3 mm thick 400 MPa grade ultrafine grained ferritic steel plates were bead-on-plate welded by CO2 laser with heat input of 120-480 J/mm. The microstructures of the weld metal mainly consist of bainite, which form is l...3 mm thick 400 MPa grade ultrafine grained ferritic steel plates were bead-on-plate welded by CO2 laser with heat input of 120-480 J/mm. The microstructures of the weld metal mainly consist of bainite, which form is lower bainite plates or polygonal ferrite containing quantities of dispersed cementite particles, mixed with a few of low carbon martensite laths or ferrite, depending on the heat input. The hardness and the tensile strength of the weld metal are higher than those of the base metal, and monotonously increase as the heat input decreases. No softened zone exists in heat affected zone (HAZ). Compared with the base metal, although the grains of laser weld are much larger, the toughness of the weld metal is higher within a large range of heat input. Furthermore, as the heat input increases, the toughness of the weld metal rises to a maximum value, at which point the percentage of lower bainite is the highest, and then drops.展开更多
The influence of three important operation parameters in Jinlong flashsmelting furnace, including the distributing blast speed, the oxygen enrichment rate of process airand the ratio of central oxygen to overall oxyge...The influence of three important operation parameters in Jinlong flashsmelting furnace, including the distributing blast speed, the oxygen enrichment rate of process airand the ratio of central oxygen to overall oxygen (O_c/O_o), has been investigated using a virtualsimulation system on copper flash smelting furnace. The core of this virtual simulation system is anumerical simulation of CFD (computational fluid dynamics), and this system incorporates couplingmomentum transport, heat transport, mass transport, reaction kinetics between gas and particles andchemical reactions between gas and gas. A set of numerical predicted data were obtained. The CFDsimulation shows that there is a sensitive zone of the distributing blast speed, and the dustcontent ascends when the speed exceeds 180 m centre dot s^(-1). Increasing the oxygen concentrationof processing air benefits the efficient production of the flash smelting furnace.展开更多
The Ti-48Al alloy was pack siliconized with 15%Si+85%Al2O3. The microstructure of the siliconized coating on the TiAl-based alloy was analyzed and its effect on oxidation resistance was investigated. The specimens bef...The Ti-48Al alloy was pack siliconized with 15%Si+85%Al2O3. The microstructure of the siliconized coating on the TiAl-based alloy was analyzed and its effect on oxidation resistance was investigated. The specimens before and after cycle oxidation were examined by XRD and SEM equipped with XEDS. The results showed that the coating is composed of a thin Al2O3 outer layer and a composite inner layer of Ti5Si3 with an appropriate amount of Al2O3 dispersed in. Cycle oxidation tests showed that the high temperature oxidation resistance of TiAl-based alloy was greatly improved by forming such composite coating. No spaliation and crack happened and the weight gain was very small after cycle oxidation at 900℃ for 314h.展开更多
The effects of operation parameters of combined blowing converter on the volumetric mass transfer coefficient between slag and steel are studied with a cold model with water simulating steel, oil simulating slag and b...The effects of operation parameters of combined blowing converter on the volumetric mass transfer coefficient between slag and steel are studied with a cold model with water simulating steel, oil simulating slag and benzoic acid as the transferred substance between water and oil. The results show that, with lance level of 2.1m and the top blowing rate of 25000Nm3/h, the volumetric mass transfer coefficient changes most significantly when the bottom blowing rate ranges from 384 to 540Nm3/h. The volumetric mass transfer coefficient reaches its maximum when the lance level is 2.1m, the top blowing rates is 30000Nm3/h, and the bottom blowing rate is 384Nm3/h with tuyeres located symmetrically at 0.66D of the converter bottom.展开更多
