Complex [Mn2(C6H11CO2)3(4,4'-bipy)2(H2O)2]ClO4(C6H11CO2H=cyclohexanecarboxylic acid) was synthesized by reaction of Mn(ClO4)2.6H2O,C6H11CO2Na and 4,4'-bipy in methanol.The title complex crystallizes in triclin...Complex [Mn2(C6H11CO2)3(4,4'-bipy)2(H2O)2]ClO4(C6H11CO2H=cyclohexanecarboxylic acid) was synthesized by reaction of Mn(ClO4)2.6H2O,C6H11CO2Na and 4,4'-bipy in methanol.The title complex crystallizes in triclinic space group P1,with a=1.008 8(2) nm,b=1.086 3(1) nm,c=1.164 9(3) nm,α=63.016(3)°,β=81.998(4)°,γ=88.604(1)°,V= 1.125 4(4) nm3,Z=1.There are two types of Mn atoms in the structure with each in octahedral geometry.Mn1 and Mn2 are bridged by cyclohexanecarboxylate ligands into a chain and the chains are further linked together by 4,4'-bipy into a 2D plane.CCDC:692247.展开更多
A novel coordination polymer, [Cd(py)(SSZ)2]n, was synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectra and X-ray single crystal diffraction. CCDC: 295625.
文摘Complex [Mn2(C6H11CO2)3(4,4'-bipy)2(H2O)2]ClO4(C6H11CO2H=cyclohexanecarboxylic acid) was synthesized by reaction of Mn(ClO4)2.6H2O,C6H11CO2Na and 4,4'-bipy in methanol.The title complex crystallizes in triclinic space group P1,with a=1.008 8(2) nm,b=1.086 3(1) nm,c=1.164 9(3) nm,α=63.016(3)°,β=81.998(4)°,γ=88.604(1)°,V= 1.125 4(4) nm3,Z=1.There are two types of Mn atoms in the structure with each in octahedral geometry.Mn1 and Mn2 are bridged by cyclohexanecarboxylate ligands into a chain and the chains are further linked together by 4,4'-bipy into a 2D plane.CCDC:692247.
文摘A novel coordination polymer, [Cd(py)(SSZ)2]n, was synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectra and X-ray single crystal diffraction. CCDC: 295625.
