Nanoparticles(NPs)can promote the column flotation process in mining industry.Nanoparticles'effects on column flotation process(copper recovery,grade and flotation rate constant)are assessed in Sarcheshmeh Copper ...Nanoparticles(NPs)can promote the column flotation process in mining industry.Nanoparticles'effects on column flotation process(copper recovery,grade and flotation rate constant)are assessed in Sarcheshmeh Copper Complex,Iran,through response surface methodology(RSM)optimization technique.The c-Al2O3,a-Fe2O3,SiO2,and TiO2 nanoparticles are selected for these experiments.A flotation rate constant is chosen as a response to assess the effect of nanoparticles on flotation in its kinetic sense.The process p H and nanoparticle dosage are selected as the influential parameters.Results obtained from RSM indicated that the maximum percentage of Cu recovery and grade is obtained at p H of 12 and nanoparticle dosage of 6 kg/t,through a-Fe2O3 and c-Al2O3 nanoparticles,respectively.Applying nanoparticles in particular c-Al2O3 and a-Fe2O3 increases the Cu recovery by 8–10%together with the grade by 3–6%in a significant manner.It is revealed that nanoparticles could effectively be applied in enhancing the flotation performance.展开更多
The properties of propagating surface plasmon polaritons(SPPs)along one-dimensional metal structures have been investigated for more than 10 years and are now well understood.Because of the high confinement of electro...The properties of propagating surface plasmon polaritons(SPPs)along one-dimensional metal structures have been investigated for more than 10 years and are now well understood.Because of the high confinement of electromagnetic energy,propagating SPPs have been considered to represent one of the best potential ways to construct next-generation circuits that use light to overcome the speed limit of electronics.Many basic plasmonic components have already been developed.In this review,researches on plasmonic waveguides are reviewed from the perspective of plasmonic circuits.Several circuit components are constructed to demonstrate the basic function of an optical digital circuit.In the end of this review,a prototype for an SPP-based nanochip is proposed,and the problems associated with building such plasmonic circuits are discussed.A plasmonic chip that can be practically applied is expected to become available in the near future.展开更多
Small-scale rotorcraft unmanned robotic systems(SRURSs) are a kind of unmanned rotorcraft with manipulating devices. This review aims to provide an overview on aerial manipulation of SRURSs nowadays and promote relati...Small-scale rotorcraft unmanned robotic systems(SRURSs) are a kind of unmanned rotorcraft with manipulating devices. This review aims to provide an overview on aerial manipulation of SRURSs nowadays and promote relative research in the future. In the past decade, aerial manipulation of SRURSs has attracted the interest of researchers globally. This paper provides a literature review of the last 10 years(2008–2017) on SRURSs, and details achievements and challenges. Firstly, the definition, current state, development, classification, and challenges of SRURSs are introduced. Then, related papers are organized into two topical categories: mechanical structure design, and modeling and control. Following this, research groups involved in SRURS research and their major achievements are summarized and classified in the form of tables. The research groups are introduced in detail from seven parts. Finally, trends and challenges are compiled and presented to serve as a resource for researchers interested in aerial manipulation of SRURSs. The problem,trends, and challenges are described from three aspects. Conclusions of the paper are presented,and the future of SRURSs is discussed to enable further research interests.展开更多
Recent advances in ubiquitous low-power electronics call for the development of light-weight and flexible energy sources.The textile format is highly attractive for unobtrusive harvesting of energy from e.g.,biomechan...Recent advances in ubiquitous low-power electronics call for the development of light-weight and flexible energy sources.The textile format is highly attractive for unobtrusive harvesting of energy from e.g.,biomechanical movements.Here,we report the manufacture and characterisation of fully textile piezoelectric generators that can operate under wet conditions.We use a weaving loom to realise textile bands with yarns of melt-spun piezoelectric microfibres,that consist of a conducting core surrounded byβ-phase poly(vinylidene fluoride)(PVDF),in the warp direction.The core-sheath constitution of