In this work,the micromechanical properties,crystallographic texture,welding residual stresses and their evolution after plastic strain were investigated in a Ti-6Al-4V alloy tungsten inert gas weld joint.It was found...In this work,the micromechanical properties,crystallographic texture,welding residual stresses and their evolution after plastic strain were investigated in a Ti-6Al-4V alloy tungsten inert gas weld joint.It was found that the welding process affected the Young modulus and microhardness values in bothαandβphases in the different regions of the weld joint.The highest microhardness and Young modulus values of a phase were recorded in the heat-affected zone,whereas the highest values of these characteristics for theβphase were found in the fusion zone(FZ).The change in the micro mechanical properties was accompanied by a change in the crystallographic texture components of the dominant a phase from(0001)<10-10>and(11-20)<10-10>components in the base material to(10-10)<11-20>and(11-20)<3-302>components in the FZ.The introduction of tensile testing resulted in a continuous stress relaxation and improved the weld joint performances.展开更多
Ti-6Al,Ti-6Al-2Mo and Ti-6Al-3Nb alloys were prepared to investigate the toughening effects ofβstabilizers Mo and Nb on impact toughness and crack resistance of titanium alloys.Instrumented Charpy impact tests showed...Ti-6Al,Ti-6Al-2Mo and Ti-6Al-3Nb alloys were prepared to investigate the toughening effects ofβstabilizers Mo and Nb on impact toughness and crack resistance of titanium alloys.Instrumented Charpy impact tests showed that the total impact absorbed energy of Ti-6Al-2Mo and Ti-6Al-3Nb(∼64 J)were two times higher than that of Ti-6Al(∼30 J),indicating the higher impact toughness of Ti-6Al-2Mo and Ti-6Al-3Nb alloys.Analysis of load-displacement curves revealed the similar crack initiation energy of Ti-6Al,Ti-6Al-2Mo and Ti-6Al-3Nb(15.4 J,16.1 J and 15.0 J,respectively).However,the higher crack propagation energy of Ti-6Al-2Mo and Ti-6Al-3Nb(46.7 J and 48.3 J,respectively)were about three times higher than that of Ti-6Al(14.4 J),indicating the stronger resistance to crack propagation in Ti-6Al-2Mo and Ti-6Al-3Nb.Post-mortem analysis of impact samples demonstrated that the increased dislocation density and deformation twinning were mainly responsible for the stronger resistance to crack propagation in Ti-6Al-2Mo and Ti-6Al-3Nb.Due to the invisibility of dislocation activation and deformation twinning during the Charpy impact process,a mathematical model has been proposed to evaluate the effects of Al,Mo and Nb elements on dislocation mobility based on the Yu Rui-huang electron theory.Addition of Mo and Nb elements significantly improved the dislocation mobility in Ti-6Al-2Mo and Ti-6Al-3Nb compared to that in Ti-6Al alloy.Therefore,more dislocations were activated in Ti-6Al-2Mo and Ti-6Al-3Nb which supplied the larger plastic deformation under impact loading.A dislocation-based model also has been proposed to interpret the nucleation and propagation of deformation twinning under the impact loading.Dislocation pileup atα/βinterfaces provided potential sites for nucleation of deformation twinning in Ti-6Al-2Mo and Ti-6Al-3Nb.Furthermore,deformation twinning facilitated the dislocation motion inαgrains with hard orientations.The increased dislocation mobility and deformation twinning were responsible for the strong展开更多
The aim of this work is to study the influence of successive weld repairs on the microstructure and the mechanical behavior of the heat-affected zone（HAZ） of an HSLA X70 steel. Detailed microstructural examination c...The aim of this work is to study the influence of successive weld repairs on the microstructure and the mechanical behavior of the heat-affected zone（HAZ） of an HSLA X70 steel. Detailed microstructural examination combined to grain size measurement showed that beyond the second weld repair, the microstructure of the HAZ undergoes significant change in the grain morphology and grain growth. The results of the X-ray diffraction analyzed using MAUD software indicated an increase in the crystallite size and a decrease in the dislocation density according to the number of weld repair operations. Consequently, a loss of mechanical properties, namely the yield strength and the toughness with the number of weld repairs, was recorded. Beyond the second weld repair operation, the properties of the welded joint do not fulfill the standards applied in piping industry.展开更多
