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Deuteron electromagnetic form factors and tensor polarization observables in the framework of the hard-wall AdS/QCD model
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作者 Narmin Huseynova Shahin Mamedov Jannat Samadov 《Chinese Physics C》 SCIE CAS CSCD 2023年第1期55-62,共8页
We study the electromagnetic form factors and tensor polarization observables of the deuteron in the framework of the hard-wall AdS/QCD model.We find a profile function for the bulk twistτ=6 vector field,which descri... We study the electromagnetic form factors and tensor polarization observables of the deuteron in the framework of the hard-wall AdS/QCD model.We find a profile function for the bulk twistτ=6 vector field,which describes the deuteron on the boundary and fix the infrared boundary cut-off of AdS space in accordance with the ground state mass of the deuteron.We obtain the deuteron charge monopole,quadrupole,and magnetic dipole form factors and tensor polarization observables from the bulk Lagrangians for the deuteron and photon field interactions.We plot the momentum transfer dependence of the form factors and tensor polarization observables and compare our numerical results with those in the soft-wall model and experimental data. 展开更多
关键词 DEUTERON electromagnetic form factors structure functions tensor polarization observables hard-wall model
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Generalised tanh-shaped hyperbolic potential: Klein–Gordon equation's bound state solution
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作者 V H Badalov S V Badalov 《Communications in Theoretical Physics》 SCIE CAS CSCD 2023年第7期22-32,共11页
The development of potential theory heightens the understanding of fundamental interactions in quantum systems.In this paper,the bound state solution of the modified radial Klein–Gordon equation is presented for gene... The development of potential theory heightens the understanding of fundamental interactions in quantum systems.In this paper,the bound state solution of the modified radial Klein–Gordon equation is presented for generalised tanh-shaped hyperbolic potential from the Nikiforov–Uvarov method.The resulting energy eigenvalues and corresponding radial wave functions are expressed in terms of the Jacobi polynomials for arbitrary l states.It is also demonstrated that energy eigenvalues strongly correlate with potential parameters for quantum states.Considering particular cases,the generalised tanh-shaped hyperbolic potential and its derived energy eigenvalues exhibit good agreement with the reported findings.Furthermore,the rovibrational energies are calculated for three representative diatomic molecules,namely H2,HCl and O2.The lowest excitation energies are in perfect agreement with experimental results.Overall,the potential model is displayed to be a viable candidate for concurrently prescribing numerous quantum systems. 展开更多
关键词 Klein-Gordon equation hyperbolic potential Nikiforov-Uvarov method diatomic molecules
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The Discrete-Analytical Solution Method for Investigation Dynamics of the Sphere with Inhomogeneous Initial Stresses 被引量:2
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作者 Surkay D.Akbarov Hatam H.Guliyev +1 位作者 Yusif M.Sevdimaliyev Nazmiye Yahnioglu 《Computers, Materials & Continua》 SCIE EI 2018年第5期359-380,共22页
The paper deals with a development of the discrete-analytical method for the solution of the dynamical problems of a hollow sphere with inhomogeneous initial stresses.The examinations are made with respect to the prob... The paper deals with a development of the discrete-analytical method for the solution of the dynamical problems of a hollow sphere with inhomogeneous initial stresses.The examinations are made with respect to the problem on the natural vibration of the hollow sphere the initial stresses in which is caused by internal and external uniformly distributed pressure.The initial stresses in the sphere are determined within the scope of the exact equations of elastostatics.It is assumed that after appearing this static initial stresses the sphere gets a dynamical excitation and mechanical behavior of the sphere caused by this excitation is described with the so-called three-dimensional linearized equations of elastic wave propagation in initially stressed bodies.For the solution of these equations,which have variable coefficients,the discrete analytical solution method is developed and applied.In particular,it is established that the convergence of the numerical results with respect to the number of discretization is very acceptable and applicable for the considered type dynamical problems.Numerical results on the influence of the initial stresses on the values of the natural frequencies of the hollow sphere are also presented and these results are discussed. 展开更多