the piezoelectric microfibres results in a—for electronic textiles—unique architecture.The inner electrode is fully shielded from the outer electrode(made up of conducting yarns that are integrated in the weft direction)which prevents shorting under wet conditions.As a result,and in contrast to other energy harvesting textiles,we are able to demonstrate piezoelectric fabrics that do not only continue to function when in contact with water,but show enhanced performance.The piezoelectric bands generate an output of several volts at strains below one percent.We show that integration into the shoulder strap of a laptop case permits the continuous generation of four microwatts of power during a brisk walk.This promising performance,combined with the fact that our solution uses scalable materials and well-established industrial manufacturing methods,opens up the possibility to develop wearable electronics that are powered by piezoelectric textiles.展开更多
Lower limb injures are frequently observed in passenger car traffic accidents.Previous studies of the injuries focus on long bone fractures by using either cadaver component tests or simulations of the long bone kinem...Lower limb injures are frequently observed in passenger car traffic accidents.Previous studies of the injuries focus on long bone fractures by using either cadaver component tests or simulations of the long bone kinematics,which lack in-depth study on the fractures in stress analysis.This paper aims to investigate lower limb impact biomechanics in real-world car to pedestrian accidents and to predict fractures of long bones in term of stress parameter for femur,tibia,and fibula.For the above purposes,a 3D finite element(FE) model of human body lower limb(HBM-LL) is developed based on human anatomy.The model consists of the pelvis,femur,tibia,fibula,patella,foot bones,primary tendons,knee joint capsule,meniscus,and ligaments.The FE model is validated by comparing the results from a lateral impact between simulations and tests with cadaver lower limb specimens.Two real-world accidents are selected from an in-depth accident database with detailed information about the accident scene,car impact speed,damage to the car,and pedestrian injuries.Multi-body system(MBS) models are used to reconstruct the kinematics of the pedestrians in the two accidents and the impact conditions are calculated for initial impact velocity and orientations of the car and pedestrian during the collision.The FE model is used to perform injury reconstructions and predict the fractures by using physical parameters,such as von Mises stress of long bones.The calculated failure level of the long bones is correlated with the injury outcomes observed from the two accident cases.The reconstruction result shows that the HBM-LL FE model has acceptable biofidelity and can be applied to predict the risk of long bone fractures.This study provides an efficient methodology to investigate the long bone fracture suffered from vehicle traffic collisions.展开更多
The three-dimensional vortical structures for an impinging transverse jet in the near region were numerically investigated by means of Large-Eddy Simulation （LES）. The LES results reproduced the skewed jet shear lay...The three-dimensional vortical structures for an impinging transverse jet in the near region were numerically investigated by means of Large-Eddy Simulation （LES）. The LES results reproduced the skewed jet shear layer vortices close to the jet nozzle and the scarf vortex in the near-wall zone in good agreement with the experimental observations. Different vortical modes in the skewed jet shear layer close to the jet nozzle were identified depending upon the velocity ratio between jet and crossflow, namely changing from an approximately axisymmetric mode to a helical one with the velocity ratios varying from 20 to 8. Moreover, the scarf vortex wrapped around the impinging jet in the near-wall zone showed distinct asymmetry with regard to its bilateral spiral legs within the near region. And the entrainment of the ambient crossflow fluids by the scarf vortex in the near-wall zone was appreciably influenced by its asymmetry and in a large part occurred on the surface of the spiral roller structures in the course of spreading downstream.展开更多
