Tribological behavior and wear mechanisms of mechanically milled Al5083 alloy and Al5083−5wt.%B4C composite at room temperature and 200°C were discussed.Results revealed that due to the oxidative wear at room tem...Tribological behavior and wear mechanisms of mechanically milled Al5083 alloy and Al5083−5wt.%B4C composite at room temperature and 200°C were discussed.Results revealed that due to the oxidative wear at room temperature,a mechanically mixed layer(MML)was formed to protect the surface of the samples.Under 80 N of load at room temperature,the milled Al5083 and the Al5083−5wt.%B4C samples showed evidence of abrasion with limited volume loss.In this case,the wear rates were 5.8×10−7 and 4.4×10−7 mm3/(m·N),respectively.At 200°C and under 80 N of applied load,severe wear occurred in the milled Al5083 sample,and wear rate reached 10.8×10−7 mm3/(m·N)while the Al5083−5wt.%B4C sample showed mild wear with local 3-body abrasion and the wear rate reached 5.3×10−7 mm3/(m·N).Strengthening mechanisms such as dislocation pinning and the Hall−Petch theory,high hardness and the load transfer effect were crucial in determining the wear behavior of the Al5083−5wt.%B4C composite.On the other hand,the milled Al5083 sample represented a relatively high wear rate at 200°C,which seemed to be related to the local grain growth and a drop in its hardness.展开更多
The poor corrosion and wear resistances of Mg alloys seriously limit their potential applications in various industries.The conventional epoxy coating easily forms many intrinsic defects during the solidification proc...The poor corrosion and wear resistances of Mg alloys seriously limit their potential applications in various industries.The conventional epoxy coating easily forms many intrinsic defects during the solidification process,which cannot provide sufficient protection.In the current study,we design a double-layer epoxy composite coating on Mg alloy with enhanced anti-corrosion/wear properties,via the spin-assisted assembly technique.The outer layer is functionalized graphene(FG)in waterborne epoxy resin(WEP)and the inner layer is Ce-based conversion(Ce)film.The FG sheets can be homogeneously dispersed within the epoxy matrix to fill the intrinsic defects and improve the barrier capability.The Ce film connects the outer layer with the substrate,showing the transition effect.The corrosion rate of Ce/WEP/FG composite coating is 2131 times lower than that of bare Mg alloy,and the wear rate is decreased by~90%.The improved corrosion resistance is attributed to the labyrinth effect(hindering the penetration of corrosive medium)and the obstruction of galvanic coupling behavior.The synergistic effect derived from the FG sheet and blocking layer exhibits great potential in realizing the improvement of multi-functional integration,which will open up a new avenue for the development of novel composite protection coatings of Mg alloys.展开更多
To reduce the usage of classical lubricants in deep drawing,a new tribological system based on volatile lubricants was developed.Therefore,a volatile medium is injected under high pressure into the interstice between ...To reduce the usage of classical lubricants in deep drawing,a new tribological system based on volatile lubricants was developed.Therefore,a volatile medium is injected under high pressure into the interstice between drawing tool and sheet metal.Depending on temperature and pressure,the temporary lubricant may exist in its gaseous or liquid phase.In this study,a novel high fluid pressure tribometer was designed to investigate the friction and wear of dry steel contacts under comparable conditions like in dry deep drawing.Therefore,a new ball-on-disc tribometer was designed and integrated into a high-pressure vessel.To specifically investigate the effects of different environments(technical air,liquid and gaseous carbon dioxide,nitrogen,argon)at atmospheric and high pressure(0.1 MPa,6 MPa)on tribology,the specimens and all components were operating unlubricated.During the experiments,the friction was measured continuously.Results show that the highest friction occurs in air and the lowest in carbon dioxide environment.Subsequent to the experiments,the wear of the specimens was assessed along with changes in surface chemistry related to tribochemical reactions.Therefore,the tribology of the dry sliding contacts is correlated to changes of the surface chemistry.Also differences as well as similarities regarding the different fluid environments are shown.As the results show,the differences between the media used are most pronounced at elevated pressure.Concluding,this work gives clear indications on the suitability of volatile lubricants in dry friction or rather gas lubrication,especially for dry deep drawing.展开更多
基金Authors would like to appreciate the former chief of Faculty of Materials&Manufacturing Processes of the Malek-Ashtar University of Technology,Professor EHSANI and the chief of the Composite Department,Dr.POURHOSSEINI along with the Razi and Kimiazi SEM labs and mechanical properties and SEM labs of Iran University of Science and Technology.Furthermore,the authors would like to thank Professor REZAEI,Ms.HAMIDI,and Ms.DAYYANI,Mr.SA'ADAT,and Mr.ATAEI from Iran University of Science and Technology.Special thanks to Mrs.KESHAVARZ,Ms.HAMEDANIZADEH,Ms.SHABANI,Ms.SHOJAEI and Mr.GANDOMKAR for their help and support.