The hardness, tensile strength and impact toughness of one quenched andtempered steel with nominal composition of Fe-0.25C-3.0Cr-3.0Mo-0.6Ni-0.1Nb (mass fraction) both atroom temperature and at elevated temperatures w...The hardness, tensile strength and impact toughness of one quenched andtempered steel with nominal composition of Fe-0.25C-3.0Cr-3.0Mo-0.6Ni-0.1Nb (mass fraction) both atroom temperature and at elevated temperatures were investigated in order to develop high-strengthsteel for long-life gun barrel use. It is found that the steel has lower decrease rate of tensilestrength at elevated temperature in comparison with the commonly used G4335V high-strength gunsteel, which contains higher Ni and lower Cr and Mo contents. The high elevated-temperature strengthof the steel is attributed to the strong secondary hardening effect and high tempering softeningresistance caused by the tempering precipitation of fine Mo-rich M_2C carbides in the α-Fe matrix.The experimental steel is not susceptible to secondary hardening embrittlement, meanwhile, itsroom-temperature impact energy is much higher than the normal requirement of impact toughness forhigh strength gun steels. Therefore, the steel is suitable for production of long-life high-strengthgun barrels with the combination of superior elevated-temperature strength and good impacttoughness.展开更多
The giant magnetoimpedance effect of the nanocrystalline ribbonFe_(84)Zr_(2.08)Nb_(1.92)Cu_1B_(11) (atom fraction in %) was investigated. There is an optimumannealing temperature (T_A≈ 998 K) for obtaining the larges...The giant magnetoimpedance effect of the nanocrystalline ribbonFe_(84)Zr_(2.08)Nb_(1.92)Cu_1B_(11) (atom fraction in %) was investigated. There is an optimumannealing temperature (T_A≈ 998 K) for obtaining the largest GMI (giant magneto-impedance) effectin the ribbon Fe_(84)Zr_(2.08)Nb_(1.92)Cu_1B_(11). The ribbon with longer ribbon length has strongerGMI effect, which may be connected with the demagnetization effect of samples. The frequencyf_(max), where the maximum magnetoimpedance GMI(Z)_(max) = [(Z(H) - Z(0))/Z(0)]_(max) occurs, isnear the intersecting frequency f_i of the curves of GMI(R), GMI(X), and GMI(Z) versus frequency.The magnetoreactance GMI(X) decreases monotonically with increasing frequency, which may be due tothe decrease of permeability. In contrast, with the AC (alternating current) frequency increasing,the inagnetore-sistance GMI(R) increases at first, undergoes a peak, and under then drops. Theincrease of the magnetoresistance may result from the enhancement of the skin effect with frequency.The maximum magnetoimpedance value GMI(Z)_(max) under H = 7.2 kA/m is about -56.18% at f= 0.3 MHzfor the nanocrystalline ribbon Fe_(84)Zr_(2.08)Nb_(1.92)Cu_1B_(11) with the annealing temperatureT_A= 998 K and the ribbon length L = 6 cm.展开更多
The method consisting of cold test and hot simulating has been proved to be reliable for designing permeable ele-ments.The carbon-magnesia multiple-tube permeable ele-ments which are formed by isostatical pressure ha...The method consisting of cold test and hot simulating has been proved to be reliable for designing permeable ele-ments.The carbon-magnesia multiple-tube permeable ele-ments which are formed by isostatical pressure have higher density,high heat resistance and good thermoshock resis-tance,The brickwork ,maintenance and erosion meha-nism of permeable elements were studied.The tehnology of combined blowing wa established based on the peculiari-ties of semi-steel refining at Panzhihua Irom& Steel Co.(PZISC).The service life of permeable elements reahed 600 heats,that means the permeable elements can work synchronitially with converter lining.展开更多
The first imported off-gas analysis system on 150 t BOF at Benxi Plates Co.Ltd. is presented and the continuous determination of bath carbon content has been studied. Thecomparison between the whole-course carbon inte...The first imported off-gas analysis system on 150 t BOF at Benxi Plates Co.Ltd. is presented and the continuous determination of bath carbon content has been studied. Thecomparison between the whole-course carbon integral model and the end-point carbon prediction modelhas been made. The results show that the regular change of CO, CO_2 and N_2 content in the off-gasduring blowing plays an important role in judging the smelting end-point of converter; the cubiccurve fitting model has a higher hit rate over 95 percent for the heats whose end-point carboncontent is lower than 0.10 percent with a precision of +-0.02 percent and has a large error for theheats whose end-point carbon content is more than 0.15 percent.展开更多
The giant magnetoimpedance(GMI)effect in as-quenchedFe_89-xZr_7B_4Cu_x(x=1.0-2.5)ribbons is reported. The as-quenchedFe_89-xZr_7B_4Cu_x(x=1.0-2.5)ribbons were prepared by the vacuummelt-spun processes with the quenchi...The giant magnetoimpedance(GMI)effect in as-quenchedFe_89-xZr_7B_4Cu_x(x=1.0-2.5)ribbons is reported. The as-quenchedFe_89-xZr_7B_4Cu_x(x=1.0-2.5)ribbons were prepared by the vacuummelt-spun processes with the quenching speed of 37 m/s. The magne-Toimpedance measurement were performance at room temperature, wherethe current flow through the length of the ribbons in the directionParallel to the dc fields. results show that values Z(impedance),R(resistance)for both H = 0 A/m and H = 5 127 A/m Increases withincreasing ac frequency. This can be explained by the skin effectmechanism.展开更多