Due to its amazing ability to manipulate light at the nanoscale,plasmonics has become one of the most interesting topics in the field of light–matter interaction.As a promising application of plasmonics,surface-enhan...Due to its amazing ability to manipulate light at the nanoscale,plasmonics has become one of the most interesting topics in the field of light–matter interaction.As a promising application of plasmonics,surface-enhanced Raman scattering(SERS)has been widely used in scientific investigations and material analysis.The large enhanced Raman signals are mainly caused by the extremely enhanced electromagnetic field that results from localized surface plasmon polaritons.Recently,a novel SERS technology called remote SERS has been reported,combining both localized surface plasmon polaritons and propagating surface plasmon polaritons(PSPPs,or called plasmonic waveguide),which may be found in prominent applications in special circumstances compared to traditional local SERS.In this article,we review the mechanism of remote SERS and its development since it was first reported in 2009.Various remote metal systems based on plasmonic waveguides,such as nanoparticle–nanowire systems,single nanowire systems,crossed nanowire systems and nanowire dimer systems,are introduced,and recent novel applications,such as sensors,plasmon-driven surface-catalyzed reactions and Raman optical activity,are also presented.Furthermore,studies of remote SERS in dielectric and organic systems based on dielectric waveguides remind us that this useful technology has additional,tremendous application prospects that have not been realized in metal systems.展开更多
The non-fully conjugated polymer as a new class of acceptor materials has shown some advantages over its small molecular counterpart when used in photoactive layers for all-polymer solar cells(all-PSCs),despite a low ...The non-fully conjugated polymer as a new class of acceptor materials has shown some advantages over its small molecular counterpart when used in photoactive layers for all-polymer solar cells(all-PSCs),despite a low power conversion efficiency(PCE)caused by its narrow absorption spectra.Herein,a novel non-fully conjugated polymer acceptor PFY-2TS with a low bandgap of~1.40 eV was developed,via polymerizing a largeπ-fused small molecule acceptor(SMA)building block(namely YBO)with a non-conjugated thioalkyl linkage.Compared with its precursor YBO,PFY-2TS retains a similar low bandgap but a higher LUMO level.Moreover,compared with the structural analog of YBO-based fully conjugated polymer acceptor PFY-DTC,PFY-2TS shows a similar absorption spectrum and electron mobility,but significantly different molecular crystallinity and aggregation properties,which results in optimal blend morphology with a polymer donor PBDB-T and physical processes of the device in all-PSCs.As a result,PFY-2TS-based all-PSCs achieved a PCE of 12.31%with a small energy loss of 0.56 eV enabled by the reduced non-radiative energy loss(0.24 eV),which is better than that of 11.08%for the PFY-DTC-based ones.Our work clearly demonstrated that non-fully conjugated polymers as a new class of acceptor materials are very promising for the development of high-performance all-PSCs.展开更多
In current years,the improvement of deep learning has brought about tremendous changes:As a type of unsupervised deep learning algorithm,generative adversarial networks(GANs)have been widely employed in various fields...In current years,the improvement of deep learning has brought about tremendous changes:As a type of unsupervised deep learning algorithm,generative adversarial networks(GANs)have been widely employed in various fields including transportation.This paper reviews the development of GANs and their applications in the transportation domain.Specifically,many adopted GAN variants for autonomous driving are classified and demonstrated according to data generation,video trajectory prediction,and security of detection.To introduce GANs to traffic research,this review summarizes the related techniques for spatio-temporal,sparse data completion,and time-series data evaluation.GAN-based traffic anomaly inspections such as infrastructure detection and status monitoring are also assessed.Moreover,to promote further development of GANs in intelligent transportation systems(ITSs),challenges and noteworthy research directions on this topic are provided.In general,this survey summarizes 130 GAN-related references and provides comprehensive knowledge for scholars who desire to adopt GANs in their scientific works,especially transportation-related tasks.展开更多
