Electronics, such as printed circuit board （PCB）, transistor, radio frequency identification （RFID）, organic light emitting diode （OLED）, solar cells, electronic display, lab on a chip （LOC）, sensor, actuator,...Electronics, such as printed circuit board （PCB）, transistor, radio frequency identification （RFID）, organic light emitting diode （OLED）, solar cells, electronic display, lab on a chip （LOC）, sensor, actuator, and transducer etc. are playing increasingly important roles in people＇s daily life. Conventional fabrication strategy towards integrated circuit working steps, generally （IC）, requesting at least six consumes too much energy, material and water, and is not environmentally friendly. During the etching process, a large amount of raw materials have to be abandoned. Besides, lithography and microfabrication are typically carried out in ＂Clean room＂ which restricts the location of IC fabrication and leads to high production costs. As an alternative, the newly emerging inkjet printing electronics are gradually shaping modem electronic industry and its related areas, owing to the invention of a series of conductive inks composed of polymer matrix, conductive fillers, solvents and additives. Nevertheless, the currently available methods also encoun ter some technical troubles due to the low electroconduc tivity, complex sythesis and sintering process of the inks. As an alternative, a fundamentally different strategy was recently proposed by the authors＇ lab towards truly direct writing of electronics through introduction of a new class of conductive inks made of low melting point liquid metal or its alloy. The method has been named as direct writingof electronics based on alloy series of functional circuits, and metal （DREAM） ink. A sensors, electronic elements and devices can thus be easily written on various either soft or rigid substrates in a moment. With more and more technical progresses and fundamental discoveries being kept made along this category, it was found that a new area enabled by the DREAM ink electronics is emerging, which would have tremendous impacts on future energy and environmental sciences. In order to promote the research and development along this direction展开更多
A quantitative model was applied to analyze the energy demand and CO2 emissions in China following the Energy Production and Consumption Revolution Strategy(2016e2030)and long-term economic and social development targ...A quantitative model was applied to analyze the energy demand and CO2 emissions in China following the Energy Production and Consumption Revolution Strategy(2016e2030)and long-term economic and social development target China Dream.Results showed that 1)toward the 2050 China Dream target,total final energy consumption is expected to peak at 3.9 Gtce in 2030 and remain stable until 2050,whereas total primary energy consumption is expected to reach an upper platform by 2040 and around 5.8 Gtce by 2050;2)the proportion of non-fossil fuels is expected to reach approximately 50%and that of natural gas to reach more than 16%by 2050;3)CO2 emissions from energy use are expected to peak at 9.6 Gt by no later than 2030 and then gradually decline to 6.7 Gt by 2050.展开更多
Carbon dioxide capture,utilization and storage(CCUS)eincluding conversion to valuable chemicals-is a challenging contemporary issue having multi-facets.The prospect to utilize carbon dioxide(CO_(2))as a feedstock for ...Carbon dioxide capture,utilization and storage(CCUS)eincluding conversion to valuable chemicals-is a challenging contemporary issue having multi-facets.The prospect to utilize carbon dioxide(CO_(2))as a feedstock for synthetic applications in chemical and fuel industries-through carboxylation and reduction reactions-is the subject of this review.Current statute of the heterogeneously catalyzed hydrogenation,as well as the photocatalytic and electrocatalytic activations of conversion of CO_(2) to value-added chemicals is overviewed.Envisaging CO_(2) as a viable alternative to natural gas and oil as carbon resource for the chemical supply chain,three stages of development;namely,(i)existing mature technologies(such as urea production),(ii)emerging technologies(such as formic acid or other single carbon(C1)chemicals manufacture)and(iii)innovative explorations(such as electrocatalytic ethylene production)have been identified and highlighted.A unique aspect of this review is the exploitations of reactions of CO2 ewhich stems from existing petrochemical plants-with the commodity petrochemicals(such as,methanol,ethylene and ethylene oxide)produced at the same or nearby complex in order to obtain value-added products while contributing also to CO_(2) fixation simultaneously.Exemplifying worldwide ethylene oxide facilities,it is recognized that they produce about 3 million tons of CO2 annually.Such a CO_(2) resource,which is already separated in pure form as a requirement of the process,should best be converted to a value-added chemical there avoiding current practice of discharging to the atmosphere.The potential utilization of CO_(2),captured at power plants,should also been taken into consideration for sustainability.This CO_(2) source,which is potentially a raw material for the chemical industry,will be available at sufficient quality and at gigantic quantity upon realization of on-going tangible capture projects.Products resulting from carboxylation reactions are obvious conversions.In addition,provided that enough s展开更多