In current work,Ni-Ti-CeO_(2) nanocomposite coatings were achieved by co-adding Ti microparticles and CeO_(2) nanoparticles.Designed experiments and COMSOL computer simulation were applied to reveal the synergistic ro...In current work,Ni-Ti-CeO_(2) nanocomposite coatings were achieved by co-adding Ti microparticles and CeO_(2) nanoparticles.Designed experiments and COMSOL computer simulation were applied to reveal the synergistic role of Ti microparticles and CeO_(2) nanoparticles in tailoring the spatial microstructures and properties of Ni-Ti-CeO_(2) nanocomposite coating.Unilaterally,the conductive Ti microparticles conducted the growth behavior of Ni grains by current density concentration,distorting electronic feld lines and heterogeneous nucleation.Individual domains consisting of inner nanograins and outer radial columnar grains surrounded Ti microparticles,where Ti microparticles acted as seeds.Ti microparticles tended to be aggregated,leading to spatial heterogeneity of microstructures.Ni deposits buried the Ti microparticles in forms of“covering model”,contributing to the formation of inside voids and rough surface and aggregation of Ti microparticles;on the other hand,the non-conductive CeO_(2)microparticles hardly changed the distribution of current density and electronic feld lines on the cathode surface.Ni deposits buried the CeO_(2)microparticle in forms of“stacking model”,avoiding the inside voids and aggregation of particles.The incorporation of CeO_(2)microparticle brought in microstructure evolutions only on its top side without disturbing the growth behavior of Ni grains on its lateral side or bottom,suggesting the limited effects.This was correlated with the presence of current concentration above the CeO_(2) microparticle at the last stage of burying CeO_(2) microparticle.The co-addition of Ti microparticles and CeO_(2) nanoparticles into Ni deposits exploited the complementary action of the two particles,which gave birth to satisfed spatial microstructures and improved hardness.Ti microparticles took major responsibility for microstructure evolutions,while the CeO_(2) nanoparticles were mainly in charge of the microstructure homogeneity.展开更多
The structural, electronic, and magnetic properties of double perovskite Sr_2FeReO_6 containing eight different imperfections of FeReor ReFeantisites, Fe1–Re1 or Fe1–Re4 interchanges, V_（Fe）, V_（Re）, VOor V_（Sr...The structural, electronic, and magnetic properties of double perovskite Sr_2FeReO_6 containing eight different imperfections of FeReor ReFeantisites, Fe1–Re1 or Fe1–Re4 interchanges, V_（Fe）, V_（Re）, VOor V_（Sr） vacancies have been studied by using the first-principles projector augmented wave（PAW） within generalized gradient approximation as well as taking into account the on-site Coulomb repulsive interaction（GGA＋U）. No obvious structural changes are observed for the imperfect Sr_2FeReO_6 containing FeReor ReFeantisites, Fe1–Re1 or Fe1–Re4 interchanges, or VSrvacancy defects. However, the six（eight） nearest oxygen neighbors of the vacancy move away from（close to） VFeor V_（Re）（VO） vacancies. The half-metallic（HM） character is maintained for the imperfect Sr_2FeReO_6 containing FeReor ReFeantisites, Fe1–Re4 interchange, V_（Fe）,VO or V_（Sr） vacancies, while it vanishes when the Fe1–Re1 interchange or VRevacancy is presented. So the Fe1–Re1 interchange and the VRevacancy defects should be avoided to preserve the HM character of Sr_2FeReO_6 and thus usage in spintronic devices. In the FeReor ReFeantisites, Fe1–Re1 or Fe1–Re4 interchanges cases, the spin moments of the Fe（Re）cations situated on Re（Fe） antisites are in an antiferromagnetic coupling with those of the Fe（Re） cations on the regular sites. In the V_（Fe）, V_（Re）, VO, or V_（Sr） vacancies cases, a ferromagnetic coupling is obtained within each cation sublattice,while the two cation sublattices are coupled antiferromagnetically. The total magnetic moments μtot（μB/f.u.） of the imperfect Sr_2FeReO_6 containing eight different defects decrease in the sequence of VSrvacancy（3.50）, VRevacancy（3.43）,FeReantisite（2.74）, VOvacancy（2.64）, VFevacancy（2.51）, ReFeantisite（2.29）, Fe1–Re4 interchange（1.96）, Fe1–Re1interchange（1.87）, and the mechanisms of the saturation magnetization reduction have been analyzed.展开更多
文摘In this work,the micromechanical properties,crystallographic texture,welding residual stresses and their evolution after plastic strain were investigated in a Ti-6Al-4V alloy tungsten inert gas weld joint.It was found that the welding process affected the Young modulus and microhardness values in bothαandβphases in the different regions of the weld joint.The highest microhardness and Young modulus values of a phase were recorded in the heat-affected zone,whereas the highest values of these characteristics for theβphase were found in the fusion zone(FZ).The change in the micro mechanical properties was accompanied by a change in the crystallographic texture components of the dominant a phase from(0001)<10-10>and(11-20)<10-10>components in the base material to(10-10)<11-20>and(11-20)<3-302>components in the FZ.The introduction of tensile testing resulted in a continuous stress relaxation and improved the weld joint performances.
