A pseudo-ternary alloy system was constructed by combining an icosahedralquasicrystal (IQC), a decagonal quasicrystal (DQC), and Zr into one alloy system. Differentproportions of Zr were added to pseudo-binary alloy I...A pseudo-ternary alloy system was constructed by combining an icosahedralquasicrystal (IQC), a decagonal quasicrystal (DQC), and Zr into one alloy system. Differentproportions of Zr were added to pseudo-binary alloy IQC_(80)DQC_(20) (mass fraction in %);Structural evolution in these alloys was discussed. An amorphous alloy composition was found in thissystem and a melt-spinning amorphous alloy was produced in this composition. Through DSC analysis,the amorphous alloy exhibits high glass forming ability comparable to that of the InoueZr_(65)Al_(7.5)Cu_(17.5)Ni_(10) amorphous alloy.展开更多
The structure and microstructure of constituent phases in annealed IQC100-xDQCx alloys, made from mixtures of (Al62Cu25.5Fe12.5) icosahedral quasicrystal (IQC) and (Al70Co15Ni15) decagonal quasicrystal (DQC), were...The structure and microstructure of constituent phases in annealed IQC100-xDQCx alloys, made from mixtures of (Al62Cu25.5Fe12.5) icosahedral quasicrystal (IQC) and (Al70Co15Ni15) decagonal quasicrystal (DQC), were studied by X-ray diffractometry(XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDAX). These constituent phases are mostly approximants: λ, β and τ3. In addition, an Al-Cu-Co DQC phase is observed in (IQC80DQC20) alloy. The nature of these approximants and their relationship with the quasicrystals(QCs) are discussed; and the evolution of these phases is interpreted by the shifting of their e/a-constant lines in the Al-(Cu, Ni)-(Fe, Co) pseudo-ternary phase diagrams.展开更多
基金This work wax financially supported by the French-Chinese Advanced Research Program on Materials (PRA MX 99/04) and by the National Natural Science Foundation of China (Nos. 59971014 and 50071013)
文摘A pseudo-ternary alloy system was constructed by combining an icosahedralquasicrystal (IQC), a decagonal quasicrystal (DQC), and Zr into one alloy system. Differentproportions of Zr were added to pseudo-binary alloy IQC_(80)DQC_(20) (mass fraction in %);Structural evolution in these alloys was discussed. An amorphous alloy composition was found in thissystem and a melt-spinning amorphous alloy was produced in this composition. Through DSC analysis,the amorphous alloy exhibits high glass forming ability comparable to that of the InoueZr_(65)Al_(7.5)Cu_(17.5)Ni_(10) amorphous alloy.
文摘The structure and microstructure of constituent phases in annealed IQC100-xDQCx alloys, made from mixtures of (Al62Cu25.5Fe12.5) icosahedral quasicrystal (IQC) and (Al70Co15Ni15) decagonal quasicrystal (DQC), were studied by X-ray diffractometry(XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDAX). These constituent phases are mostly approximants: λ, β and τ3. In addition, an Al-Cu-Co DQC phase is observed in (IQC80DQC20) alloy. The nature of these approximants and their relationship with the quasicrystals(QCs) are discussed; and the evolution of these phases is interpreted by the shifting of their e/a-constant lines in the Al-(Cu, Ni)-(Fe, Co) pseudo-ternary phase diagrams.