Human driven vehicles(HDVs)with selfish objectives cause low traffic efficiency in an un-signalized intersection.On the other hand,autonomous vehicles can overcome this inefficiency through perfect coordination.In thi...Human driven vehicles(HDVs)with selfish objectives cause low traffic efficiency in an un-signalized intersection.On the other hand,autonomous vehicles can overcome this inefficiency through perfect coordination.In this paper,we propose an intermediate solution,where we use vehicular communication and a small number of autonomous vehicles to improve the transportation system efficiency in such intersections.In our solution,two connected autonomous vehicles(CAVs)lead multiple HDVs in a double-lane intersection in order to avoid congestion in front of the intersection.The CAVs are able to communicate and coordinate their behavior,which is controlled by a deep reinforcement learning(DRL)agent.We design an altruistic reward function which enables CAVs to adjust their velocities flexibly in order to avoid queuing in front of the intersection.The proximal policy optimization(PPO)algorithm is applied to train the policy and the generalized advantage estimation(GAE)is used to estimate state values.Training results show that two CAVs are able to achieve significantly better traffic efficiency compared to similar scenarios without and with one altruistic autonomous vehicle.展开更多
Municipal solid waste incineration products of bottom ash(BA),fly ash(FA),and pickling sludge(PS),causing severe environ-mental pollution,were transformed into glass ceramic foams with the aid of CaCO3 as a pore-foami...Municipal solid waste incineration products of bottom ash(BA),fly ash(FA),and pickling sludge(PS),causing severe environ-mental pollution,were transformed into glass ceramic foams with the aid of CaCO3 as a pore-foaming agent during sintering.The effect of the BA/FA mass ratio on the phase composition,pore morphology,pore size distribution,physical properties,and glass structure was investigated,with results showing that with the increase in the BA/FA ratio,the content of the glass phase,Si-O-Si,and Q3Si units decrease gradually.The glass transmission temperature of the mixture was also reduced.When combined,the glass viscosity decreases,causing bubble coalescence and uneven pore distribution.Glass ceramic foams with uniform spherical pores are fabricated.When the content of BA,FA,and PS are 35wt%,45wt%,and 20wt%,respectively,contributing to high performance glass ceramic foams with a bulk density of 1.76 g/cm3,porosity of 56.01%,and compressive strength exceeding 16.23 MPa.This versatile and low-cost approach provides new insight into synergistically recycling solid wastes.展开更多
This study presents results of experiments where roughness applications are evaluated in delaying the tip vortex cavitation inception of an elliptical foil.High-speed video recordings and laser doppler velocimetry(LDV...This study presents results of experiments where roughness applications are evaluated in delaying the tip vortex cavitation inception of an elliptical foil.High-speed video recordings and laser doppler velocimetry(LDV)measurements are employed to provide further details on the cavitation behavior and tip vortex flow properties in different roughness pattern configurations.The angular momentum measurements of the vortex core region at one chord length downstream of the tip indicate that roughness leads to a lower angular momentum compared with the smooth foil condition while the vortex core radius remains similar in the smooth and roughened conditions.The observations show that the cavitation number for tip vortex cavitation inception is reduced by 33%in the optimized roughness pattern compared with the smooth foil condition where the drag force increase is observed to be around 2%.During the tests,no obvious differences in the cavitation inception properties of uniform and non-uniform roughness distributions are observed.However,the drag force is found to be higher with a non-uniform roughness distribution.展开更多
Dramatic fall in costs of renewable energy in the last 24 months has not only accelerated the replacement of fossil fuels by renewable energy in electricity generation. The low cost renewable electricity is now starti...Dramatic fall in costs of renewable energy in the last 24 months has not only accelerated the replacement of fossil fuels by renewable energy in electricity generation. The low cost renewable electricity is now starting to replace fossil fuels in other sectors. One reason is that renewable electricity is now cheaper per unit energy than oil, about the same price as fossil methan but, still, more expensive than coal. Another reason is that electricity often offer other opportunities, such as cheaper transport, better control, higher energy efficiency in final production of energy services and lower local environmental costs.展开更多
基金The authors would like to extend their appreciation to the Sarcheshmeh Copper Complex management for providing the pilot plant Concentrator and R&D of this Complex and their financial support for this research.