关键词 Discrete-analytical solution method initial stress hollow sphere natural frequency dynamical problem
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Low temperature thermoluminescence behaviour of Y_2O_3 nanoparticles 被引量:4
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作者 S.Delice M.Isik N.M.Gasanly 《Journal of Rare Earths》 SCIE EI CAS CSCD 2019年第1期19-23,M0002,共6页
Y_2O_3 nanoparticles were investigated using low temperature thermoluminescence (TL) experiments. TL glow curve recorded at constant heating rate of 0.4 K/s exhibits seven peaks around 19, 62, 91,115,162,196 and 215 K... Y_2O_3 nanoparticles were investigated using low temperature thermoluminescence (TL) experiments. TL glow curve recorded at constant heating rate of 0.4 K/s exhibits seven peaks around 19, 62, 91,115,162,196 and 215 K. Activation energies and characteristics of traps responsible for observed curves were revealed under the light of results of initial rise analyses and T_(max)-T_(stop) experimental methods. Analyses of TL curves obtained at different stopping temperatures resulted in presence of one quasi-continuously distributed trap with activation energies increasing from 18 to 24 meV and six single trapping centers at49, 117, 315, 409, 651 and 740 meV. Activation energies of all revealed centers were reported in the present paper. Structural characterization of Y_2O_3 nanoparticles was accomplished using X-ray diffraction and scanning electron microscopy measurements. 展开更多
关键词 Y2O3 LUMINESCENCE THERMOLUMINESCENCE DEFECTS RARE earths
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Self-assembled patches in PtSi/n-Si(111)diodes 被引量:1
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作者 I.M.Afandiyeva S.Altιndal +1 位作者 L.K.Abdullayeva A.I.Bayramova 《Journal of Semiconductors》 EI CAS CSCD 2018年第5期41-47,共7页
Using the effect of the temperature on the capacitance–voltage(C–V)and conductance–voltage(G/ω–V)characteristics of PtSi/n-Si(111)Schottky diodes the profile of apparent doping concentrationthe potential di... Using the effect of the temperature on the capacitance–voltage(C–V)and conductance–voltage(G/ω–V)characteristics of PtSi/n-Si(111)Schottky diodes the profile of apparent doping concentrationthe potential difference between the Fermi energy level and the bottom of the conduction bandapparent barrier heightseries resistanceand the interface state density Nss have been investigated.From the temperature dependence of(C–V)it was found that these parameters are non-uniformly changed with increasing temperature in a wide temperature range of 79–360 K.The voltage and temperature dependences of apparent carrier distribution we attributed to the existence of self-assembled patches similar the quantum wells,which formed due to the process of Pt Si formation on semiconductor and the presence of hexagonal voids of Si(111). 展开更多
关键词 Schottky barrier diode(SBD) temperature dependence self-assembled patches temperature dependence PtSi/n-Si(111) C–V characteristics quantum wells
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The Interface Stress Field in the Elastic System Consisting of the Hollow Cylinder and Surrounding Elastic Medium Under 3D Non-Axisymmetric Forced Vibration 被引量:2
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作者 Surkay D.Akbarov Mahir A.Mehdiyev 《Computers, Materials & Continua》 SCIE EI 2018年第1期61-81,共21页