基金The authors acknowledge the financial supports of National Key Research and Development Program of China(2016YFB0301201)。
文摘Ti-6Al,Ti-6Al-2Mo and Ti-6Al-3Nb alloys were prepared to investigate the toughening effects ofβstabilizers Mo and Nb on impact toughness and crack resistance of titanium alloys.Instrumented Charpy impact tests showed that the total impact absorbed energy of Ti-6Al-2Mo and Ti-6Al-3Nb(∼64 J)were two times higher than that of Ti-6Al(∼30 J),indicating the higher impact toughness of Ti-6Al-2Mo and Ti-6Al-3Nb alloys.Analysis of load-displacement curves revealed the similar crack initiation energy of Ti-6Al,Ti-6Al-2Mo and Ti-6Al-3Nb(15.4 J,16.1 J and 15.0 J,respectively).However,the higher crack propagation energy of Ti-6Al-2Mo and Ti-6Al-3Nb(46.7 J and 48.3 J,respectively)were about three times higher than that of Ti-6Al(14.4 J),indicating the stronger resistance to crack propagation in Ti-6Al-2Mo and Ti-6Al-3Nb.Post-mortem analysis of impact samples demonstrated that the increased dislocation density and deformation twinning were mainly responsible for the stronger resistance to crack propagation in Ti-6Al-2Mo and Ti-6Al-3Nb.Due to the invisibility of dislocation activation and deformation twinning during the Charpy impact process,a mathematical model has been proposed to evaluate the effects of Al,Mo and Nb elements on dislocation mobility based on the Yu Rui-huang electron theory.Addition of Mo and Nb elements significantly improved the dislocation mobility in Ti-6Al-2Mo and Ti-6Al-3Nb compared to that in Ti-6Al alloy.Therefore,more dislocations were activated in Ti-6Al-2Mo and Ti-6Al-3Nb which supplied the larger plastic deformation under impact loading.A dislocation-based model also has been proposed to interpret the nucleation and propagation of deformation twinning under the impact loading.Dislocation pileup atα/βinterfaces provided potential sites for nucleation of deformation twinning in Ti-6Al-2Mo and Ti-6Al-3Nb.Furthermore,deformation twinning facilitated the dislocation motion inαgrains with hard orientations.The increased dislocation mobility and deformation twinning were responsible for the strong
基金the Research Center in Industria Technologies(CRTI)for its financial supportMohamed Khider University,Biskra,for its help to accomplish this study
文摘The aim of this work is to study the influence of successive weld repairs on the microstructure and the mechanical behavior of the heat-affected zone（HAZ） of an HSLA X70 steel. Detailed microstructural examination combined to grain size measurement showed that beyond the second weld repair, the microstructure of the HAZ undergoes significant change in the grain morphology and grain growth. The results of the X-ray diffraction analyzed using MAUD software indicated an increase in the crystallite size and a decrease in the dislocation density according to the number of weld repair operations. Consequently, a loss of mechanical properties, namely the yield strength and the toughness with the number of weld repairs, was recorded. Beyond the second weld repair operation, the properties of the welded joint do not fulfill the standards applied in piping industry.
