^(-1) at 1C and a small capacity decay rate of 0.109%per cycle.Additionally,the density functional theory(DFT)calculation models have been rationally constructed and demonstrated that the doped S atoms in SMG possess higher binding energy to lithium polysulfides than that in MG,indicating that the SMG/PP separator can effectively capture soluble lithium polysulfides via chemical binding forces.This work would provide valuable insight into developing a versatile carbon-based separator modifier for LSB.
基金supported by Natural Science Foundation of Henan Province of China(162300410253)the Open Research Fund of State Key Laboratory of Coking Coal Exploitation and Comprehensive Utilization,China Pingmei Shen-ma Group(41040220181107-8).
文摘Porous silica nano-flowers(KCC-1)immobilized Pt-Pd alloy NPs(Pt-Pd/KCC-1)with different mass ratios of Pd and Pt were successfully prepared by a facile in situ one-step reduction,using hydrazinium hydroxide as a reducing agent.The as-synthesized silica nanospheres possess radial fibers with a distance of 15 nm,exhibiting a high specific surface area(443.56 m^(2)·g^(-1)).Meanwhile,the obtained Pt-Pd alloy NPs are uniformly dispersed on the silica surface with a metallic particle size of 4-6 nm,which exist as metallic Pd and Pt on the surface of monodisperse KCC-1,showing the transfer of electrons from Pd to Pt.The as-synthesized 2.5%Pt-2.5%Pd/KCC-1 exhibited excellent catalytic activity and stability for the continuous dehydrogenation of 2-methoxycyclohexanol to prepare guaiacol.Compared with Pt or Pd single metal supported catalysts,the obtained 2.5%Pt-2.5%Pd/KCC-1 shows 97.2%conversion rate of 2-methoxycyclohexanol and 76.8%selectivity for guaiacol,which attributed to the significant synergistic effect of bimetallic Pt-Pd alloy NPs.Furthermore,turn over frequency value of the obtained 2.5%Pt-2.5%Pd/KCC-1 NPs achieved 4.36 s^(-1),showing higher catalytic efficiency than other two monometallic catalysts.Reaction pathways of dehydro-aromatization of 2-methoxycyclohexanol over the obtained catalyst are proposed.Consequently,the obtained 2.5%Pt-2.5%Pd/KCC-1 NPs prove their potential in the dehydrogenation of 2-methoxycyclohexanol,while the kinetics and mechanistic study of the dehydrogenation reaction over the catalyst in a continuous fixed-bed reactor may provide valuable information for the development of green,outstanding and powerful synthetic pathway of guaiacol.
基金supported by the Program for Guangdong Introducing Innovative and Enterpreneurial Teams(Grant No.2019ZT08G315)the National Natural Science Foundation of China(Grant No.51827901)
文摘With the continuous development of deep oil and gas,minerals,geothermal resources,and other resources,there are increasingly more stringent requirements for equipment.In particular,the ultra-highpressure dynamic seals of deep mining device need to be developed.Therefore,considering the use of dynamic seals in unique deep mining environments,an ultra-high-pressure rotating combined dynamic seal was designed and developed and its sealing performance was experimentally measured and analyzed.The results show that the experimental device can operate stably under a pressure of up to150 MPa and a rotating speed of 76 r/min,and can also operate normally under a rotating speed of up to 140 r/min and a sealing pressure of 120 MPa.During the operation of the ultra-high-pressure rotating combined dynamic seal,the sealing ring does not show obvious damage,which vouches for its sealing performance.No leakage of flow and pressure was detected in the all seal structures within the sealing pressure range of 0-150 MPa.Therefore,the dynamic sealing performance of the device is intact under ultra-high-pressure conditions and can be applied in deep mining environments at a certain depth.The research and development of this device can aid future deep energy exploration and exploitation.