The paper develops and employs analytical-numerical solution method for the study of the time-harmonic dynamic stress field in the system consisting of the hollow cylinder and surrounding elastic medium under the non-... The paper develops and employs analytical-numerical solution method for the study of the time-harmonic dynamic stress field in the system consisting of the hollow cylinder and surrounding elastic medium under the non-axisymmetric forced vibration of this system.It is assumed that in the interior of the hollow cylinder the point-located with respect to the cylinder axis,non-axisymmetric with respect to the circumferential direction and uniformly distributed time-harmonic forces act.Corresponding boundary value problem is solved by employing of the exponential Fourier transformation with respect to the axial coordinate and by employing of the Fourier series expansion of these transformations.Numerical results on the frequency response of the interface normal stresses are presented and discussed. 展开更多
关键词 Interface stress field frequency response hollow cylinder elastic medium forced vibration
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The Fine Spectra of the Difference Operator △ Over the Sequence Space bv_p,(1≤p<∞) 被引量:2
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作者 Ali M.AKHMEDOV Feyzi BASAR 《Acta Mathematica Sinica,English Series》 SCIE CSCD 2007年第10期1757-1768,共12页
The sequence space bvp consisting of all sequences (xk) such that (xk -xk-1) belongs to the space gp has recently been introduced by Basar and Altay [Ukrainian Math. J., 55(1), 136-147(2003)]; where 1 ≤ p ≤ ... The sequence space bvp consisting of all sequences (xk) such that (xk -xk-1) belongs to the space gp has recently been introduced by Basar and Altay [Ukrainian Math. J., 55(1), 136-147(2003)]; where 1 ≤ p ≤ ∞. In the present paper, some results concerning with the continuous dual and f-dual, and the AD-property of the sequence space bvp have been given and the norm of the difference operator A acting on the sequence space bvp has been found. The fine spectrum with respect to the Goldberg's classification of the difference operator △ over the sequence space bvp has been determined, where 1≤p〈∞. 展开更多
关键词 spectrum of an operator difference operator the continuous dual and f-dual of a sequence space the AD-property and the sequence space bvp
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Indentation fracture toughness of single-crystal Bi2Te3 topological insulators 被引量:1
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作者 Caterina Lamuta Anna Cupolillo +4 位作者 Antonio Politano Ziya S. Aliev Mahammad B. Babanly Evgueni V. Chulkov Leonardo Pagnotta 《Nano Research》 SCIE EI CAS CSCD 2016年第4期1032-1042,共11页
Bismuth teUuride (Bi2Te3) is one of the most important commercial thermoelectric materials. In recent years, the discovery of topologically protected surface states in Bi chalcogenides has paved the way for their ap... Bismuth teUuride (Bi2Te3) is one of the most important commercial thermoelectric materials. In recent years, the discovery of topologically protected surface states in Bi chalcogenides has paved the way for their application in nanoelectronics. Determination of the fracture toughness plays a crucial role for the potential application of topological insulators in flexible electronics and nanoelectro- mechanical devices. Using depth-sensing nanoindentation tests, we investigated for the first time the fracture toughness of bulk single crystals of Bi2Te3 topological insulators, grown using the Bridgmantockbarger method. Our results highlight one of the possible pitfalls of the technology based on topological insulators. 展开更多
关键词 topological insulators bismuth telluride (Bi2Te3) fracture toughness NANOINDENTATION
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Electronic and Optical Properties of Rare Earth Oxides: <i>Ab Initio</i>Calculation 被引量:1
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作者 Sezen Horoz Sevket Simsek +1 位作者 Selami Palaz Amirullah M. Mamedov 《World Journal of Condensed Matter Physics》 2015年第2期78-85,共8页
In this work, we have investigated the electronic and optical properties of the technologically important rare earth oxide compounds—X2O3 (X: Gd, Tb) using the density functional theory within the GGA. The band struc... In this work, we have investigated the electronic and optical properties of the technologically important rare earth oxide compounds—X2O3 (X: Gd, Tb) using the density functional theory within the GGA. The band structure of X2O3 have been calculated along high symmetry directions in the first brillouin zone. The real and imaginary parts of dilectric functions and the other optical responses such as energy-loss function, the effective number of valence electrons and the effective optical dielectric constants of the rare earth sesquioxides (Gd2O3 and Tb2O3) were calculated. 展开更多
