为了提高聚能战斗部对水中目标的毁伤威力,提出形成串联爆炸成型弹丸(Explosively Formed Projectile,EFP)的组合药型罩战斗部结构。利用平板抛掷和圆筒压垮公式建立组合药型罩EFP速度分析模型,并使用AUTODYN-2D软件对EFP成型和入水毁...为了提高聚能战斗部对水中目标的毁伤威力,提出形成串联爆炸成型弹丸(Explosively Formed Projectile,EFP)的组合药型罩战斗部结构。利用平板抛掷和圆筒压垮公式建立组合药型罩EFP速度分析模型,并使用AUTODYN-2D软件对EFP成型和入水毁伤过程进行数值模拟,研究组合药型罩结构参数对串联EFP成型的影响,证明其在水中高效的侵彻性能。研究结果表明:理论与数值模拟计算得到的EFP速度基本吻合,最大误差不超过10%;组合药型罩分离形成串联EFP是由于内外罩不同的材料和结构组合使罩微元从接触面处开始形成较大的速度差所引起的;随着内罩直径的增大,内外罩形成的EFP速度同时减小,长径比分别增大与减小;单独增大内外罩外曲率半径与罩顶壁厚,对应罩成型的EFP性能变化规律和单一药型罩相同,但另一罩成型EFP的长径比均减小或分别减小与增大,速度变化幅度较小;组合药型罩串联EFP侵彻4倍装药直径的水后,动能衰减率较双层药型罩降低21.55%,剩余速度提高5.77%,且随着侵彻距离的增加该差距进一步扩大。展开更多
The oxidative cyclization reaction of 2-nitroaniline via sodium hypochlorite to yield benzo- furoxan is investigated by the hybrid density functional theory B3LYP/6-31G（d,p） method. Solvent effects are estimated wit...The oxidative cyclization reaction of 2-nitroaniline via sodium hypochlorite to yield benzo- furoxan is investigated by the hybrid density functional theory B3LYP/6-31G（d,p） method. Solvent effects are estimated with the polarizable continuum model to optimize structures. The title reaction is predicted to undergo two pathways, each of which is a stepwise process. Path A includes four steps, namely oxidization, H-attack, hydrolysis, and cyclization. Path B involves the nucleophilic attack of OH^- to the H atom of the N-H bond and the proton transfer to the N atom of amino group leading to the cleavage of the N-H single bond in the amino group. The calculated results indicate that path A is favored mechanism for the title reaction. Furthermore, it is rational for one water molecule serving as a bridge to assist in the hydrolysis step of Path A and our calculations exhibit that this process is the rate-determining step.展开更多
文摘为了提高聚能战斗部对水中目标的毁伤威力,提出形成串联爆炸成型弹丸(Explosively Formed Projectile,EFP)的组合药型罩战斗部结构。利用平板抛掷和圆筒压垮公式建立组合药型罩EFP速度分析模型,并使用AUTODYN-2D软件对EFP成型和入水毁伤过程进行数值模拟,研究组合药型罩结构参数对串联EFP成型的影响,证明其在水中高效的侵彻性能。研究结果表明:理论与数值模拟计算得到的EFP速度基本吻合,最大误差不超过10%;组合药型罩分离形成串联EFP是由于内外罩不同的材料和结构组合使罩微元从接触面处开始形成较大的速度差所引起的;随着内罩直径的增大,内外罩形成的EFP速度同时减小,长径比分别增大与减小;单独增大内外罩外曲率半径与罩顶壁厚,对应罩成型的EFP性能变化规律和单一药型罩相同,但另一罩成型EFP的长径比均减小或分别减小与增大,速度变化幅度较小;组合药型罩串联EFP侵彻4倍装药直径的水后,动能衰减率较双层药型罩降低21.55%,剩余速度提高5.77%,且随着侵彻距离的增加该差距进一步扩大。
文摘The oxidative cyclization reaction of 2-nitroaniline via sodium hypochlorite to yield benzo- furoxan is investigated by the hybrid density functional theory B3LYP/6-31G（d,p） method. Solvent effects are estimated with the polarizable continuum model to optimize structures. The title reaction is predicted to undergo two pathways, each of which is a stepwise process. Path A includes four steps, namely oxidization, H-attack, hydrolysis, and cyclization. Path B involves the nucleophilic attack of OH^- to the H atom of the N-H bond and the proton transfer to the N atom of amino group leading to the cleavage of the N-H single bond in the amino group. The calculated results indicate that path A is favored mechanism for the title reaction. Furthermore, it is rational for one water molecule serving as a bridge to assist in the hydrolysis step of Path A and our calculations exhibit that this process is the rate-determining step.