基金National Natural Science Foundation of China(grant number 51827901)funded by the Program for Guangdong Introducing Innovative and Enterpreneurial Teams(No.2019ZT08G315)Shenzhen Basic Research Program(General Program)(No.JCYJ20190808153416970)
文摘Deep petroleum resources are in a high-temperature environment.However,the traditional deep rock coring method has no temperature preserved measures and ignores the effect of temperature on rock porosity and permeability,which will lead to the distortion of the petroleum resources reserves assessment.Therefore,the hollow glass microspheres/epoxy resin(HGM/EP)composites were innovatively proposed as temperature preserved materials for in-situ temperature-preserved coring(ITP-Coring),and the physical,mechanical,and temperature preserved properties were evaluated.The results indicated that:As the HGM content increased,the density and mechanical properties of the composites gradually decreased,while the water absorption was deficient without hydrostatic pressure.For composites with 50 vol%HGM,when the hydrostatic pressure reached 60 MPa,the water absorption was above 30.19%,and the physical and mechanical properties of composites were weakened.When the hydrostatic pressure was lower than 40 MPa,the mechanical properties and thermal conductivity of composites were almost unchanged.Therefore,the composites with 50 vol%HGM can be used for ITPCoring operations in deep environments with the highest hydrostatic pressure of 40 MPa.Finally,to further understand the temperature preserved performance of composites in practical applications,the temperature preserved properties were measured.An unsteady-state heat transfer model was established based on the test results,then the theoretical change of the core temperature during the coring process was obtained.The above tests results can provide a research basis for deep rock in-situ temperature preserved corer and support accurate assessment of deep petroleum reserves.
基金supported by the Program for Guangdong Introducing Innovative and Enterpreneurial Teams(No.2019ZT08G315)National Natural Science Foundation of China No.51827901 and U2013603
文摘In situ pressure-preserved coring(IPP-Coring)technology is considered one of the most efficient methods for assessing resources.However,seal failure caused by the rotation of pressure controllers greatly affects the success of pressure coring.In this paper,a novel spherical-cylindrical shell pressure controller was proposed.The finite element analysis model was used to analyze the stress distribution and deformation characteristics of the pressure controller at different rotation angles.The seal failure mechanism caused by the rotation of the pressure controller was discussed.The stress deviation rate was defined to quantitatively characterize the stress concentration.Based on the test equipment designed in this laboratory,the ultimate bearing strength of the pressure controller was tested.The results show that the rotation of the valve cover causes an increase in the deformation on its lower side.Furthermore,the specific sealing pressure in the weak zone is greatly reduced by a statistically significant amount,resulting in seal failure.When the valve cover rotates 5°around the major axis,the stress deviation rate is-92.6%.To prevent rotating failure of the pressure controller,it is necessary to control the rotation angle of the valve cover within 1°around the major axis.The results of this research can help engineers reduce failure-related accidents,provide countermeasures for pressure coring,and contribute to the exploration and evaluation of deep oil and gas resources.
基金supported by the Program for Guangdong Introducing Innovative and Entrepreneurial Teams(No.2019ZT08G315)Shenzhen Basic Research Program(General Program,No.JCYJ20190808153416970)National Natural Science Foundation of China No.51827901
文摘The sealing performance of contact interfaces plays the most important role in the design and operation of the in-situ pressure-preserved coring system.To meet the demand of ultra-high pressure-retained coring for oil and gas exploration in deep reservoirs,a quantitative analysis of the contact mechanical behavior of the pressure controller was performed.Based on the micro-contact theory of rough surfaces,a three-dimensional numerical model of the rough contact interface between the valve cover and the valve seat was constructed,and the micro-contact behavior of the metal contact surfaces was comprehensively studied.The results show that the actual contact area of the valve interface increases with the increase of surface roughness before the critical contact point,but decreases after that.Compared with the real contact model with double rough surfaces,although the simplified hard-contact model with a single rough surface can reflect the micro-contact behavior of the rough surface to a certain extent,it cannot truly reveal the microchannel morphology between the sealing interfaces under pressure.Therefore,the realistic double-rough-surface model should be recommended to evaluate the sealing performance of coring tools,particularly for high pressure conditions.The material properties of valves have a significant effect on the contact characteristics of rough surfaces,which suggested that the actual contact area decreases with the increase of the elastic modulus of the contact material under the same loading conditions.The knowledge of this work could help to enhance the seal design of pressure controllers for in-situ pressure-preserved coring.
