Much attention has been paid to copper staves because they have excellentperformance and longevity. The hot test of copper staves was carried out using all-scale staveexperiment system and according to the results, th...Much attention has been paid to copper staves because they have excellentperformance and longevity. The hot test of copper staves was carried out using all-scale staveexperiment system and according to the results, the temperature distribution and heatcharacteristics were studied. The result shows that copper stave possesses outstanding heat transferability, a well-distributed temperature field and low temperature on the hot side. In addition, amodel was established to calculate the cooling water channels' inner face temperature. Thecalculation results indicates that the highest temperature of the inner wall of the channels is 42deg C, and at the same time, the cold side of the stave temperature is 42-43 deg C. That is to say,the temperature in the stave is quite uniform.展开更多
With the help of solidification kinetics, precipitation and growth of TiNhave been studied theoretically and the effect of cooling rate on the growth of TiN has beendiscussed. Through induction electric furnace experi...With the help of solidification kinetics, precipitation and growth of TiNhave been studied theoretically and the effect of cooling rate on the growth of TiN has beendiscussed. Through induction electric furnace experiment and electroslag remelting experiment withdifferent cooling rates, the distribution and particle size of TiN were investigated. It is provedthat the higher cooling rate is, the smaller the final size of TiN is and the more TiN particles canbe found in the steel. That TiN can restrain the growth of columnar crystal and enhance theproportion of equiaxed crystals to refine solidification structure as the heterogeneous nucleationsites of δ-ferrite is confirmed preliminarily. A new method to reduce macrosegregation incontinuous cast steel is provided.展开更多
The pure iron was melted and deoxidized by metallic Al and rare earth elements La, Ce and Y respectively at 1600℃ in a vertical resistance furnace. The morphology, chemical composition and size distribution of the in...The pure iron was melted and deoxidized by metallic Al and rare earth elements La, Ce and Y respectively at 1600℃ in a vertical resistance furnace. The morphology, chemical composition and size distribution of the inclusions in deoxidized liquid iron have been investigated by using of SEM and image-analysis techniques. The investigated results show that the deoxidation products in molten iron are complex inclusions of rare earth oxide or A12O3 combined with FeO finely distributed. The proper holding time and rapid cooling rate can make inclusions finer. La, Y and Al are more effective than Ce for obtaining finely distributed inclusions.展开更多
A geometric model for calculating the viscosity of multi-component melt fromrelated binary physicochemistry properties was derived based on Chou's thermodynamic geometricmodel. The model derived was employed to pr...A geometric model for calculating the viscosity of multi-component melt fromrelated binary physicochemistry properties was derived based on Chou's thermodynamic geometricmodel. The model derived was employed to predict the viscosity of Au-Ag-Cu alloys. The results showthat the calculated viscosity for Au-Ag-Cu alloys meet the experimental data very well. In addition,the viscosity of Bi-Sn-In systems was also predicted with this model.展开更多
A two-dimensional model was applied to simulate the liquid core reduction (LCR) technology of bloom CC using ANSYS software. The deformation characteristics of bloom under different liquid fraction and reducing amount...A two-dimensional model was applied to simulate the liquid core reduction (LCR) technology of bloom CC using ANSYS software. The deformation characteristics of bloom under different liquid fraction and reducing amount are obtained. The results indicate that the main deformation condition of bloom shell is compressive strain, mainly undertaken by the liquid core, which increases with the enhancement of reducing amount. Solidified shell takes minor deformation. The longitudinal section of bloom appears sunken and the narrow side bulges, which grow serious when the liquid fraction increases.展开更多