关键词 Rare Earth OXIDES Ab INITIO CALCULATION Electronic Structure Optical Properties
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Complete ablation of tumors using synchronous chemoradiation with bimetallic theranostic nanoparticles
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作者 Hamed Nosrati Elahe Attari +9 位作者 Fatemeh Abhari Murat Barsbay Mohammadreza Ghaffarlou Navid Mousazadeh Rasoul Vaezi Taras Kavetskyy Hamed Rezaeejam Thomas J.Webster Behrooz Johari Hossein Danafar 《Bioactive Materials》 SCIE 2022年第1期74-84,共11页
Synchronous chemotherapy and radiotherapy,termed chemoradiation therapy,is now an important standard regime for synergistic cancer treatment.For such treatment,nanoparticles can serve as improved carriers of chemother... Synchronous chemotherapy and radiotherapy,termed chemoradiation therapy,is now an important standard regime for synergistic cancer treatment.For such treatment,nanoparticles can serve as improved carriers of chemotherapeutics into tumors and as better radiosensitizers for localized radiotherapy.Herein,we designed a Schottky-type theranostic heterostructure,Bi_(2)S_(3)-Au,with deep level defects(DLDs)in Bi_(2)S_(3) as a nano-radiosensitizer and CT imaging contrast agent which can generate reactive free radicals to initiate DNA damage within tumor cells under X-ray irradiation.Methotrexate(MTX)was conjugated onto the Bi_(2)S_(3)-Au nanoparticles as a chemotherapeutic agent showing enzymatic stimuli-responsive release behavior.The designed hybrid system also contained curcumin(CUR),which cannot only serve as a nutritional supplement for chemotherapy,but also can play an important role in the radioprotection of normal cells.Impressively,this combined one-dose chemoradiation therapeutic injection of co-drug loaded bimetallic multifunctional theranostic nanoparticles with a one-time clinical X-ray irradiation,completely eradicated tumors in mice after approximately 20 days after irradiation showing extremely effective anticancer efficacy which should be further studied for numerous anti-cancer applications. 展开更多
关键词 Combination therapy RADIOSENSITIZER Semiconductor Heterojunction RADIOPROTECTOR
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Principles of Diagnosis and Treatment of Patients with Diagnosis of Covid-19 and Developing Viral Pneumonia
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作者 Kamala Namazova Hasanov Hafiz +7 位作者 Hasanov Fuad Muradov Nizami Guliev Rashad Abasova Machruch Karimov Qeys Asgerov Gunel Mamedova Gunel Shirinova Lala 《Journal of Pharmacy and Pharmacology》 CAS 2021年第7期239-244,共6页
The article provides information on our achievements in the application of modern diagnostic methods and modern methods of treating patients with viral pneumonia,confirmed by covid-19.For this,statistical data of 2,00... The article provides information on our achievements in the application of modern diagnostic methods and modern methods of treating patients with viral pneumonia,confirmed by covid-19.For this,statistical data of 2,000 patients were used.Of the 2,000 patients treated,920 were men,1,070 were women and 10 were children.Viral pneumonia-glaucoma syndrome in 1650 out of 2,000 patients with 10-20%damage;In 350,the diagnosis of viral pneumonia-frostbite syndrome with 50-85%damage,CRDS,respiratory failure was confirmed.Thus,50 out of 350 patients treated at the intensive care unit(ICU)out of 2,000 were intubated and connected to artificial ventilation.The research was carried out in 3 stages:I stage-admission to the intensive care unit;II stage-from the day of intubation to spontaneous breathing(7-14 days);and III stage-covers the period of extubation and recovery.The results of clinical,functional,hemodynamic and echocardiographic studies of the patients participating in the examination were analyzed.Also,the patients underwent bacteriological research studied the sensitivity to antibiotics.In addition,the composition of blood gases and the oxygenation index-Carrico were studied. 展开更多
关键词 Covid-19 acute respiratory distress syndrome total pnevmonia acute respiratory failure oxygenation index.
