A distributed feedback diode laser （DFB-DL） based hygrometer combined with a long-path-length Herriot gas cell and waterless optical components was proposed and investigated. The main function of this sensor was to ...A distributed feedback diode laser （DFB-DL） based hygrometer combined with a long-path-length Herriot gas cell and waterless optical components was proposed and investigated. The main function of this sensor was to simultaneously improve the measurement reliability and resolution. A comparison test between a 10-cm normal transmission-type gas cell and a 3-m Herriot gas cell was carried out to demonstrate the improvement. Reliability improvement was achieved by influence suppression of water vapor inside optical components （WVOC） through combined action of the Herriot gas cell and waterless optical components. The influence of WVOC was suppressed from 726ppmv to 25ppmv using the Herriot gas cell. Moreover, combined with waterless optical components, the influence of WVOC was further suppressed to no more than 4ppmv. Resolution improvement from l l.7ppmv to 0.32ppmv was achieved mainly due to the application of the long-path-length Herriot gas cell. The results show that the proposed sensor has a good performance and considerable potential application in gas sensing, especially when probed gas possibly permeates into optical components.展开更多
This study investigated the partitioning behavior of dissolved organic matter（DOM） in liquid and ice phases, as well as the changes in the optical properties and chlorine reactivity of DOM during the freezing proces...This study investigated the partitioning behavior of dissolved organic matter（DOM） in liquid and ice phases, as well as the changes in the optical properties and chlorine reactivity of DOM during the freezing processes of water. DOM was rejected from the ice phase and accumulated in the remaining liquid phase during water freezing. Moreover, the decrease in freezing temperature, as well as the increase in dissolved organic carbon（DOC）concentration of feed water, caused an increase in DOM captured in the ice phase. The ultraviolet-absorbing compounds, trihalomethane precursors, as well as fulvic acid- and humic acid-like fluorescent materials, were more liable to be to be rejected from the ice phase and were more easily retained in the unfrozen liquid phase during water freezing, as compared with organics（on average） that comprise DOC. In addition, it was also found a higher accumulation of these organics in the unfrozen liquid phase during water freezing at higher temperature. The freeze/thaw processes altered the quantity, optical properties, and chlorine reactivity of DOM. The decrease in ultraviolet light at 254 nm as well as the production of aromatic protein- and soluble microbial byproduct-like fluorescent materials in DOM due to freeze/thaw were consistently observed. On the other hand, the changes in DOC, trihalomethane formation potential, and fulvic acid- and humic acid-like fluorescence caused by freeze/thaw varied significantly between samples.展开更多
基金This work was supported by the National Natural Science Foundation of China （60977058 ＆ 61475085）, the Science and Technology Development Project of Shandong Province （2014GGX101007）, and the Fundamental Research Funds of Shandong University （2014YQ011）.
文摘A distributed feedback diode laser （DFB-DL） based hygrometer combined with a long-path-length Herriot gas cell and waterless optical components was proposed and investigated. The main function of this sensor was to simultaneously improve the measurement reliability and resolution. A comparison test between a 10-cm normal transmission-type gas cell and a 3-m Herriot gas cell was carried out to demonstrate the improvement. Reliability improvement was achieved by influence suppression of water vapor inside optical components （WVOC） through combined action of the Herriot gas cell and waterless optical components. The influence of WVOC was suppressed from 726ppmv to 25ppmv using the Herriot gas cell. Moreover, combined with waterless optical components, the influence of WVOC was further suppressed to no more than 4ppmv. Resolution improvement from l l.7ppmv to 0.32ppmv was achieved mainly due to the application of the long-path-length Herriot gas cell. The results show that the proposed sensor has a good performance and considerable potential application in gas sensing, especially when probed gas possibly permeates into optical components.
基金supported by the National Natural Science Foundation of China (No. 21107039)the Science and Technology Research Project of Liaoning Provincial Education Department (Nos. L2011002, L2012006)+1 种基金the Science and Technology Plan Project of Liaoning Province (No. 2011230009)the Natural Science Foundation of Liaoning Province of China (No. 201202091)
文摘This study investigated the partitioning behavior of dissolved organic matter（DOM） in liquid and ice phases, as well as the changes in the optical properties and chlorine reactivity of DOM during the freezing processes of water. DOM was rejected from the ice phase and accumulated in the remaining liquid phase during water freezing. Moreover, the decrease in freezing temperature, as well as the increase in dissolved organic carbon（DOC）concentration of feed water, caused an increase in DOM captured in the ice phase. The ultraviolet-absorbing compounds, trihalomethane precursors, as well as fulvic acid- and humic acid-like fluorescent materials, were more liable to be to be rejected from the ice phase and were more easily retained in the unfrozen liquid phase during water freezing, as compared with organics（on average） that comprise DOC. In addition, it was also found a higher accumulation of these organics in the unfrozen liquid phase during water freezing at higher temperature. The freeze/thaw processes altered the quantity, optical properties, and chlorine reactivity of DOM. The decrease in ultraviolet light at 254 nm as well as the production of aromatic protein- and soluble microbial byproduct-like fluorescent materials in DOM due to freeze/thaw were consistently observed. On the other hand, the changes in DOC, trihalomethane formation potential, and fulvic acid- and humic acid-like fluorescence caused by freeze/thaw varied significantly between samples.