文摘Nanoparticles(NPs)can promote the column flotation process in mining industry.Nanoparticles'effects on column flotation process(copper recovery,grade and flotation rate constant)are assessed in Sarcheshmeh Copper Complex,Iran,through response surface methodology(RSM)optimization technique.The c-Al2O3,a-Fe2O3,SiO2,and TiO2 nanoparticles are selected for these experiments.A flotation rate constant is chosen as a response to assess the effect of nanoparticles on flotation in its kinetic sense.The process p H and nanoparticle dosage are selected as the influential parameters.Results obtained from RSM indicated that the maximum percentage of Cu recovery and grade is obtained at p H of 12 and nanoparticle dosage of 6 kg/t,through a-Fe2O3 and c-Al2O3 nanoparticles,respectively.Applying nanoparticles in particular c-Al2O3 and a-Fe2O3 increases the Cu recovery by 8–10%together with the grade by 3–6%in a significant manner.It is revealed that nanoparticles could effectively be applied in enhancing the flotation performance.
基金This work was supported by National Nature Science Foundation of China(Grant Nos.91436102,11374353 and 11474141).
文摘The properties of propagating surface plasmon polaritons(SPPs)along one-dimensional metal structures have been investigated for more than 10 years and are now well understood.Because of the high confinement of electromagnetic energy,propagating SPPs have been considered to represent one of the best potential ways to construct next-generation circuits that use light to overcome the speed limit of electronics.Many basic plasmonic components have already been developed.In this review,researches on plasmonic waveguides are reviewed from the perspective of plasmonic circuits.Several circuit components are constructed to demonstrate the basic function of an optical digital circuit.In the end of this review,a prototype for an SPP-based nanochip is proposed,and the problems associated with building such plasmonic circuits are discussed.A plasmonic chip that can be practically applied is expected to become available in the near future.
基金supported by the National Natural Science Foundation of China (Nos. 91748201 and 51505014)
文摘Small-scale rotorcraft unmanned robotic systems(SRURSs) are a kind of unmanned rotorcraft with manipulating devices. This review aims to provide an overview on aerial manipulation of SRURSs nowadays and promote relative research in the future. In the past decade, aerial manipulation of SRURSs has attracted the interest of researchers globally. This paper provides a literature review of the last 10 years(2008–2017) on SRURSs, and details achievements and challenges. Firstly, the definition, current state, development, classification, and challenges of SRURSs are introduced. Then, related papers are organized into two topical categories: mechanical structure design, and modeling and control. Following this, research groups involved in SRURS research and their major achievements are summarized and classified in the form of tables. The research groups are introduced in detail from seven parts. Finally, trends and challenges are compiled and presented to serve as a resource for researchers interested in aerial manipulation of SRURSs. The problem,trends, and challenges are described from three aspects. Conclusions of the paper are presented,and the future of SRURSs is discussed to enable further research interests.
基金research engineer Roger Sagdahl,Chalmers University of Technology,for valuable discussions on energy harvesting.CHESS(supported by the NSF&NIH/NIGMS via NSF award DMR-1332208)is gratefully acknowledged for providing experimental time for WAXS measurementsFinancial support from the Swedish Foundation for Strategic Research(SSF)through grant no.SBE13-0086+1 种基金the Knut and Alice Wallenberg Foundation through a Wallenberg Academy Fellowshipthe European Research Council(ERC)under grant agreement no.637624 is gratefully acknowledged.
文摘Recent advances in ubiquitous low-power electronics call for the development of light-weight and flexible energy sources.The textile format is highly attractive for unobtrusive harvesting of energy from e.g.,biomechanical movements.Here,we report the manufacture and characterisation of fully textile piezoelectric generators that can operate under wet conditions.We use a weaving loom to realise textile bands with yarns of melt-spun piezoelectric microfibres,that consist of a conducting core surrounded byβ-phase poly(vinylidene fluoride)(PVDF),in the warp direction.The core-sheath constitution of the piezoelectric microfibres results in a—for electronic textiles—unique architecture.The inner electrode is fully shielded from the outer electrode(made up of conducting yarns that are integrated in the weft direction)which prevents shorting under wet conditions.As a result,and in contrast to other energy harvesting textiles,we are able to demonstrate piezoelectric fabrics that do not only continue to function when in contact with water,but show enhanced performance.The piezoelectric bands generate an output of several volts at strains below one percent.We show that integration into the shoulder strap of a laptop case permits the continuous generation of four microwatts of power during a brisk walk.This promising performance,combined with the fact that our solution uses scalable materials and well-established industrial manufacturing methods,opens up the possibility to develop wearable electronics that are powered by piezoelectric textiles.