The hot ductility of the V-containing micro-alloying steel CC (continuouscasting) slabs and precipitation of vanadium carbide in the tensile specimens were investigated. Theresults indicate that the precipitation rati...The hot ductility of the V-containing micro-alloying steel CC (continuouscasting) slabs and precipitation of vanadium carbide in the tensile specimens were investigated. Theresults indicate that the precipitation ratio and precipitation rate of vanadium in the specimensreach maximum respectively at 900, -825 and 825 deg C. There is still l0 percent-l7 percent ofvanadium precipitated when the deformation temperature decreases to 800-700 deg C. Vanadium largelyaffects the ductility of the steel in the low ductility temperature Region III. Embrittlement ofsteel with higher V content is severer in the region and the embrittlement extends to lowertemperature.展开更多
Kinetics of carbothermic reduction of manganese oxide and the catalyticeffect of La_2O_3 on the reduction have been studied by the measurement of mass loss in N_2atmosphere at different temperatures and followed by SE...Kinetics of carbothermic reduction of manganese oxide and the catalyticeffect of La_2O_3 on the reduction have been studied by the measurement of mass loss in N_2atmosphere at different temperatures and followed by SEM analysis. It is concluded that the kineticsof carbothermic reduction of manganese oxide is divided into three stages: gas diffusioncontrolling stage, carbon gasification con-trolling stage and solid state diffusion controllingstage. La_2O_3 has catalytic effect on the reduction. The catalytic effect of La_2O_3 increases withthe added amount of La_2O_3. SEM analysis shows that the catalytic mechanism is that La_2O_3promotes the transfer of oxygen ions so that carbon gasifying is catalyzed and thus carbothermicreduction of MnO_2 is catalyzed.展开更多
According to the electrical operation and steelmaking theory of EAF, animproved power input procedure of 70 t high impedance EAF in Nanjinng Iron and Steel Corp. Ltd. wasstudied. The investigation method, process and ...According to the electrical operation and steelmaking theory of EAF, animproved power input procedure of 70 t high impedance EAF in Nanjinng Iron and Steel Corp. Ltd. wasstudied. The investigation method, process and result for use of power supply of high impedance EAFwas proposed, and the optimized power-supply curve to EAF steelmaking practice was given, andelectrical operation was improved, the electric energy consumption can be reduced by 25 kW. T/t, andpower supply time can also be reduced 3 min.展开更多
The solid-solid phase transitions in the perovskite type layer materials(n-C_(12)H_(25)NH_3)_2ZnCl_4 (C_(12)Zn) and (n-C_(18)H_(37)NH_3)_2ZnCl_4 (C_(18)Zn) that are onekind of potential thermal storage material, were ...The solid-solid phase transitions in the perovskite type layer materials(n-C_(12)H_(25)NH_3)_2ZnCl_4 (C_(12)Zn) and (n-C_(18)H_(37)NH_3)_2ZnCl_4 (C_(18)Zn) that are onekind of potential thermal storage material, were synthesized and, at the same time, a series oftheir mixtures C_(12)Zn/C_(18)Zn were prepared. The experimental binary phase diagram ofC_(12)Zn/C_(18)Zn was established by means of differential scanning calorimetry (DSC) and X-raydiffraction. In the phase diagram a stable solid compound(n-C_(12)H_(25)NH_3)(n-C_(18)H_(37)NH_3)ZnCl_4(C_(12)C_(18)Zn) and two eutectoid invariants wereobserved. It is noticeable that the phase diagram contains solid solution ranges.dodecylammonium展开更多
The thermodynamic factor in diffusion in the L1_2-type non-stoichiometricintermetallic compounds Ni_3Ga and Pt_3In was derived from the experimentally measured activities ofGa and In, respectively. The results show th...The thermodynamic factor in diffusion in the L1_2-type non-stoichiometricintermetallic compounds Ni_3Ga and Pt_3In was derived from the experimentally measured activities ofGa and In, respectively. The results show that the thermodynamic factor in diffusion in the Ni_3Gaand Pt_3In compounds exhibits the maximum near the stoichiometric composition with the variation ofcomposition over the compound region. The values indicate strong interaction between Ni and Gaatoms, as well as Pt and In atoms, respectively, as expected in ordered alloys.展开更多
A mathematical model was established and applied to simulate thedecarburization of RH-MFB process in Pansteel Company. Study of theeffects of w_[C]0, w_[O]0, Ar flowrate, evaluation rate the MFB lanceblowing parameter...A mathematical model was established and applied to simulate thedecarburization of RH-MFB process in Pansteel Company. Study of theeffects of w_[C]0, w_[O]0, Ar flowrate, evaluation rate the MFB lanceblowing parameters on the decarburization process was car- Ried out.The results showed that this model could give the quantitativeunderstanding of the process, especially the behavior of MFB Lanceblowing. This model has realized the optimum process of RH-MFBrefining for ultra-low carbon steels in Pansteel.展开更多