文摘In current work,Ni-Ti-CeO_(2) nanocomposite coatings were achieved by co-adding Ti microparticles and CeO_(2) nanoparticles.Designed experiments and COMSOL computer simulation were applied to reveal the synergistic role of Ti microparticles and CeO_(2) nanoparticles in tailoring the spatial microstructures and properties of Ni-Ti-CeO_(2) nanocomposite coating.Unilaterally,the conductive Ti microparticles conducted the growth behavior of Ni grains by current density concentration,distorting electronic feld lines and heterogeneous nucleation.Individual domains consisting of inner nanograins and outer radial columnar grains surrounded Ti microparticles,where Ti microparticles acted as seeds.Ti microparticles tended to be aggregated,leading to spatial heterogeneity of microstructures.Ni deposits buried the Ti microparticles in forms of“covering model”,contributing to the formation of inside voids and rough surface and aggregation of Ti microparticles;on the other hand,the non-conductive CeO_(2)microparticles hardly changed the distribution of current density and electronic feld lines on the cathode surface.Ni deposits buried the CeO_(2)microparticle in forms of“stacking model”,avoiding the inside voids and aggregation of particles.The incorporation of CeO_(2)microparticle brought in microstructure evolutions only on its top side without disturbing the growth behavior of Ni grains on its lateral side or bottom,suggesting the limited effects.This was correlated with the presence of current concentration above the CeO_(2) microparticle at the last stage of burying CeO_(2) microparticle.The co-addition of Ti microparticles and CeO_(2) nanoparticles into Ni deposits exploited the complementary action of the two particles,which gave birth to satisfed spatial microstructures and improved hardness.Ti microparticles took major responsibility for microstructure evolutions,while the CeO_(2) nanoparticles were mainly in charge of the microstructure homogeneity.
基金Project supported by the National Natural Science Foundation of China(Grant No.51501017)
文摘The structural, electronic, and magnetic properties of double perovskite Sr_2FeReO_6 containing eight different imperfections of FeReor ReFeantisites, Fe1–Re1 or Fe1–Re4 interchanges, V_（Fe）, V_（Re）, VOor V_（Sr） vacancies have been studied by using the first-principles projector augmented wave（PAW） within generalized gradient approximation as well as taking into account the on-site Coulomb repulsive interaction（GGA＋U）. No obvious structural changes are observed for the imperfect Sr_2FeReO_6 containing FeReor ReFeantisites, Fe1–Re1 or Fe1–Re4 interchanges, or VSrvacancy defects. However, the six（eight） nearest oxygen neighbors of the vacancy move away from（close to） VFeor V_（Re）（VO） vacancies. The half-metallic（HM） character is maintained for the imperfect Sr_2FeReO_6 containing FeReor ReFeantisites, Fe1–Re4 interchange, V_（Fe）,VO or V_（Sr） vacancies, while it vanishes when the Fe1–Re1 interchange or VRevacancy is presented. So the Fe1–Re1 interchange and the VRevacancy defects should be avoided to preserve the HM character of Sr_2FeReO_6 and thus usage in spintronic devices. In the FeReor ReFeantisites, Fe1–Re1 or Fe1–Re4 interchanges cases, the spin moments of the Fe（Re）cations situated on Re（Fe） antisites are in an antiferromagnetic coupling with those of the Fe（Re） cations on the regular sites. In the V_（Fe）, V_（Re）, VO, or V_（Sr） vacancies cases, a ferromagnetic coupling is obtained within each cation sublattice,while the two cation sublattices are coupled antiferromagnetically. The total magnetic moments μtot（μB/f.u.） of the imperfect Sr_2FeReO_6 containing eight different defects decrease in the sequence of VSrvacancy（3.50）, VRevacancy（3.43）,FeReantisite（2.74）, VOvacancy（2.64）, VFevacancy（2.51）, ReFeantisite（2.29）, Fe1–Re4 interchange（1.96）, Fe1–Re1interchange（1.87）, and the mechanisms of the saturation magnetization reduction have been analyzed.