文摘Tribological behavior and wear mechanisms of mechanically milled Al5083 alloy and Al5083−5wt.%B4C composite at room temperature and 200°C were discussed.Results revealed that due to the oxidative wear at room temperature,a mechanically mixed layer(MML)was formed to protect the surface of the samples.Under 80 N of load at room temperature,the milled Al5083 and the Al5083−5wt.%B4C samples showed evidence of abrasion with limited volume loss.In this case,the wear rates were 5.8×10−7 and 4.4×10−7 mm3/(m·N),respectively.At 200°C and under 80 N of applied load,severe wear occurred in the milled Al5083 sample,and wear rate reached 10.8×10−7 mm3/(m·N)while the Al5083−5wt.%B4C sample showed mild wear with local 3-body abrasion and the wear rate reached 5.3×10−7 mm3/(m·N).Strengthening mechanisms such as dislocation pinning and the Hall−Petch theory,high hardness and the load transfer effect were crucial in determining the wear behavior of the Al5083−5wt.%B4C composite.On the other hand,the milled Al5083 sample represented a relatively high wear rate at 200°C,which seemed to be related to the local grain growth and a drop in its hardness.
基金the National Natural Science Foundation of China(Grant number 51771178)Shaanxi Outstanding Youth Fund project(Grant number 2021JC-45)+2 种基金Key international cooperation projects in Shaanxi Province(Grant number 2020KWZ-007)the Major Program of Science and Technology in Shaanxi Province(Grant number20191102006)Open Fund of State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body(Grant number 32115019)。
文摘The poor corrosion and wear resistances of Mg alloys seriously limit their potential applications in various industries.The conventional epoxy coating easily forms many intrinsic defects during the solidification process,which cannot provide sufficient protection.In the current study,we design a double-layer epoxy composite coating on Mg alloy with enhanced anti-corrosion/wear properties,via the spin-assisted assembly technique.The outer layer is functionalized graphene(FG)in waterborne epoxy resin(WEP)and the inner layer is Ce-based conversion(Ce)film.The FG sheets can be homogeneously dispersed within the epoxy matrix to fill the intrinsic defects and improve the barrier capability.The Ce film connects the outer layer with the substrate,showing the transition effect.The corrosion rate of Ce/WEP/FG composite coating is 2131 times lower than that of bare Mg alloy,and the wear rate is decreased by~90%.The improved corrosion resistance is attributed to the labyrinth effect(hindering the penetration of corrosive medium)and the obstruction of galvanic coupling behavior.The synergistic effect derived from the FG sheet and blocking layer exhibits great potential in realizing the improvement of multi-functional integration,which will open up a new avenue for the development of novel composite protection coatings of Mg alloys.
文摘To reduce the usage of classical lubricants in deep drawing,a new tribological system based on volatile lubricants was developed.Therefore,a volatile medium is injected under high pressure into the interstice between drawing tool and sheet metal.Depending on temperature and pressure,the temporary lubricant may exist in its gaseous or liquid phase.In this study,a novel high fluid pressure tribometer was designed to investigate the friction and wear of dry steel contacts under comparable conditions like in dry deep drawing.Therefore,a new ball-on-disc tribometer was designed and integrated into a high-pressure vessel.To specifically investigate the effects of different environments(technical air,liquid and gaseous carbon dioxide,nitrogen,argon)at atmospheric and high pressure(0.1 MPa,6 MPa)on tribology,the specimens and all components were operating unlubricated.During the experiments,the friction was measured continuously.Results show that the highest friction occurs in air and the lowest in carbon dioxide environment.Subsequent to the experiments,the wear of the specimens was assessed along with changes in surface chemistry related to tribochemical reactions.Therefore,the tribology of the dry sliding contacts is correlated to changes of the surface chemistry.Also differences as well as similarities regarding the different fluid environments are shown.As the results show,the differences between the media used are most pronounced at elevated pressure.Concluding,this work gives clear indications on the suitability of volatile lubricants in dry friction or rather gas lubrication,especially for dry deep drawing.