The application of the optimal sinter burden design in the sinter shop of No.1 Iron-making Plant in Tangshan Iron & Steel Corp was reported. By using burden calculation andsimulating production under different sit...The application of the optimal sinter burden design in the sinter shop of No.1 Iron-making Plant in Tangshan Iron & Steel Corp was reported. By using burden calculation andsimulating production under different situations, it is demonstrated that the technology can providethe relevant information in product quality and cost etc. for decision-makers. The technology hasbeen used to guide production of the Sinter Shop since 2000, and a remarkable achievement has beenobtained.展开更多
文摘Much attention has been paid to copper staves because they have excellentperformance and longevity. The hot test of copper staves was carried out using all-scale staveexperiment system and according to the results, the temperature distribution and heatcharacteristics were studied. The result shows that copper stave possesses outstanding heat transferability, a well-distributed temperature field and low temperature on the hot side. In addition, amodel was established to calculate the cooling water channels' inner face temperature. Thecalculation results indicates that the highest temperature of the inner wall of the channels is 42deg C, and at the same time, the cold side of the stave temperature is 42-43 deg C. That is to say,the temperature in the stave is quite uniform.
基金This work was financially supported by the National Basic Research on New Generation Steel (973) (No.J1998061511-3)
文摘With the help of solidification kinetics, precipitation and growth of TiNhave been studied theoretically and the effect of cooling rate on the growth of TiN has beendiscussed. Through induction electric furnace experiment and electroslag remelting experiment withdifferent cooling rates, the distribution and particle size of TiN were investigated. It is provedthat the higher cooling rate is, the smaller the final size of TiN is and the more TiN particles canbe found in the steel. That TiN can restrain the growth of columnar crystal and enhance theproportion of equiaxed crystals to refine solidification structure as the heterogeneous nucleationsites of δ-ferrite is confirmed preliminarily. A new method to reduce macrosegregation incontinuous cast steel is provided.
文摘The pure iron was melted and deoxidized by metallic Al and rare earth elements La, Ce and Y respectively at 1600℃ in a vertical resistance furnace. The morphology, chemical composition and size distribution of the inclusions in deoxidized liquid iron have been investigated by using of SEM and image-analysis techniques. The investigated results show that the deoxidation products in molten iron are complex inclusions of rare earth oxide or A12O3 combined with FeO finely distributed. The proper holding time and rapid cooling rate can make inclusions finer. La, Y and Al are more effective than Ce for obtaining finely distributed inclusions.
基金This work is financially supported by the National Natural Science Foundation of China (Nos. 59674028 and 20101006).
文摘A geometric model for calculating the viscosity of multi-component melt fromrelated binary physicochemistry properties was derived based on Chou's thermodynamic geometricmodel. The model derived was employed to predict the viscosity of Au-Ag-Cu alloys. The results showthat the calculated viscosity for Au-Ag-Cu alloys meet the experimental data very well. In addition,the viscosity of Bi-Sn-In systems was also predicted with this model.
文摘A two-dimensional model was applied to simulate the liquid core reduction (LCR) technology of bloom CC using ANSYS software. The deformation characteristics of bloom under different liquid fraction and reducing amount are obtained. The results indicate that the main deformation condition of bloom shell is compressive strain, mainly undertaken by the liquid core, which increases with the enhancement of reducing amount. Solidified shell takes minor deformation. The longitudinal section of bloom appears sunken and the narrow side bulges, which grow serious when the liquid fraction increases.
