In order to study the gas explosion suppression performance based on ferrocene, the self-constructed experimental facility was used to accomplish the experiment of gas explosion suppression. By means of thermogravimet...In order to study the gas explosion suppression performance based on ferrocene, the self-constructed experimental facility was used to accomplish the experiment of gas explosion suppression. By means of thermogravimetric analysis, the thermal characteristics of ferrocene have been gotten and the gas explosion suppression mechanism of ferrocene has been analyzed. The results show that ferrocene had good effects on gas explosion suppression, and the explosion pressure and flame propagation speed declined obviously. When ferrocene concentration is 0.08 g/L and methane volume concentration is 9.5%, the maximum explosion overpressure and maximum flame propagation speed of methane-air respectively decreased by about 59.5% and 19.6%, respectively. TG and DSC curves showed that the mass loss of ferrocene consists of two processes, which are sublimation and lattice fracture. The temperature of mass loss ranged from 128 ℃ to 230 ℃. The results showed profoundly theoretical significance to gas explosion suppression by ferrocene in coal mines.展开更多
The pyrolysis behavior of polycarbosilane （PCS） and chemical reaction mechanism during the pyrolysis process were studied by thermogravimetric-mass spectrometry （TG-MS） combined with X-ray diffraction and infrared...The pyrolysis behavior of polycarbosilane （PCS） and chemical reaction mechanism during the pyrolysis process were studied by thermogravimetric-mass spectrometry （TG-MS） combined with X-ray diffraction and infrared spectroscopic analysis methods. The experimental results indicate that the main gas phase products generated during pyrolysis of PCS in nitrogen atmosphere include H2, -CH3 and CH4. The heating rate has a large effect on the pyrolysis process of PCS, the lower heating rate releases more small molecule gases and gets bigger rate of pyrolysis mass loss, demonstrating that the lower heating rate is beneficial to fully pyrolysis of PCS and obtain ceramics products with better microstructure.展开更多
基金Supported by the National Natural Science Foundation of China （50974055, 50476033） the Doctor Foundation Project from the Henan Polytechnic University （B2011 - 101）
文摘In order to study the gas explosion suppression performance based on ferrocene, the self-constructed experimental facility was used to accomplish the experiment of gas explosion suppression. By means of thermogravimetric analysis, the thermal characteristics of ferrocene have been gotten and the gas explosion suppression mechanism of ferrocene has been analyzed. The results show that ferrocene had good effects on gas explosion suppression, and the explosion pressure and flame propagation speed declined obviously. When ferrocene concentration is 0.08 g/L and methane volume concentration is 9.5%, the maximum explosion overpressure and maximum flame propagation speed of methane-air respectively decreased by about 59.5% and 19.6%, respectively. TG and DSC curves showed that the mass loss of ferrocene consists of two processes, which are sublimation and lattice fracture. The temperature of mass loss ranged from 128 ℃ to 230 ℃. The results showed profoundly theoretical significance to gas explosion suppression by ferrocene in coal mines.
基金Funded by the Natural Science Foundation of Hubei Province(No.2013CFB340)
文摘The pyrolysis behavior of polycarbosilane （PCS） and chemical reaction mechanism during the pyrolysis process were studied by thermogravimetric-mass spectrometry （TG-MS） combined with X-ray diffraction and infrared spectroscopic analysis methods. The experimental results indicate that the main gas phase products generated during pyrolysis of PCS in nitrogen atmosphere include H2, -CH3 and CH4. The heating rate has a large effect on the pyrolysis process of PCS, the lower heating rate releases more small molecule gases and gets bigger rate of pyrolysis mass loss, demonstrating that the lower heating rate is beneficial to fully pyrolysis of PCS and obtain ceramics products with better microstructure.