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Associations in the Two-Nucleon Transfer Reactions
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作者 Sajida G. Abdulvahabova Rasim A. Ahmedov Irada G. Afandiyeva 《Journal of Physical Science and Application》 2015年第2期158-162,共5页
On the basis of the association theory of nuclear structure, we have studied the (t, p) reaction. Study was carried out with the distorted plane waves of triton and of proton. It has been suggested that bineutron as... On the basis of the association theory of nuclear structure, we have studied the (t, p) reaction. Study was carried out with the distorted plane waves of triton and of proton. It has been suggested that bineutron association is acceptable if the time during which the association maintains its structure, is large compared with the time when neutrons are in a dissociated form, and there is no exchange of nucleons between fragments associations. The cross section is written as a product of two factors, one is the spectroscopic factor which reflects the nature of the nuclear structure concerned and the other describes the process in which the target nucleus captures two nucleons as a cluster into an orbit which is characterized by a form factor. In the argument, that the radial wave function of two neutrons which form association captured nuclei close to each other, this leads to the formation of bineutron association on the nuclei surface. In this approach, the proton is emitted at the same point, which is captured bineutron association. 展开更多
关键词 SCATTERING matrix element nucleon association two-nucleon transfers cross section.
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The Change of Physical-Mechanical Properties of Viscoelastic Liquids in Consideration of Nanoparticles
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作者 M. A. Ramazanov M. S. Aslanov 《Applied Mathematics》 2013年第10期1367-1370,共4页
The paper studies the viscoelastic body described by the generalized Maxwell model. This model consists of several parallel-connected simple models of Maxwell. Assuming the interaction of atoms of the body with embedd... The paper studies the viscoelastic body described by the generalized Maxwell model. This model consists of several parallel-connected simple models of Maxwell. Assuming the interaction of atoms of the body with embedded nanoparticles leads to a change in model parameters. It is shown that with the addition of nanoparticles with a specific property, it can change the value of the deformation points of a viscoelastic body. This change depends on the number of elements. 展开更多
关键词 VISCOELASTIC BODY The MAXWELL Model NANOPARTICLE Value of the Deformation POINTS
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Study of the Influence of Nanoparticles on the Molecular Model of an Ideal Fluid
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作者 Mahammadali Ahmad oglu Ramazanov Mammad Samad oglu Aslanov 《Applied Mathematics》 2016年第9期908-911,共4页
In the article a molecular model of oil with nanoparticles on the basis of the model of ideal fluid is considered. It is assumed that the molecular model of the oil can be represented as a homogenous distribution of i... In the article a molecular model of oil with nanoparticles on the basis of the model of ideal fluid is considered. It is assumed that the molecular model of the oil can be represented as a homogenous distribution of identical molecules in space. It is assumed that the central interaction between the oil molecules and nanoparticles, results in a change of the model parameters. It is shown that for an ideal fluid the effect of nanoparticles is reduced to a change of the coefficient at the pressure. 展开更多
关键词 Ideal Fluid Molecular Model of Oil NANOPARTICLES Coefficient of Elasticity
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Effect of diode size and series resistance on barrier height and ideality factor in nearly ideal Au/n type-GaAs micro Schottky contact diodes 被引量:2
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作者 M. A. Yeganeh Sh. Rahmatallahpur +1 位作者 A. Nozad R. K. Mamedov 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第10期477-484,共8页