基金supported by National Hi-tech Research and Development Program of China (863 Program,Grant No. 2006AA110101)"111 Program" of Ministry of Education and State Administration of Foreign Experts Affairs of China (Grant No. 111-2-11)+1 种基金General Motors Research and Development Center (Grant No. RD-209)Project of State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body,Hunan University,China (Grant No. 60870004)
文摘Lower limb injures are frequently observed in passenger car traffic accidents.Previous studies of the injuries focus on long bone fractures by using either cadaver component tests or simulations of the long bone kinematics,which lack in-depth study on the fractures in stress analysis.This paper aims to investigate lower limb impact biomechanics in real-world car to pedestrian accidents and to predict fractures of long bones in term of stress parameter for femur,tibia,and fibula.For the above purposes,a 3D finite element(FE) model of human body lower limb(HBM-LL) is developed based on human anatomy.The model consists of the pelvis,femur,tibia,fibula,patella,foot bones,primary tendons,knee joint capsule,meniscus,and ligaments.The FE model is validated by comparing the results from a lateral impact between simulations and tests with cadaver lower limb specimens.Two real-world accidents are selected from an in-depth accident database with detailed information about the accident scene,car impact speed,damage to the car,and pedestrian injuries.Multi-body system(MBS) models are used to reconstruct the kinematics of the pedestrians in the two accidents and the impact conditions are calculated for initial impact velocity and orientations of the car and pedestrian during the collision.The FE model is used to perform injury reconstructions and predict the fractures by using physical parameters,such as von Mises stress of long bones.The calculated failure level of the long bones is correlated with the injury outcomes observed from the two accident cases.The reconstruction result shows that the HBM-LL FE model has acceptable biofidelity and can be applied to predict the risk of long bone fractures.This study provides an efficient methodology to investigate the long bone fracture suffered from vehicle traffic collisions.
基金Project supported by the National Natural Science Foundation of China (Grant No. 10572084)Shanghai Leading Academic Discipline Project (Grant No. Y0103)
文摘The three-dimensional vortical structures for an impinging transverse jet in the near region were numerically investigated by means of Large-Eddy Simulation （LES）. The LES results reproduced the skewed jet shear layer vortices close to the jet nozzle and the scarf vortex in the near-wall zone in good agreement with the experimental observations. Different vortical modes in the skewed jet shear layer close to the jet nozzle were identified depending upon the velocity ratio between jet and crossflow, namely changing from an approximately axisymmetric mode to a helical one with the velocity ratios varying from 20 to 8. Moreover, the scarf vortex wrapped around the impinging jet in the near-wall zone showed distinct asymmetry with regard to its bilateral spiral legs within the near region. And the entrainment of the ambient crossflow fluids by the scarf vortex in the near-wall zone was appreciably influenced by its asymmetry and in a large part occurred on the surface of the spiral roller structures in the course of spreading downstream.
基金This study was financially supported by the National Natural Science Foundation of China(Grants 11374353,11204390 and 11274149)the Fundamental Research Funds for the Central Universities(CQDXWL-2013-009)+1 种基金the Program of Shenyang Key Laboratory of Optoelectronic Materials and Technology(F12-254-1-00)Special Fund for Agro-scientific Research in the Public Interest(NO.201303045).
文摘Due to its amazing ability to manipulate light at the nanoscale,plasmonics has become one of the most interesting topics in the field of light–matter interaction.As a promising application of plasmonics,surface-enhanced Raman scattering(SERS)has been widely used in scientific investigations and material analysis.The large enhanced Raman signals are mainly caused by the extremely enhanced electromagnetic field that results from localized surface plasmon polaritons.Recently,a novel SERS technology called remote SERS has been reported,combining both localized surface plasmon polaritons and propagating surface plasmon polaritons(PSPPs,or called plasmonic waveguide),which may be found in prominent applications in special circumstances compared to traditional local SERS.In this article,we review the mechanism of remote SERS and its development since it was first reported in 2009.Various remote metal systems based on plasmonic waveguides,such as nanoparticle–nanowire systems,single nanowire systems,crossed nanowire systems and nanowire dimer systems,are introduced,and recent novel applications,such as sensors,plasmon-driven surface-catalyzed reactions and Raman optical activity,are also presented.Furthermore,studies of remote SERS in dielectric and organic systems based on dielectric waveguides remind us that this useful technology has additional,tremendous application prospects that have not been realized in metal systems.
