The in situ Al 2O 3p TiC p/Al composite was fabricated by XD (exothermic dispersion) process in TiO 2 Al C system, and the effect of carbon content on the microstructure of the fabricated composite and the reactive te...The in situ Al 2O 3p TiC p/Al composite was fabricated by XD (exothermic dispersion) process in TiO 2 Al C system, and the effect of carbon content on the microstructure of the fabricated composite and the reactive temperature characteristics had been studied. The results show that carbon content affects the microstructure and reactive temperature of Al 2O 3p TiC p/Al composite greatly. The quantity of TiC phases in the fabricated composites increases, while the Al 3Ti phases reduces with increasing carbon content. And when C/TiO 2 molecular ratio is equal to one, the Al 3Ti phase nearly disappears. High temperature metallurgical field caused by strong exothermic reaction influences the synthetic reaction greatly, and higher synthetic temperature was favorable to the synthesis of Al 2O 3p TiC p reinforce particles.展开更多
TiC particle reinforced titanium alloy matrix composites with different aluminum content was prepared by the XD TM method. The constitute phase and the microstructure of the composites were studied by XRD and SEM. The...TiC particle reinforced titanium alloy matrix composites with different aluminum content was prepared by the XD TM method. The constitute phase and the microstructure of the composites were studied by XRD and SEM. The results show that the calculated lattice parameter of TiC there exists a diffraction peak shift for TiC, which may be due to the vacancies of C in TiC. The stoichiometry of TiC is Ti 62 C 38 . There exist two different kinds of TiC in the composites: dendritic primary TiC and short bar shape eutectic TiC, respectively. Although TiC of macrostructure is homogeneously distributed in the matrix, the eutectic TiC of microstructure mainly segregates at the grain boundary, especially at the triangular grain boundaries. The aluminum content has a great influence on the morphology of TiC. With increasing aluminum content up to 25%, the size of TiC becomes small although it is still in dendrite or short bar shape. When the aluminum content is more than 35%, TiC is changed into thin plate or particle and the size is about 2~5 μm. [展开更多
文摘The in situ Al 2O 3p TiC p/Al composite was fabricated by XD (exothermic dispersion) process in TiO 2 Al C system, and the effect of carbon content on the microstructure of the fabricated composite and the reactive temperature characteristics had been studied. The results show that carbon content affects the microstructure and reactive temperature of Al 2O 3p TiC p/Al composite greatly. The quantity of TiC phases in the fabricated composites increases, while the Al 3Ti phases reduces with increasing carbon content. And when C/TiO 2 molecular ratio is equal to one, the Al 3Ti phase nearly disappears. High temperature metallurgical field caused by strong exothermic reaction influences the synthetic reaction greatly, and higher synthetic temperature was favorable to the synthesis of Al 2O 3p TiC p reinforce particles.
文摘TiC particle reinforced titanium alloy matrix composites with different aluminum content was prepared by the XD TM method. The constitute phase and the microstructure of the composites were studied by XRD and SEM. The results show that the calculated lattice parameter of TiC there exists a diffraction peak shift for TiC, which may be due to the vacancies of C in TiC. The stoichiometry of TiC is Ti 62 C 38 . There exist two different kinds of TiC in the composites: dendritic primary TiC and short bar shape eutectic TiC, respectively. Although TiC of macrostructure is homogeneously distributed in the matrix, the eutectic TiC of microstructure mainly segregates at the grain boundary, especially at the triangular grain boundaries. The aluminum content has a great influence on the morphology of TiC. With increasing aluminum content up to 25%, the size of TiC becomes small although it is still in dendrite or short bar shape. When the aluminum content is more than 35%, TiC is changed into thin plate or particle and the size is about 2~5 μm. [