The mechanical properties of pressureless sintering Fe-Si_ 3N_ 4 bonded SiC and Si_ 3N_ 4 bonded SiC with same manufacture process have been compared in this paper. The oxidizing mechanism of Fe-Si_ 3N_ 4 bonded...The mechanical properties of pressureless sintering Fe-Si_ 3N_ 4 bonded SiC and Si_ 3N_ 4 bonded SiC with same manufacture process have been compared in this paper. The oxidizing mechanism of Fe-Si_ 3N_ 4 bonded SiC ceramic matrix composite has been investigated especially through TG-DSC (thermo gravimetric analysis-differential scanning calorimeter) experiment. During oxidation procedure the main reaction is the oxidation of SiC and Si_ 3N_ 4, SiO_ 2 which form protecting film to prevent further oxidizing. And residual iron in the samples become Fe_ 2O_ 3 and Fe_ 3O_ 4,_ the oxidation kinetics at 1100~1300℃ of Fe-Si_ 3N_ 4 bonded SiC has been studied especially. The weight gain per unit area at initial stage changes according to beeline rule, in the middle according to conic, and in the last oxidation period follows parabola rule.展开更多
The liquid structure of pure iron at 1540, 1560 and 1580 deg C was studied byX-ray diffraction. The results show that near the melting point there is a medium-range orderstructure that fades away with the increasing t...The liquid structure of pure iron at 1540, 1560 and 1580 deg C was studied byX-ray diffraction. The results show that near the melting point there is a medium-range orderstructure that fades away with the increasing temperature. The average nearest distance of atoms isalmost independent of the melts temperature, but the average coordination number, the atom clustersize and the atom number in an atom cluster all decrease with the increasing temperature of themelt. Near the melting point there are a lot of atom clusters in the pure iron melt. The atomcluster of pure iron has the body-centered cubic lattices, which are kept from the solid state. Andthe body-centered cubic lattices connect into network by occupying a same edge. The atoms in thesurrounding of the atom clusters are arranged disorderly.展开更多
Carbon-containing refiactories are easily oxidized at high tenperature,thus making service life rapidly drop.The anti-oxidation methods,such as impregnation and adding anti-oxidaton agents,can't meet the require-m...Carbon-containing refiactories are easily oxidized at high tenperature,thus making service life rapidly drop.The anti-oxidation methods,such as impregnation and adding anti-oxidaton agents,can't meet the require-ments of industry's development and some special cases, By analyzing the charcteristics of several oxides and non-oxides raw maerials,the oxidation resistant mechanism of the refractory anti-oxidation coatings(RAOC),which possess the characteristc of self-healing at hight temperature,is discussed.展开更多
This paper describes the resisting ability of gunning material for blast furnace to carbon monoxide corrosion under the mixed gas condition through inletting hydrogen into pure CO . A standard for testing ike resistin...This paper describes the resisting ability of gunning material for blast furnace to carbon monoxide corrosion under the mixed gas condition through inletting hydrogen into pure CO . A standard for testing ike resisting ability of refractory to CO corrosion with mixed gas instead of pure CO has also been discussed. The results show : the addition of hydrogen accelerates the CO corrosion on gunning material ; the same results has been reached with the CO , 200 hours and CO 95 % + H2 5 % , 24 hours. It is reasonable to use CO 95% + H25% , 24 hours instead of pure CO, 200 hours to lest the resisting ability of refractory to carbon monoxide corrosion.展开更多
Based on introducing the quasi-parabolid rule,which indicates the relation of Gibbs free energy of formation of compounds and its compostitions,the Gibbs free energes of formation of Sialons (O'-and X-phases) were...Based on introducing the quasi-parabolid rule,which indicates the relation of Gibbs free energy of formation of compounds and its compostitions,the Gibbs free energes of formation of Sialons (O'-and X-phases) were estimated.展开更多
