The TiO 2/SiO 2 coating particles have been prepared by a sol gel method with Ti(OC 4H 9) 4 and SiO 2 as precursors. The IR results indicate the existence of Si—O—Ti bonds on the catalyst. The crystalline phase of c...The TiO 2/SiO 2 coating particles have been prepared by a sol gel method with Ti(OC 4H 9) 4 and SiO 2 as precursors. The IR results indicate the existence of Si—O—Ti bonds on the catalyst. The crystalline phase of coating thin films(TiO 2) was studied by XRD. The amount of TiO 2 bound to the SiO 2 was determined by spectrophotometry. The TiO 2/SiO 2 can be used repeatedly and shows a higher photocatalytic decomposition rate for dichlorvos than TiO 2.展开更多
The surface organic modification of TiO2 particles with titanate coupling reagent,which was pre-coated with double layers of SiO2 and Al2O3,was studied.Experiments showed that the modified particles exhibited hydropho...The surface organic modification of TiO2 particles with titanate coupling reagent,which was pre-coated with double layers of SiO2 and Al2O3,was studied.Experiments showed that the modified particles exhibited hydrophobic characteristics.The modification state of the particle surface was characterized by IR spectroscopic measurement,pyrolytic gas chromatography,thermogravimetric analysis and X-ray photoelectron spectra.The titanate coupling reagent binding with the hydroxyl on the particle surface was analyzed.The surface characteristics of pre-modification and post-modification particles were compared.展开更多
Titanium alloys are widely used in aeronautics that demand a good combination of high strength, good corrosion resistance and low mass. The mechanical properties lead to challenges in machining operations such as high...Titanium alloys are widely used in aeronautics that demand a good combination of high strength, good corrosion resistance and low mass. The mechanical properties lead to challenges in machining operations such as high process temperature as well as rapidly increasing tool wear. The conventional tool materials are not able to maintain their hardness and other mechanical prop- erties at higher cutting temperatures encountered in high speed machining. In this work, the new material tools, which are poly- crystalline diamond （PCD） and polycrystalline cubic boron nitride （PCBN） tools, are used in high-speed milling of Ti-6.5AI-2Zr-IMo-IV （TA15） alloy. The performance and wear mechanism of the tools are investigated. Compared to PCBN tool, PCD tool has a much longer tool life, especially at higher cutting speeds. Analyses based on the SEM and EDX suggest that attrition, adhesion and diffusion are the main wear mechanisms of PCD and PCBN tools in high-speed milling of TA 15. Oxida- tion wear is also observed at PCBN tool/workpiece interface. Roughness, defects, micro-hardness and microstructure of the ma- chined surface are investigated. The recorded surface roughness values with PCD/PCBN tools are bellow 0.3 μm at initial and steady cutting stage. Micro-hardness analysis shows that the machined surface hardening depth with PCD and PCBN tools is small. There is no evidence of sub-surface defects with PCD and PCBN tools. It is concluded that for TA15 alloy, high-speed milling can be carried out with PCD/PCBN tools.展开更多
文摘The TiO 2/SiO 2 coating particles have been prepared by a sol gel method with Ti(OC 4H 9) 4 and SiO 2 as precursors. The IR results indicate the existence of Si—O—Ti bonds on the catalyst. The crystalline phase of coating thin films(TiO 2) was studied by XRD. The amount of TiO 2 bound to the SiO 2 was determined by spectrophotometry. The TiO 2/SiO 2 can be used repeatedly and shows a higher photocatalytic decomposition rate for dichlorvos than TiO 2.
文摘The surface organic modification of TiO2 particles with titanate coupling reagent,which was pre-coated with double layers of SiO2 and Al2O3,was studied.Experiments showed that the modified particles exhibited hydrophobic characteristics.The modification state of the particle surface was characterized by IR spectroscopic measurement,pyrolytic gas chromatography,thermogravimetric analysis and X-ray photoelectron spectra.The titanate coupling reagent binding with the hydroxyl on the particle surface was analyzed.The surface characteristics of pre-modification and post-modification particles were compared.
基金National High-tech Research and Development Program of China (2009AA04Z116)Program for Changjiang Scholars and Innovative Research Team in University ( IRT0837)
文摘Titanium alloys are widely used in aeronautics that demand a good combination of high strength, good corrosion resistance and low mass. The mechanical properties lead to challenges in machining operations such as high process temperature as well as rapidly increasing tool wear. The conventional tool materials are not able to maintain their hardness and other mechanical prop- erties at higher cutting temperatures encountered in high speed machining. In this work, the new material tools, which are poly- crystalline diamond （PCD） and polycrystalline cubic boron nitride （PCBN） tools, are used in high-speed milling of Ti-6.5AI-2Zr-IMo-IV （TA15） alloy. The performance and wear mechanism of the tools are investigated. Compared to PCBN tool, PCD tool has a much longer tool life, especially at higher cutting speeds. Analyses based on the SEM and EDX suggest that attrition, adhesion and diffusion are the main wear mechanisms of PCD and PCBN tools in high-speed milling of TA 15. Oxida- tion wear is also observed at PCBN tool/workpiece interface. Roughness, defects, micro-hardness and microstructure of the ma- chined surface are investigated. The recorded surface roughness values with PCD/PCBN tools are bellow 0.3 μm at initial and steady cutting stage. Micro-hardness analysis shows that the machined surface hardening depth with PCD and PCBN tools is small. There is no evidence of sub-surface defects with PCD and PCBN tools. It is concluded that for TA15 alloy, high-speed milling can be carried out with PCD/PCBN tools.
