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模拟ThO2辐照靶件中微量233U提取工艺研究 被引量:1
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作者 邓建 何遥 谢翔 《同位素》 CAS 2020年第6期329-337,共9页
为了从模拟ThO2辐照靶件中分离提取微量铀,系统考察了基于TBP萃取剂的溶剂萃取法和基于Dowex 1×8阴离子交换树脂的离子交换法的工艺参数。在最优工艺条件下,通过比较铀回收率、铀中钍及裂变产物的去污因子、分离流程耗时及废物产... 为了从模拟ThO2辐照靶件中分离提取微量铀,系统考察了基于TBP萃取剂的溶剂萃取法和基于Dowex 1×8阴离子交换树脂的离子交换法的工艺参数。在最优工艺条件下,通过比较铀回收率、铀中钍及裂变产物的去污因子、分离流程耗时及废物产生量等关键工艺参数,系统评估了这两种方法从钍中分离提取微量铀的优缺点。结果表明,在小批量样品分离中(5~10 g ThO2),阴离子交换法优于溶剂萃取法,该工艺得到的铀产品中裂变产物的含量均小于0.01%,钍的含量小于0.02%,铀的回收率为98.3%。一次流程耗时约5 h,产生废物量约500 mL。本文研究结果可为下一步辐照ThO2制备233U的台架实验及分离装置的设计与加工提供关键技术参数。 展开更多
关键词 ThO2 233U 裂片元素 溶剂萃取 离子交换
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Use of Thorium in the Generation IV Molten Salt Reactors and Perspectives for Brazil
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作者 Jose Antonio Seneda Paulo Ernesto Oliveira Lainetti 《Journal of Energy and Power Engineering》 2014年第10期1655-1662,共8页
Interest in thorium stems mainly from the fact that it is expected to have a substantial increase in uranium prices. So, advanced fuel cycles which increase the reserves of nuclear materials are interesting, particula... Interest in thorium stems mainly from the fact that it is expected to have a substantial increase in uranium prices. So, advanced fuel cycles which increase the reserves of nuclear materials are interesting, particularly, the use of thorium is to produce the fissile isotope ^233U. Thorium is three to five times more abundant than uranium in the earth's crust. Additionally, thoria produces less radiotoxicity than the UO2, because it produces fewer amounts of actinides. ThO2 has higher corrosion resistance, besides being chemically stable, and the burning of Pu in a reactor based in thorium also decreases the inventories of Pu from the current fuel cycles. There are some ongoing projects in the world, taking into consideration the proposed goals for Generation IV reactors, namely: sustainability, economics, safety and reliability, proliferation resistance and physical protection. Some developments on the use of thorium in reactors are underway, with the support of the IAEA (International Atomic Energy Agency) and some govern like molten salt reactor. In this paper, we discuss the future importance of thorium, particularly for Brazil, which has large mineral reserves of this strategic element, the characteristics of the molten salt reactor and the experience of the IPEN (Instituto de Pesquisas Energ6ticas e Nucleares) in the purification of thorium compounds. 展开更多
关键词 Molten salt reactor Generation IV reactors THORIUM uranium-233.
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