文摘Electronics, such as printed circuit board （PCB）, transistor, radio frequency identification （RFID）, organic light emitting diode （OLED）, solar cells, electronic display, lab on a chip （LOC）, sensor, actuator, and transducer etc. are playing increasingly important roles in people＇s daily life. Conventional fabrication strategy towards integrated circuit working steps, generally （IC）, requesting at least six consumes too much energy, material and water, and is not environmentally friendly. During the etching process, a large amount of raw materials have to be abandoned. Besides, lithography and microfabrication are typically carried out in ＂Clean room＂ which restricts the location of IC fabrication and leads to high production costs. As an alternative, the newly emerging inkjet printing electronics are gradually shaping modem electronic industry and its related areas, owing to the invention of a series of conductive inks composed of polymer matrix, conductive fillers, solvents and additives. Nevertheless, the currently available methods also encoun ter some technical troubles due to the low electroconduc tivity, complex sythesis and sintering process of the inks. As an alternative, a fundamentally different strategy was recently proposed by the authors＇ lab towards truly direct writing of electronics through introduction of a new class of conductive inks made of low melting point liquid metal or its alloy. The method has been named as direct writingof electronics based on alloy series of functional circuits, and metal （DREAM） ink. A sensors, electronic elements and devices can thus be easily written on various either soft or rigid substrates in a moment. With more and more technical progresses and fundamental discoveries being kept made along this category, it was found that a new area enabled by the DREAM ink electronics is emerging, which would have tremendous impacts on future energy and environmental sciences. In order to promote the research and development along this direction
基金We thank National Key R&D Program of China(2016YFA0602601),National Natural Science Foundation of China(71573062),China Energy Modeling Forum(CEMF),for support of the study.
文摘A quantitative model was applied to analyze the energy demand and CO2 emissions in China following the Energy Production and Consumption Revolution Strategy(2016e2030)and long-term economic and social development target China Dream.Results showed that 1)toward the 2050 China Dream target,total final energy consumption is expected to peak at 3.9 Gtce in 2030 and remain stable until 2050,whereas total primary energy consumption is expected to reach an upper platform by 2040 and around 5.8 Gtce by 2050;2)the proportion of non-fossil fuels is expected to reach approximately 50%and that of natural gas to reach more than 16%by 2050;3)CO2 emissions from energy use are expected to peak at 9.6 Gt by no later than 2030 and then gradually decline to 6.7 Gt by 2050.
基金Authors gratefully acknowledge Hasan Arslan,Senior Process Consultant,PTTGC America,for the hindsight provided for matured and developing petrochemical processes.
文摘Carbon dioxide capture,utilization and storage(CCUS)eincluding conversion to valuable chemicals-is a challenging contemporary issue having multi-facets.The prospect to utilize carbon dioxide(CO_(2))as a feedstock for synthetic applications in chemical and fuel industries-through carboxylation and reduction reactions-is the subject of this review.Current statute of the heterogeneously catalyzed hydrogenation,as well as the photocatalytic and electrocatalytic activations of conversion of CO_(2) to value-added chemicals is overviewed.Envisaging CO_(2) as a viable alternative to natural gas and oil as carbon resource for the chemical supply chain,three stages of development;namely,(i)existing mature technologies(such as urea production),(ii)emerging technologies(such as formic acid or other single carbon(C1)chemicals manufacture)and(iii)innovative explorations(such as electrocatalytic ethylene production)have been identified and highlighted.A unique aspect of this review is the exploitations of reactions of CO2 ewhich stems from existing petrochemical plants-with the commodity petrochemicals(such as,methanol,ethylene and ethylene oxide)produced at the same or nearby complex in order to obtain value-added products while contributing also to CO_(2) fixation simultaneously.Exemplifying worldwide ethylene oxide facilities,it is recognized that they produce about 3 million tons of CO2 annually.Such a CO_(2) resource,which is already separated in pure form as a requirement of the process,should best be converted to a value-added chemical there avoiding current practice of discharging to the atmosphere.The potential utilization of CO_(2),captured at power plants,should also been taken into consideration for sustainability.This CO_(2) source,which is potentially a raw material for the chemical industry,will be available at sufficient quality and at gigantic quantity upon realization of on-going tangible capture projects.Products resulting from carboxylation reactions are obvious conversions.In addition,provided that enough s
