Poly-crystalline anatase TiO2 layer fabricated by LPCVD using titanium-tetra-iso-propoxide and NbF5 in H2-ambient was treated in conc.-HCl solution after thin layer of IIIb-group metal was deposited on the TiO2 layer....Poly-crystalline anatase TiO2 layer fabricated by LPCVD using titanium-tetra-iso-propoxide and NbF5 in H2-ambient was treated in conc.-HCl solution after thin layer of IIIb-group metal was deposited on the TiO2 layer. Resistivity of the as-deposited layer about 1 × 10-1 Ω·cm was drastically reduced to 3 × 10-3 Ω·cm by the wet-treatment using indium. Temperature dependence of the resistivity increased with temperature above 100 K for the wet-treated layer was quite different from that decreased above 100 K for the as-deposited layer, whereas the resistivity was saturated at lower temperatures. The resistivity at room-temperature was decreased with the thickness before the wet-treatment but independent on the thickness above 100 nm for the wet-treated layer. Indium was more effective for the resistivity reduction than gallium but aluminum was not useful for the treatment. As the results that the wet-treatment using indium was examined for the TiO2 layers deposited by various conditions, the optimum deposition condition to reduce the resistivity of the layer after the wet-treatment was clearly different from that for the as-deposited layer.展开更多
为研究烟气“消白”工程的环境效益,采用RJ-SO3-M型便携式SO3分析仪对河北邯郸某电厂600 MW机组烟气“消白”工程进行了现场测试,收集了烟气“消白”工程实施前后相近运行负荷、相近煤质、相同时间段的烟尘、SO2、NOx的连续监测数据。...为研究烟气“消白”工程的环境效益,采用RJ-SO3-M型便携式SO3分析仪对河北邯郸某电厂600 MW机组烟气“消白”工程进行了现场测试,收集了烟气“消白”工程实施前后相近运行负荷、相近煤质、相同时间段的烟尘、SO2、NOx的连续监测数据。研究结果表明,烟气“消白”工程中的冷却降温对FGD、WESP脱除SO3的影响很小,烟气温降与FGD、WESP、FGD+WESP对SO3的脱除效率之间没有相关性,温降为0℃、2.9℃、3.9℃和5.8℃的4种工况条件下,F G D+W E S P对S O 3总的脱除效率介于75.6%~81.9%,平均为78.9%。烟气“消白”工程中,烟气降温有利于WESP对颗粒物的脱除,烟尘排放质量浓度约下降0.5 mg/m3,SO2和NOx排放浓度基本无变化。烟气中SO3的脱除主要取决于FGD和WESP,而与烟气是否冷却降温基本无关。烟气冷却降温不是减少污染物排放的有效方法。展开更多
文摘Poly-crystalline anatase TiO2 layer fabricated by LPCVD using titanium-tetra-iso-propoxide and NbF5 in H2-ambient was treated in conc.-HCl solution after thin layer of IIIb-group metal was deposited on the TiO2 layer. Resistivity of the as-deposited layer about 1 × 10-1 Ω·cm was drastically reduced to 3 × 10-3 Ω·cm by the wet-treatment using indium. Temperature dependence of the resistivity increased with temperature above 100 K for the wet-treated layer was quite different from that decreased above 100 K for the as-deposited layer, whereas the resistivity was saturated at lower temperatures. The resistivity at room-temperature was decreased with the thickness before the wet-treatment but independent on the thickness above 100 nm for the wet-treated layer. Indium was more effective for the resistivity reduction than gallium but aluminum was not useful for the treatment. As the results that the wet-treatment using indium was examined for the TiO2 layers deposited by various conditions, the optimum deposition condition to reduce the resistivity of the layer after the wet-treatment was clearly different from that for the as-deposited layer.
文摘为研究烟气“消白”工程的环境效益,采用RJ-SO3-M型便携式SO3分析仪对河北邯郸某电厂600 MW机组烟气“消白”工程进行了现场测试,收集了烟气“消白”工程实施前后相近运行负荷、相近煤质、相同时间段的烟尘、SO2、NOx的连续监测数据。研究结果表明,烟气“消白”工程中的冷却降温对FGD、WESP脱除SO3的影响很小,烟气温降与FGD、WESP、FGD+WESP对SO3的脱除效率之间没有相关性,温降为0℃、2.9℃、3.9℃和5.8℃的4种工况条件下,F G D+W E S P对S O 3总的脱除效率介于75.6%~81.9%,平均为78.9%。烟气“消白”工程中,烟气降温有利于WESP对颗粒物的脱除,烟尘排放质量浓度约下降0.5 mg/m3,SO2和NOx排放浓度基本无变化。烟气中SO3的脱除主要取决于FGD和WESP,而与烟气是否冷却降温基本无关。烟气冷却降温不是减少污染物排放的有效方法。