基金the National Natural Science Foundation of China(No.50401003)the Foundation for the Author of National Excellent Doctoral Dissertation of China(FANEDD)of China(No.200335)+1 种基金the Natural Science Foundation of Tianjin City(No.033608811)the Fok Ying Tong Education Foundation,and the Program for New Century Excellent Talents in University for grant and financial support.
文摘The influences of thermal stabilization of austenitic on the onset temperature for a martensite transformation in T91 ferritic heat-resistant steel were studied by high-resolution differential dilatometer. The phase transformation kinetic information was obtained by adopting lever rule from the recorded dilatometric curves. The results show that an inverse stabilization, featured by the damage of ＂the atmosphere of carbon atoms＂ and the increase of the starting temperature for martensite transformation takes place when the T91 ferritic steel is isothermally treated above the Ms point, and it becomes strong with increasing the holding time. While the continued temperature for martensite transformation decreases gradually when isothermally holding at a temperature below Ms point. The observed inverse stabilization behavior could be attributed to the relatively high temperature of Ms point in the explored T91 ferritic heat-resistant steel.
基金Supported by the NSF of education Department of Henan Province(200510475038)
文摘A Roman dominating function on a graph G = （V, E） is a function f ： V→{0, 1, 2} satisfying the condition that every vertex u for which f（u） = 0 is adjacent to at least one vertex v for which f（v） = 2. The weight of a Roman dominating function is the value f（V） = Σu∈Vf（u）. The minimum weight of a Roman dominating function on a graph G, denoted by γR（G）, is called the Roman dominating number of G. In this paper, we will characterize a tree T with γR（T） = γ（T） ＋ 3.
文摘This paper considers the scalar differential delay equation x（t） -μ x（t）-f（x（t-τ））, where f（x） is a decreasing continuous function. By proving that all solutions will beultimately in some interval, we give tile conditions under which the unique equilibrium pointof the differential delay equation is globally attractive.
基金supported by the National Natural Science Foundation of China(No.20677008)The Research Fund for the Doctoral Program of Higher Education(20060255004)Shanghai Leading Academic Discipline Project(No.B604).
文摘Three polychlorinated biphenyls （PCBs） congeners and their corresponding haptens bearing four carbon length carboxylic groups that can be linked to a protein for raising antibodies were synthesized. The three resultant immunogens were fabricated and used to stimulate immune responses in rabbits to survey the characteristics of the haptens. Three of the resultant polyclonal antibodies （Pabs） were obtained. The antiserum exhibited relatively high antibody titres （1：32-64） in double agar diffusion.
基金Jiangsu University Scientific Research Funding (No. 04JDG017)
文摘Active attapulbgite as adsorptive reagent, the adsorptive behavior of Mn(II) and Zn(II) was studied with Flame atomic absorption spectroscopy (FAAS) method. The mainly factors of influencing the adsorption and desorption of Mn(II) and Zn(II) were discussed. The interference of coexisting ions was investigated, and the actual sample determination from adzuki beans, mung beans and phosphating waste water was conducted with good result.
基金Supported by National Natural Science Foundation of China(No.05378041/E0807)Postdoctoral Foundation of Huazhong Universityof Science and Technology.