Small high-quality Au/n type-GaAs Schottky barrier diodes (SBDs) with low reverse leakage current are produced using lithography. Their effective barrier heights (BHs) and ideality factors from current-voltage (... Small high-quality Au/n type-GaAs Schottky barrier diodes (SBDs) with low reverse leakage current are produced using lithography. Their effective barrier heights (BHs) and ideality factors from current-voltage (I-V) characteristics are measured by a Pico ampere meter and home-built I-V instrument. In spite of the identical preparation of the diodes there is a diode-to-diode variation in ideality factor and barrier height parameters. Measurement of topology of a surface of a thin metal film with atomic force microscope (AFM) shows that Au-n type-GaAS SD consists of a set of parallel-connected micro and nanocontacts diodes with sizes approximately in a range of 100-200 nm. Between barrier height and ideality factor there is an inversely proportional dependency. With the diameter of contact increasing from 5 μm up to 200 μm, the barrier height increases from 0.833 up to 0.933 eV and its ideality factor decreases from 1.11 down to 1.006. These dependencies show the reduction of the contribution of the peripheral current with the diameter of contact increasing. We find the effect of series resistance on barrier height and ideality factor. 展开更多
关键词 Schottky barrier diodes conducting probe-atomic force microscope barrier height andideality factor
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Determination of Lead(II) in Liver Corpse of a Slaughtered Cattle with Preconcentration on a Chelating Sorbent
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作者 R. A. Aliyeva N. S. Huseynova +2 位作者 Ulviya M. Abilova G. B. İskandarov F. M. Chiragov 《American Journal of Analytical Chemistry》 2016年第8期617-622,共7页
The copolymer of the maleic anhydride-styrene is modified at the presence of 4-amino-2-thiouracil and formaldehyde and the new polymeric sorbate with spatial structure is received. The received sorbate is identified b... The copolymer of the maleic anhydride-styrene is modified at the presence of 4-amino-2-thiouracil and formaldehyde and the new polymeric sorbate with spatial structure is received. The received sorbate is identified by the IR-spectroscopy method. The complete static sorption capacitance was studied (CSSC<sup>+</sup>K</sub>= 7.8 mmol/g) and the ionization constants of ionic groups in a sorbate link was defined by electrometric method. Ionization constants were determined by potentiometric titration of the sorbent (). Sorption and desorption of the received sorbent with a lead ion (II) are investigated and optimum concentration conditions are defined: рН<sub>opt.</sub> = 5, ionic force μ = 0.8 pier/l, full sorption balance 4 hours, optimum eluent 5 ml of 0.5 M HCl. 展开更多
关键词 Sorption Capacity PRECONCENTRATION Polymeric Sorbate Lead(II)
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Characteristic of Species Composition of Fungi Involved in the Formation of Mycobiota of Honey Bees in Azerbaijan
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作者 Aysel F.Isayeva Guler M.Seyidova +2 位作者 Sahla A.Abdullayeva Matanat S.Novruzova Panah Z.Muradov 《Advances in Bioscience and Biotechnology》 2019年第9期282-287,共6页
The purpose of the presented work was dedicated to identifying the species composition of the mycobiota of honey bees in Azerbaijan condition. From the samples taken from bees, materials became clear that in the forma... The purpose of the presented work was dedicated to identifying the species composition of the mycobiota of honey bees in Azerbaijan condition. From the samples taken from bees, materials became clear that in the formation of mycobiota those materials (from bees, from where they live and their products) in generally participate 52 species of fungi. Among the recorded fungi, species take part such as Alternaria alternata (Fr.) Keissl., Aspergillus flavus Link, Candida albicans (C.P. Robin) Berkhout, Cladosporium herbarum (Pers.) Link, Penicillium cuclopium Westling, P. granulatum Bainier and etc. which carry features conditionally pathogenicity, toxicity, allergens and danger to biological productivity of bees and as well as to pollution of their products. It is known for a long time to scientists that these species are dangerous for human health. For this reason, preparation of normative documents that reflect the principles of microbiological safety of bee products is a necessary task. 展开更多
关键词 Honey Bees MYCOBIOTA Toxigenes Askosferoz ASPERGILLOSIS
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Nano-Coupling of Cephalosporin Antibiotics with Fe<SUB>3</SUB>O<SUB>4</SUB>Nanoparticles: Trojan Horse Approach in Antimicrobial Chemotherapy of Infections Caused by <i>Klebsiella spp</i>. 被引量:1