The coercivity mechanism of Nd-Fe-B based magnets prepared by a new techniqueof strip casting was investigated. Different from the traditional magnets, α-Fe phases aredifficult to be found in Nd-Fe-B magnets prepared...The coercivity mechanism of Nd-Fe-B based magnets prepared by a new techniqueof strip casting was investigated. Different from the traditional magnets, α-Fe phases aredifficult to be found in Nd-Fe-B magnets prepared by strip casting. Meanwhile, the rich-Nd phasesoccur not only near the grain boundaries of main phases, but also within the main-phase grains.Investigation on the magnetizing field dependence of the coercivity for the(Nd_(0.935)Dy_(0.065))_(14.5)Fe_(79.4)B_(6.1) magnet and the temperature dependence of thecoercivity for the Nd_(14.5)Fe_(79.4)B_(6.1) magnet hav been done. Results show that coercivitiesfor strip casting magnets are controlled by the nucleation mechanism.展开更多
The Ni-Al alloy containing Cr,Fe additives were prepared as Raney Ni Catalyst by high energy milling.The size and surface state of Ni-Al alloy powder were studied by particle size analyzer and sanning electron microsc...The Ni-Al alloy containing Cr,Fe additives were prepared as Raney Ni Catalyst by high energy milling.The size and surface state of Ni-Al alloy powder were studied by particle size analyzer and sanning electron microscopy.the Structure was analyzed by XRD and Moessbauer methods.The results showed that after a high-energy milling(HEM).the Ni-Al alloy transforms to a nano-scale NiAl structure with rich Al.By annealing the alloy,a metastable Ni2Al3 phase can be obtained.展开更多
基金This work was supported by the‘973'ScienceTechnology Development Plan of the National Basic Research Foundation(No.1998061500)the 985'Foundation of Tsinghua University.
文摘3 mm thick 400 MPa grade ultrafine grained ferritic steel plates were bead-on-plate welded by CO2 laser with heat input of 120-480 J/mm. The microstructures of the weld metal mainly consist of bainite, which form is lower bainite plates or polygonal ferrite containing quantities of dispersed cementite particles, mixed with a few of low carbon martensite laths or ferrite, depending on the heat input. The hardness and the tensile strength of the weld metal are higher than those of the base metal, and monotonously increase as the heat input decreases. No softened zone exists in heat affected zone (HAZ). Compared with the base metal, although the grains of laser weld are much larger, the toughness of the weld metal is higher within a large range of heat input. Furthermore, as the heat input increases, the toughness of the weld metal rises to a maximum value, at which point the percentage of lower bainite is the highest, and then drops.
文摘The influence of three important operation parameters in Jinlong flashsmelting furnace, including the distributing blast speed, the oxygen enrichment rate of process airand the ratio of central oxygen to overall oxygen (O_c/O_o), has been investigated using a virtualsimulation system on copper flash smelting furnace. The core of this virtual simulation system is anumerical simulation of CFD (computational fluid dynamics), and this system incorporates couplingmomentum transport, heat transport, mass transport, reaction kinetics between gas and particles andchemical reactions between gas and gas. A set of numerical predicted data were obtained. The CFDsimulation shows that there is a sensitive zone of the distributing blast speed, and the dustcontent ascends when the speed exceeds 180 m centre dot s^(-1). Increasing the oxygen concentrationof processing air benefits the efficient production of the flash smelting furnace.
文摘The Ti-48Al alloy was pack siliconized with 15%Si+85%Al2O3. The microstructure of the siliconized coating on the TiAl-based alloy was analyzed and its effect on oxidation resistance was investigated. The specimens before and after cycle oxidation were examined by XRD and SEM equipped with XEDS. The results showed that the coating is composed of a thin Al2O3 outer layer and a composite inner layer of Ti5Si3 with an appropriate amount of Al2O3 dispersed in. Cycle oxidation tests showed that the high temperature oxidation resistance of TiAl-based alloy was greatly improved by forming such composite coating. No spaliation and crack happened and the weight gain was very small after cycle oxidation at 900℃ for 314h.
文摘The effects of operation parameters of combined blowing converter on the volumetric mass transfer coefficient between slag and steel are studied with a cold model with water simulating steel, oil simulating slag and benzoic acid as the transferred substance between water and oil. The results show that, with lance level of 2.1m and the top blowing rate of 25000Nm3/h, the volumetric mass transfer coefficient changes most significantly when the bottom blowing rate ranges from 384 to 540Nm3/h. The volumetric mass transfer coefficient reaches its maximum when the lance level is 2.1m, the top blowing rates is 30000Nm3/h, and the bottom blowing rate is 384Nm3/h with tuyeres located symmetrically at 0.66D of the converter bottom.