基金This work was supported by the Swedish Research Council(2015-04853,2016-06146,2019-04683)the Swedish Research Council Formas,the Knut and Alice Wallenberg Foundation(2017.0186,2016.0059)+5 种基金the Open Fund of the State Key Laboratory of Luminescent Materials and Devices(South China University of Technology,2020-skllmd-07)E.Moons thanks the Swedish Energy Council for financial support(project 48598-1)W.Su thanks the project funded by China Postdoctoral Science Foundation(2020M673054)Postdoctoral Fund of Jinan University,and the National Natural Science Foundation of China(22005121)L.Hou thanks the National Natural Science Foundation of China(61774077)Support from Sino-Danish Centre for Education and Research is fully acknowledged by D.Yu.Y.Li thanks the financial support from the Science and Technology Program of Shanxi Province(2019JQ-244).
文摘The non-fully conjugated polymer as a new class of acceptor materials has shown some advantages over its small molecular counterpart when used in photoactive layers for all-polymer solar cells(all-PSCs),despite a low power conversion efficiency(PCE)caused by its narrow absorption spectra.Herein,a novel non-fully conjugated polymer acceptor PFY-2TS with a low bandgap of~1.40 eV was developed,via polymerizing a largeπ-fused small molecule acceptor(SMA)building block(namely YBO)with a non-conjugated thioalkyl linkage.Compared with its precursor YBO,PFY-2TS retains a similar low bandgap but a higher LUMO level.Moreover,compared with the structural analog of YBO-based fully conjugated polymer acceptor PFY-DTC,PFY-2TS shows a similar absorption spectrum and electron mobility,but significantly different molecular crystallinity and aggregation properties,which results in optimal blend morphology with a polymer donor PBDB-T and physical processes of the device in all-PSCs.As a result,PFY-2TS-based all-PSCs achieved a PCE of 12.31%with a small energy loss of 0.56 eV enabled by the reduced non-radiative energy loss(0.24 eV),which is better than that of 11.08%for the PFY-DTC-based ones.Our work clearly demonstrated that non-fully conjugated polymers as a new class of acceptor materials are very promising for the development of high-performance all-PSCs.
基金supported by the National Natural Science Foundation of China(52221005,52220105001,52272420)European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie(101025896)。
文摘In current years,the improvement of deep learning has brought about tremendous changes:As a type of unsupervised deep learning algorithm,generative adversarial networks(GANs)have been widely employed in various fields including transportation.This paper reviews the development of GANs and their applications in the transportation domain.Specifically,many adopted GAN variants for autonomous driving are classified and demonstrated according to data generation,video trajectory prediction,and security of detection.To introduce GANs to traffic research,this review summarizes the related techniques for spatio-temporal,sparse data completion,and time-series data evaluation.GAN-based traffic anomaly inspections such as infrastructure detection and status monitoring are also assessed.Moreover,to promote further development of GANs in intelligent transportation systems(ITSs),challenges and noteworthy research directions on this topic are provided.In general,this survey summarizes 130 GAN-related references and provides comprehensive knowledge for scholars who desire to adopt GANs in their scientific works,especially transportation-related tasks.