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作者 Ulviyya Alimammad Hasanova Mahammadali Ahmad Ramazanov +6 位作者 Abel Mammadali Maharramov Qoncha Malik Eyvazova Zohrab Adalet Agamaliyev Yana Vacheslav Parfyonova Sarvinaz Faiq Hajiyeva Flora Vidadi Hajiyeva Solmaz Bayram Veliyeva 《Journal of Biomaterials and Nanobiotechnology》 2015年第3期225-235,共11页
In the present study we had an aim to develop the methods of functionalizing the surface of magnetite nanoparticles with cefotaxime and ceftriaxone antibiotics. The quantitative analysis of the nanostructured cephalos... In the present study we had an aim to develop the methods of functionalizing the surface of magnetite nanoparticles with cefotaxime and ceftriaxone antibiotics. The quantitative analysis of the nanostructured cephalosporins was determined by Atom Absorbance Spectroscopy (AAS) and based on the Lambert-Beer law. The engineered nanostructures were tested on gram-negative microorganisms Klebsiella spp., of Enterobacteriaceae, and gram-positive bacteria Staphylococcus aureus, each having multi-drug resistance properties. 展开更多
关键词 Magnetite NANOPARTICLES CEPHALOSPORIN CEFOTAXIME Ceftriaxone KLEBSIELLA Staphylococcus aureus
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Oxidation of Pyridine Bases by Hydrogen Peroxide 被引量:1
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作者 Ali-zadeh Nahmad Islam Nagieva Inara Tofik +2 位作者 Babaeva Badam Tofik Magerramov Abel Mamedali Nagiev Tofik Murtuza 《Journal of Chemistry and Chemical Engineering》 2011年第1期82-88,共7页
The interfering kinetics of the coherent synchronous reactions of hydrogen peroxide decomposition and the oxidation of pyridine derivatives have been studied experimentally. The regions of the selective oxidation of t... The interfering kinetics of the coherent synchronous reactions of hydrogen peroxide decomposition and the oxidation of pyridine derivatives have been studied experimentally. The regions of the selective oxidation of the pyridine derivatives have been found, and the optimal conditions for the production of4-vynilpyridine, 4-vynilpyridine N-monoxide, 2, 2-dipyridyl, and pyridine have been determined. The most probable synchronization mechanism is suggested for hydrogen peroxide decomposition and the free-radical chain oxidation of pyridine derivatives. The HO2 -radical plays the key role in this mechanism. The activation energies are calculated for the elementary steps of 4-ethylpyridine dehydrogenation. 展开更多
关键词 Free radical coherent synchronized CONJUGATION N-monooxidation determinant.
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The Phosphochlorinated Polymeric Sorbents for Sorption of Gold (III)
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作者 A. A. Azizov U. I. Yaqubova M. I. Aliyev 《Open Journal of Polymer Chemistry》 CAS 2016年第2期9-14,共6页
This study evaluated the simple methods to improve the sorptional capability of polymeric sorbent to gold (III) ions. The polymeric sorbents have been synthesized by a chemical modification of dithizone phosphorchlori... This study evaluated the simple methods to improve the sorptional capability of polymeric sorbent to gold (III) ions. The polymeric sorbents have been synthesized by a chemical modification of dithizone phosphorchlorinated PB. The structure and composition of functional polymers are studied by IR spectroscopy, X-ray fluorescence analysis, the diffusion of optical spectroscopy, scanning electron microscopy, thermogravimetric and elemental analysis. It found that the obtained sorbents had porous crosslinked structure and did not dissolve in any organic solvents, solutions of inorganic acids and alkalines. The sorption properties of the syntesized polymer sorbents onto gold (III) ion in aqueous solutions have been studied. It is found that the adsorption effect of gold makes 85% - 90% and the equilibrium sorption capacity of polymer sorbent is 137 mg/g in acidic media. In order to improve sorption efficiency of sorbents to gold ions, the non-covalent immobilization of organic sulfur containing compound to the polymer matrix was carried out. The gold embedded polymer matrix was characterized by SEM, EDX, XRD and visible absorption spectroscopy. The obtained results indicated that the polymeric sorbent contained metallic form of zero-valent gold. It was found that the average particle size of elemental gold crystals was 28.31 nm. 展开更多
关键词 SORPTION GOLD Phosphochlorinated Polymer
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