文摘The hardness, tensile strength and impact toughness of one quenched andtempered steel with nominal composition of Fe-0.25C-3.0Cr-3.0Mo-0.6Ni-0.1Nb (mass fraction) both atroom temperature and at elevated temperatures were investigated in order to develop high-strengthsteel for long-life gun barrel use. It is found that the steel has lower decrease rate of tensilestrength at elevated temperature in comparison with the commonly used G4335V high-strength gunsteel, which contains higher Ni and lower Cr and Mo contents. The high elevated-temperature strengthof the steel is attributed to the strong secondary hardening effect and high tempering softeningresistance caused by the tempering precipitation of fine Mo-rich M_2C carbides in the α-Fe matrix.The experimental steel is not susceptible to secondary hardening embrittlement, meanwhile, itsroom-temperature impact energy is much higher than the normal requirement of impact toughness forhigh strength gun steels. Therefore, the steel is suitable for production of long-life high-strengthgun barrels with the combination of superior elevated-temperature strength and good impacttoughness.
基金This work was financially supported by the National Natural Science Foundation of China (No. 50271036)
文摘The giant magnetoimpedance effect of the nanocrystalline ribbonFe_(84)Zr_(2.08)Nb_(1.92)Cu_1B_(11) (atom fraction in %) was investigated. There is an optimumannealing temperature (T_A≈ 998 K) for obtaining the largest GMI (giant magneto-impedance) effectin the ribbon Fe_(84)Zr_(2.08)Nb_(1.92)Cu_1B_(11). The ribbon with longer ribbon length has strongerGMI effect, which may be connected with the demagnetization effect of samples. The frequencyf_(max), where the maximum magnetoimpedance GMI(Z)_(max) = [(Z(H) - Z(0))/Z(0)]_(max) occurs, isnear the intersecting frequency f_i of the curves of GMI(R), GMI(X), and GMI(Z) versus frequency.The magnetoreactance GMI(X) decreases monotonically with increasing frequency, which may be due tothe decrease of permeability. In contrast, with the AC (alternating current) frequency increasing,the inagnetore-sistance GMI(R) increases at first, undergoes a peak, and under then drops. Theincrease of the magnetoresistance may result from the enhancement of the skin effect with frequency.The maximum magnetoimpedance value GMI(Z)_(max) under H = 7.2 kA/m is about -56.18% at f= 0.3 MHzfor the nanocrystalline ribbon Fe_(84)Zr_(2.08)Nb_(1.92)Cu_1B_(11) with the annealing temperatureT_A= 998 K and the ribbon length L = 6 cm.
文摘The method consisting of cold test and hot simulating has been proved to be reliable for designing permeable ele-ments.The carbon-magnesia multiple-tube permeable ele-ments which are formed by isostatical pressure have higher density,high heat resistance and good thermoshock resis-tance,The brickwork ,maintenance and erosion meha-nism of permeable elements were studied.The tehnology of combined blowing wa established based on the peculiari-ties of semi-steel refining at Panzhihua Irom& Steel Co.(PZISC).The service life of permeable elements reahed 600 heats,that means the permeable elements can work synchronitially with converter lining.
文摘The first imported off-gas analysis system on 150 t BOF at Benxi Plates Co.Ltd. is presented and the continuous determination of bath carbon content has been studied. Thecomparison between the whole-course carbon integral model and the end-point carbon prediction modelhas been made. The results show that the regular change of CO, CO_2 and N_2 content in the off-gasduring blowing plays an important role in judging the smelting end-point of converter; the cubiccurve fitting model has a higher hit rate over 95 percent for the heats whose end-point carboncontent is lower than 0.10 percent with a precision of +-0.02 percent and has a large error for theheats whose end-point carbon content is more than 0.15 percent.
文摘The giant magnetoimpedance(GMI)effect in as-quenchedFe_89-xZr_7B_4Cu_x(x=1.0-2.5)ribbons is reported. The as-quenchedFe_89-xZr_7B_4Cu_x(x=1.0-2.5)ribbons were prepared by the vacuummelt-spun processes with the quenching speed of 37 m/s. The magne-Toimpedance measurement were performance at room temperature, wherethe current flow through the length of the ribbons in the directionParallel to the dc fields. results show that values Z(impedance),R(resistance)for both H = 0 A/m and H = 5 127 A/m Increases withincreasing ac frequency. This can be explained by the skin effectmechanism.