文摘Human driven vehicles(HDVs)with selfish objectives cause low traffic efficiency in an un-signalized intersection.On the other hand,autonomous vehicles can overcome this inefficiency through perfect coordination.In this paper,we propose an intermediate solution,where we use vehicular communication and a small number of autonomous vehicles to improve the transportation system efficiency in such intersections.In our solution,two connected autonomous vehicles(CAVs)lead multiple HDVs in a double-lane intersection in order to avoid congestion in front of the intersection.The CAVs are able to communicate and coordinate their behavior,which is controlled by a deep reinforcement learning(DRL)agent.We design an altruistic reward function which enables CAVs to adjust their velocities flexibly in order to avoid queuing in front of the intersection.The proximal policy optimization(PPO)algorithm is applied to train the policy and the generalized advantage estimation(GAE)is used to estimate state values.Training results show that two CAVs are able to achieve significantly better traffic efficiency compared to similar scenarios without and with one altruistic autonomous vehicle.
基金the National key R&D projects(Nos.2019YFC1907101,2019YFC1907103,2017YFB0702304)the Key R&D project in Ningxia Hui Autonomous Region(No.2020BCE01001)+5 种基金the National Natural Science Foundation of China(No.51672024)the Xijiang Innovation and Entrepreneurship Team(No.2017A0109004)the Program of China Scholarships Coun-cil(No.201806465040)the Fundamental Research Funds for the Central Universities(Nos.FRF-IC-19-007,FRF-IC-19-017Z,FRF-MP-19-002,FRF-TP-19-003B1,FRF-GF-19-032B,and 06500141)the State Key Laboratory for Ad-vanced Metals and Materials(No.2019Z-05)the Integ-ration of Green Key Process Systems MIIT.
文摘Municipal solid waste incineration products of bottom ash(BA),fly ash(FA),and pickling sludge(PS),causing severe environ-mental pollution,were transformed into glass ceramic foams with the aid of CaCO3 as a pore-foaming agent during sintering.The effect of the BA/FA mass ratio on the phase composition,pore morphology,pore size distribution,physical properties,and glass structure was investigated,with results showing that with the increase in the BA/FA ratio,the content of the glass phase,Si-O-Si,and Q3Si units decrease gradually.The glass transmission temperature of the mixture was also reduced.When combined,the glass viscosity decreases,causing bubble coalescence and uneven pore distribution.Glass ceramic foams with uniform spherical pores are fabricated.When the content of BA,FA,and PS are 35wt%,45wt%,and 20wt%,respectively,contributing to high performance glass ceramic foams with a bulk density of 1.76 g/cm3,porosity of 56.01%,and compressive strength exceeding 16.23 MPa.This versatile and low-cost approach provides new insight into synergistically recycling solid wastes.
基金This work was supported by the VINNOVA through the RoughProp project(Grant No.2018-04085).The experimental measurements are conducted in the free surface cavitation tunnel at the Kongsberg Hydrodynamic Research Center,Kristinehamn,Sweden.
文摘This study presents results of experiments where roughness applications are evaluated in delaying the tip vortex cavitation inception of an elliptical foil.High-speed video recordings and laser doppler velocimetry(LDV)measurements are employed to provide further details on the cavitation behavior and tip vortex flow properties in different roughness pattern configurations.The angular momentum measurements of the vortex core region at one chord length downstream of the tip indicate that roughness leads to a lower angular momentum compared with the smooth foil condition while the vortex core radius remains similar in the smooth and roughened conditions.The observations show that the cavitation number for tip vortex cavitation inception is reduced by 33%in the optimized roughness pattern compared with the smooth foil condition where the drag force increase is observed to be around 2%.During the tests,no obvious differences in the cavitation inception properties of uniform and non-uniform roughness distributions are observed.However,the drag force is found to be higher with a non-uniform roughness distribution.
文摘Dramatic fall in costs of renewable energy in the last 24 months has not only accelerated the replacement of fossil fuels by renewable energy in electricity generation. The low cost renewable electricity is now starting to replace fossil fuels in other sectors. One reason is that renewable electricity is now cheaper per unit energy than oil, about the same price as fossil methan but, still, more expensive than coal. Another reason is that electricity often offer other opportunities, such as cheaper transport, better control, higher energy efficiency in final production of energy services and lower local environmental costs.