文摘The hot ductility of the V-containing micro-alloying steel CC (continuouscasting) slabs and precipitation of vanadium carbide in the tensile specimens were investigated. Theresults indicate that the precipitation ratio and precipitation rate of vanadium in the specimensreach maximum respectively at 900, -825 and 825 deg C. There is still l0 percent-l7 percent ofvanadium precipitated when the deformation temperature decreases to 800-700 deg C. Vanadium largelyaffects the ductility of the steel in the low ductility temperature Region III. Embrittlement ofsteel with higher V content is severer in the region and the embrittlement extends to lowertemperature.
文摘Kinetics of carbothermic reduction of manganese oxide and the catalyticeffect of La_2O_3 on the reduction have been studied by the measurement of mass loss in N_2atmosphere at different temperatures and followed by SEM analysis. It is concluded that the kineticsof carbothermic reduction of manganese oxide is divided into three stages: gas diffusioncontrolling stage, carbon gasification con-trolling stage and solid state diffusion controllingstage. La_2O_3 has catalytic effect on the reduction. The catalytic effect of La_2O_3 increases withthe added amount of La_2O_3. SEM analysis shows that the catalytic mechanism is that La_2O_3promotes the transfer of oxygen ions so that carbon gasifying is catalyzed and thus carbothermicreduction of MnO_2 is catalyzed.
文摘According to the electrical operation and steelmaking theory of EAF, animproved power input procedure of 70 t high impedance EAF in Nanjinng Iron and Steel Corp. Ltd. wasstudied. The investigation method, process and result for use of power supply of high impedance EAFwas proposed, and the optimized power-supply curve to EAF steelmaking practice was given, andelectrical operation was improved, the electric energy consumption can be reduced by 25 kW. T/t, andpower supply time can also be reduced 3 min.
基金This work was financially supported by the National Natural Science Foundation of China (No.50074003) the Hebei Natural Science Foundation of China (202139).]
文摘The solid-solid phase transitions in the perovskite type layer materials(n-C_(12)H_(25)NH_3)_2ZnCl_4 (C_(12)Zn) and (n-C_(18)H_(37)NH_3)_2ZnCl_4 (C_(18)Zn) that are onekind of potential thermal storage material, were synthesized and, at the same time, a series oftheir mixtures C_(12)Zn/C_(18)Zn were prepared. The experimental binary phase diagram ofC_(12)Zn/C_(18)Zn was established by means of differential scanning calorimetry (DSC) and X-raydiffraction. In the phase diagram a stable solid compound(n-C_(12)H_(25)NH_3)(n-C_(18)H_(37)NH_3)ZnCl_4(C_(12)C_(18)Zn) and two eutectoid invariants wereobserved. It is noticeable that the phase diagram contains solid solution ranges.dodecylammonium
基金This project is jointly supported by the National Natural Science Foundation of China (No. 29871005) the Science Foundation of Austria (No. P12962-CHE).
文摘The thermodynamic factor in diffusion in the L1_2-type non-stoichiometricintermetallic compounds Ni_3Ga and Pt_3In was derived from the experimentally measured activities ofGa and In, respectively. The results show that the thermodynamic factor in diffusion in the Ni_3Gaand Pt_3In compounds exhibits the maximum near the stoichiometric composition with the variation ofcomposition over the compound region. The values indicate strong interaction between Ni and Gaatoms, as well as Pt and In atoms, respectively, as expected in ordered alloys.
文摘A mathematical model was established and applied to simulate thedecarburization of RH-MFB process in Pansteel Company. Study of theeffects of w_[C]0, w_[O]0, Ar flowrate, evaluation rate the MFB lanceblowing parameters on the decarburization process was car- Ried out.The results showed that this model could give the quantitativeunderstanding of the process, especially the behavior of MFB Lanceblowing. This model has realized the optimum process of RH-MFBrefining for ultra-low carbon steels in Pansteel.
文摘The application of the optimal sinter burden design in the sinter shop of No.1 Iron-making Plant in Tangshan Iron & Steel Corp was reported. By using burden calculation andsimulating production under different situations, it is demonstrated that the technology can providethe relevant information in product quality and cost etc. for decision-makers. The technology hasbeen used to guide production of the Sinter Shop since 2000, and a remarkable achievement has beenobtained.
