以一水柠檬酸和六水硝酸钴为原料,采用水热-碳化联合法制备碳包覆纳米金属钴催化剂。通过调变原料比例和碳化温度,得到优选催化剂Co-CA_(2.5)-500。将制备的催化剂用于肉桂醛选择加氢反应,表现出优异的催化性能,在70℃、2 MPa H_(2)条件...以一水柠檬酸和六水硝酸钴为原料,采用水热-碳化联合法制备碳包覆纳米金属钴催化剂。通过调变原料比例和碳化温度,得到优选催化剂Co-CA_(2.5)-500。将制备的催化剂用于肉桂醛选择加氢反应,表现出优异的催化性能,在70℃、2 MPa H_(2)条件下,以9 mL EtOH+1 mL H_(2)O为溶剂反应2 h,肉桂醛转化率为75.1%,肉桂醇选择性为64.7%。表征结果表明,Co-CA_(2.5)-500的高催化性能与碳载体发达的孔道结构和活性金属钴的高度分散有关。展开更多
文摘以一水柠檬酸和六水硝酸钴为原料,采用水热-碳化联合法制备碳包覆纳米金属钴催化剂。通过调变原料比例和碳化温度,得到优选催化剂Co-CA_(2.5)-500。将制备的催化剂用于肉桂醛选择加氢反应,表现出优异的催化性能,在70℃、2 MPa H_(2)条件下,以9 mL EtOH+1 mL H_(2)O为溶剂反应2 h,肉桂醛转化率为75.1%,肉桂醇选择性为64.7%。表征结果表明,Co-CA_(2.5)-500的高催化性能与碳载体发达的孔道结构和活性金属钴的高度分散有关。
基金supported by the National Natural Science Foundation of China(21503028,21573031 and 21428301)the Fundamental Research Funds for the Central Universities(DUT15ZD106)
基金supported by the National Key Research & Development Program of China (2016YFB0600305)the National Natural Science Foundation of China (22038008)the China Postdoctoral Science Foundation (2019M651119)
基金supported by the National Natural Science Foundation of China(21073023,20906008)the Fundamental Research Funds for the Central Universities(DUT12YQ03)~~
基金supported by the National Natural Science Foundation of China(21573031,21428301)the Fundamental Research Funds for the Central Universities(DUT15ZD106)Program for Excellent Talents in Dalian City(2016RD09)~~
