C1 chemistry based on synthesis gas, methane, and carbon dioxide offers many routes to industrial chemicals. The reactions related to the synthesis of gas can be classified into direct and indirect approach for making...C1 chemistry based on synthesis gas, methane, and carbon dioxide offers many routes to industrial chemicals. The reactions related to the synthesis of gas can be classified into direct and indirect approach for making such products, such as acetic acid, dimethyl ether, and alcohol. Catalytic syngas processing is currently done at high temperatures and pressures, conditions that could be unfavorable for the life of the catalyst. Another issue of C1 chemistry is related to the methane-initiated process. It has been known that direct methane conversions are still suffering from low yields and selectivity of products resulting in unprofitable ways to produce products, such as higher hydrocarbons, methanol, and so on. However, many experts and researchers are still trying to find the best method to overcome these barriers, for example, by finding the best catalyst to reduce the high-energy barrier of the reactions and conduct only selective catalyst-surface reactions. The appli- cation of Yttria-Stabilized Zirconia （YSZ） and its combination with other metals for catalyzing purposes are increasing. The existence of an interesting site that acts as oxygen store could be the main reason for it. Moreover, formation of intermediate species on the surface of YSZ also contributes significantly in increasing the production of some specific products. Understanding the phenomena happening inside could be necessary. In this article, the use of YSZ for some C1 chemistry reactions was discussed and reviewed.展开更多
Scandia,yttria-stabilized zirconia (Sc2O3-Y2O3-ZrO2) powder for plasma spraying was synthesized by chemical co-precipitation process.The morphology and phase stability of plasma sprayed 6.8mol%Sc2O3-1.2mol%Y2O3-ZrO2 t...Scandia,yttria-stabilized zirconia (Sc2O3-Y2O3-ZrO2) powder for plasma spraying was synthesized by chemical co-precipitation process.The morphology and phase stability of plasma sprayed 6.8mol%Sc2O3-1.2mol%Y2O3-ZrO2 thermal barrier coatings (TBCs) were investigated.Samples of the coatings were heated at 1400℃ for 500 hours and then examined by X-ray diffraction.It was found that the Sc2O3-Y2O3-ZrO2 coatings showed excellent phase stability to retain single tetragonal t' phase structure and did not undergo a tetragonal-to-monoclinic phase transition upon cooling.展开更多
The correlation between particle in-flight parameter, defect content and mechanical property of yttria-stabilized zirconia coating was systematically studied in the present work. The melting state of in-flight particl...The correlation between particle in-flight parameter, defect content and mechanical property of yttria-stabilized zirconia coating was systematically studied in the present work. The melting state of in-flight particle during spraying was simulated using computational fluid dynamics. The results suggested that, with the increase of velocity and temperature of in-flight particles in the plasma jet, the particles changed from partially melted state to fully melted one. As a result, the total defect content of as-sprayed coating gradually decreased, while elastic modulus and microhardness increased correspondingly. However, the fracture toughness of as-sprayed coating reached a maximum value when the total defect content reached approximately 9.1%.展开更多
The possibility to fabricate yttria-stabilized zirconia (YSZ) thin-substrates by aqueous gel casting of high concentrated aqueous slurries was investigated. The effects of dispersant, pH value, and solid content of sl...The possibility to fabricate yttria-stabilized zirconia (YSZ) thin-substrates by aqueous gel casting of high concentrated aqueous slurries was investigated. The effects of dispersant, pH value, and solid content of slurries for gel process on stability and viscosity of slurries were optimized. YSZ thin-substrates green bodies with 100 μm thickness and 100 mm×100 mm flat plate were fabricated. Microstructure observations, density and bending measurements show that these green bodies are homogeneous and highly densified. After sintering at 1873 K×2 h, the ionic conductivity reaches 0.155 S·cm^(-1) at 1273 K.展开更多
基金Project supported by the Global R&D Program of the Korea Foundation for International Cooperation of Science and Technology (KICOS)
文摘C1 chemistry based on synthesis gas, methane, and carbon dioxide offers many routes to industrial chemicals. The reactions related to the synthesis of gas can be classified into direct and indirect approach for making such products, such as acetic acid, dimethyl ether, and alcohol. Catalytic syngas processing is currently done at high temperatures and pressures, conditions that could be unfavorable for the life of the catalyst. Another issue of C1 chemistry is related to the methane-initiated process. It has been known that direct methane conversions are still suffering from low yields and selectivity of products resulting in unprofitable ways to produce products, such as higher hydrocarbons, methanol, and so on. However, many experts and researchers are still trying to find the best method to overcome these barriers, for example, by finding the best catalyst to reduce the high-energy barrier of the reactions and conduct only selective catalyst-surface reactions. The appli- cation of Yttria-Stabilized Zirconia （YSZ） and its combination with other metals for catalyzing purposes are increasing. The existence of an interesting site that acts as oxygen store could be the main reason for it. Moreover, formation of intermediate species on the surface of YSZ also contributes significantly in increasing the production of some specific products. Understanding the phenomena happening inside could be necessary. In this article, the use of YSZ for some C1 chemistry reactions was discussed and reviewed.
文摘Scandia,yttria-stabilized zirconia (Sc2O3-Y2O3-ZrO2) powder for plasma spraying was synthesized by chemical co-precipitation process.The morphology and phase stability of plasma sprayed 6.8mol%Sc2O3-1.2mol%Y2O3-ZrO2 thermal barrier coatings (TBCs) were investigated.Samples of the coatings were heated at 1400℃ for 500 hours and then examined by X-ray diffraction.It was found that the Sc2O3-Y2O3-ZrO2 coatings showed excellent phase stability to retain single tetragonal t' phase structure and did not undergo a tetragonal-to-monoclinic phase transition upon cooling.
基金supported by the Collaborative Innovation Center of Advanced Control Valve Project (Grant No. WZYB-XTCX-001)
文摘The correlation between particle in-flight parameter, defect content and mechanical property of yttria-stabilized zirconia coating was systematically studied in the present work. The melting state of in-flight particle during spraying was simulated using computational fluid dynamics. The results suggested that, with the increase of velocity and temperature of in-flight particles in the plasma jet, the particles changed from partially melted state to fully melted one. As a result, the total defect content of as-sprayed coating gradually decreased, while elastic modulus and microhardness increased correspondingly. However, the fracture toughness of as-sprayed coating reached a maximum value when the total defect content reached approximately 9.1%.
文摘The possibility to fabricate yttria-stabilized zirconia (YSZ) thin-substrates by aqueous gel casting of high concentrated aqueous slurries was investigated. The effects of dispersant, pH value, and solid content of slurries for gel process on stability and viscosity of slurries were optimized. YSZ thin-substrates green bodies with 100 μm thickness and 100 mm×100 mm flat plate were fabricated. Microstructure observations, density and bending measurements show that these green bodies are homogeneous and highly densified. After sintering at 1873 K×2 h, the ionic conductivity reaches 0.155 S·cm^(-1) at 1273 K.