文摘Dynamic tests of three bonded and two unbonded full-prestressed concrete beams were carried out.The purpose was to seek the relation between prestressing force and natural frequency.Test results indicate that the frequency of prestressed concrete(PSC)beam increases with the increase in prestressing force approximately.The results are different from the dynamic characteristics of isotropic material beam subjected to compressive axial force which were put forward by Clough et al.The reason is that the beams were considered as isotropic,homogeneous,linear elastic material in the traditional analysis method.However,more accurate results are required in the analysis of frequency of PSC beam.The constitutive mode of PSC member is analyzed based on microstructure of concrete in this paper.The orthotropic linear elastic mode is used to analyze the relation between dynamic frequency and prestressing force of concrete beam,at the same time the equivalent stiffness of prestressed tendon relating to the prestressing force is added to the bending deformation stiffness of the beam.The analytical value agrees well with the test result,indicating that the current analysis method in this paper is feasible to full-prestressed concrete beam.
文摘This paper presents a new size effect model for normal strength concrete subjected to uniaxial tension. The model is based on two extremes, sand cement paste in uniaxial tension and a sand-cement-paste/rock interface in uniaxial tension. Uniaxial tension tests with normal strength concrete measuring the tensile strength of normal strength concrete specimens with different geometrical shapes and different ratios of the aggregate size to the characteristic dimension of the concrete specimen show a significant size effect. The theoretical size effect law prediction agrees well with the experimental data.
文摘High voltage pulse natural organic matter （NOM） toxic by-products. Fulvic acid discharge plasma can remove and produce no production of solution was treated by high voltage pulse discharge plasma in this paper. It was shown that： for the reason of thermolysis and oxidation, the pH and Oxidation Reduction Potential （ORP） of solution decreased gradually with the increase of peak voltage and fulvic acid solution concentration, meanwhile the temperature and turbidity of solution increased gradually. Adding hydrochlorid acid in the treatment could amplify the effect of plasma. When the concentration of NOM as the surrogate parameter, Ultraviolet Absorbancy Degree （UV254） increased slowly by the effect of plasma, while the degradation of Total Organic Carbon （TOC） was first-order reaction. The removal rate of TOC increased from 22.6% to 33.4% by high voltage pulse electrical field of 35 kv, and from 25.6% to 36.7% with the addition of hydrochlorid acid. This paper may provide some basis for the scale-up design of water treatment process by high voltage pulse discharge plasma with other technologies.
文摘The polystyrene supported glutamic acid Schiff base complex of Mn （ Ⅱ ） （PS-Sal-Glue-Mn） was prepared with chloromethylated styrene polymer beads, 2,4-dihydroxybenzaldehyde, L-glutamic acid and manganese （ Ⅱ ） acetate tetrahyrate. The polymeric ligand and the complex were characterized by FT-IR, small area X-ray photoelectron spectroscopy （XPS） and 1CP-AES. In the presence of the manganese complex, cyclohexene （1） was effectively oxidized by molecular oxygen without reductant. The major products of the reaction were 2-cyclohexen-l-ol （2）, 2-cyclohexen-l-one （3） and 2-cyclohexen-1- hydroperoxide （4）, which was different with typical oxidation of cyclohexene. The influence of reaction temperature and additive for oxidation had been studied. The selectivity of 2-cyclohexen-1-hydroperoxide varied with reaction time and different additives. The mechanism of cyclohexene oxidation had also been discussed.
基金Supported by Program for Science & Technology Innovation Talents of Universities of Henan Province,China (HASTIT032)Research Program for Basic & Forefront Technology of Henan Province,China (092300410144,102300410043)Scientific Research Start up Outlay of High-Position Talent at Pingdingshan University in Henan Province,China
文摘Firstly, according to the regulation of growth and decay of radioactive nuclides produced in reactions, a formula used to calculate the total activation cross section of all possible reactions producing the same radioactive nuclide for the same element is deduced, and it is pointed out that the activation formula given in two references is incorrect. Then, as an example, the so-called total activation cross section in one of the two references is analyzed and the correct results of the cross sections of ^182W（n,p）^182（m＋g）Ta, ^183W（n,p）^183Ta and ^206Pb（n,α）^203Hg induced by neutrons around 14 MeV calculated with the data given in the literature, the nuclear parameters and some evaluated values are given. Finally, the correct results are compared with other values collected in the literature.