文摘The mechanical properties of pressureless sintering Fe-Si_ 3N_ 4 bonded SiC and Si_ 3N_ 4 bonded SiC with same manufacture process have been compared in this paper. The oxidizing mechanism of Fe-Si_ 3N_ 4 bonded SiC ceramic matrix composite has been investigated especially through TG-DSC (thermo gravimetric analysis-differential scanning calorimeter) experiment. During oxidation procedure the main reaction is the oxidation of SiC and Si_ 3N_ 4, SiO_ 2 which form protecting film to prevent further oxidizing. And residual iron in the samples become Fe_ 2O_ 3 and Fe_ 3O_ 4,_ the oxidation kinetics at 1100~1300℃ of Fe-Si_ 3N_ 4 bonded SiC has been studied especially. The weight gain per unit area at initial stage changes according to beeline rule, in the middle according to conic, and in the last oxidation period follows parabola rule.
基金This work was financially supported by the National Natural Science Foundation of China (No.59974003)"973" Research Foundation of the Science and Technology Ministry of China (No. G199806150402)
文摘The liquid structure of pure iron at 1540, 1560 and 1580 deg C was studied byX-ray diffraction. The results show that near the melting point there is a medium-range orderstructure that fades away with the increasing temperature. The average nearest distance of atoms isalmost independent of the melts temperature, but the average coordination number, the atom clustersize and the atom number in an atom cluster all decrease with the increasing temperature of themelt. Near the melting point there are a lot of atom clusters in the pure iron melt. The atomcluster of pure iron has the body-centered cubic lattices, which are kept from the solid state. Andthe body-centered cubic lattices connect into network by occupying a same edge. The atoms in thesurrounding of the atom clusters are arranged disorderly.
文摘Carbon-containing refiactories are easily oxidized at high tenperature,thus making service life rapidly drop.The anti-oxidation methods,such as impregnation and adding anti-oxidaton agents,can't meet the require-ments of industry's development and some special cases, By analyzing the charcteristics of several oxides and non-oxides raw maerials,the oxidation resistant mechanism of the refractory anti-oxidation coatings(RAOC),which possess the characteristc of self-healing at hight temperature,is discussed.
文摘This paper describes the resisting ability of gunning material for blast furnace to carbon monoxide corrosion under the mixed gas condition through inletting hydrogen into pure CO . A standard for testing ike resisting ability of refractory to CO corrosion with mixed gas instead of pure CO has also been discussed. The results show : the addition of hydrogen accelerates the CO corrosion on gunning material ; the same results has been reached with the CO , 200 hours and CO 95 % + H2 5 % , 24 hours. It is reasonable to use CO 95% + H25% , 24 hours instead of pure CO, 200 hours to lest the resisting ability of refractory to carbon monoxide corrosion.
文摘Based on introducing the quasi-parabolid rule,which indicates the relation of Gibbs free energy of formation of compounds and its compostitions,the Gibbs free energes of formation of Sialons (O'-and X-phases) were estimated.
基金This work is supported by the National Natural Science Foundation of China (No. 50271036).
文摘The coercivity mechanism of Nd-Fe-B based magnets prepared by a new techniqueof strip casting was investigated. Different from the traditional magnets, α-Fe phases aredifficult to be found in Nd-Fe-B magnets prepared by strip casting. Meanwhile, the rich-Nd phasesoccur not only near the grain boundaries of main phases, but also within the main-phase grains.Investigation on the magnetizing field dependence of the coercivity for the(Nd_(0.935)Dy_(0.065))_(14.5)Fe_(79.4)B_(6.1) magnet and the temperature dependence of thecoercivity for the Nd_(14.5)Fe_(79.4)B_(6.1) magnet hav been done. Results show that coercivitiesfor strip casting magnets are controlled by the nucleation mechanism.
文摘The Ni-Al alloy containing Cr,Fe additives were prepared as Raney Ni Catalyst by high energy milling.The size and surface state of Ni-Al alloy powder were studied by particle size analyzer and sanning electron microscopy.the Structure was analyzed by XRD and Moessbauer methods.The results showed that after a high-energy milling(HEM).the Ni-Al alloy transforms to a nano-scale NiAl structure with rich Al.By annealing the alloy,a metastable Ni2Al3 phase can be obtained.