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高分子体系相分离动力学及图样生成和选择 被引量:3
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作者 杨玉良 邱枫 +1 位作者 唐萍 张红东 《化学进展》 SCIE CAS CSCD 北大核心 2006年第4期363-381,共19页
高分子共混物的混合熵很小导致其多为热力学不相容体系而发生相分离,形成特定的时空图样。本文根据多年来我们的研究工作并结合实例,基于时间分辨的Ginzberg-Landau方法研究高分子复杂体系相分离动力学及图样选择,重点介绍剪切外场下高... 高分子共混物的混合熵很小导致其多为热力学不相容体系而发生相分离,形成特定的时空图样。本文根据多年来我们的研究工作并结合实例,基于时间分辨的Ginzberg-Landau方法研究高分子复杂体系相分离动力学及图样选择,重点介绍剪切外场下高分子共混物及嵌段高分子的相分离,耦合化学反应的相分离,在弯曲曲面特别是球面上的相分离,以及TDGL与密度泛函理论的有机结合即动态自洽场理论在具有不同链拓扑结构的嵌段高分子体系中研究相分离动力学。 展开更多
关键词 tdgl方程 剪切 嵌段高分子 化学反应 曲面微分几何 动态自洽场理论
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两嵌段共聚物在闭合球壳内的相分离 被引量:3
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作者 许汇 李剑锋 +1 位作者 张红东 杨玉良 《高分子学报》 SCIE CAS CSCD 北大核心 2011年第5期548-553,共6页
嵌段共聚物所形成特定的空间图样,其微观形态不仅与各组分之间的相互作用以及各组分的含量有关,嵌段的空间受限状况也会对分相形态造成一定的影响.为了研究受限于球壳内的线型AB两嵌段共聚物的相分离行为,构建了适用于闭合球壳空间的Lap... 嵌段共聚物所形成特定的空间图样,其微观形态不仅与各组分之间的相互作用以及各组分的含量有关,嵌段的空间受限状况也会对分相形态造成一定的影响.为了研究受限于球壳内的线型AB两嵌段共聚物的相分离行为,构建了适用于闭合球壳空间的Laplace-Beltrami算子,并运用TDGL(time dependent Ginzburg-Landau)介观动力学方程,对在不同尺寸的球壳中发生的相分离行为进行分析,关注的重点是球壳的半径和厚度对微观形态的影响.通过对分相形态和不同组分在球壳内分布的考察表明,随着球壳半径和厚度的增加,高分子链所受到的空间限制减小,其在球壳内的分相形态的规整性随之降低.尤其是在球壳的厚度增加时,非对称线性AB两嵌段共聚物的不同嵌段在球壳内的浓度分布发生明显变化. 展开更多
关键词 闭合球壳 tdgl方程 两嵌段共聚物
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Linear Stability and Nonlinear Analysis of an Extended Optimal Velocity Model Considering the Speed Limit 被引量:1
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作者 Guangzhu He Cuncai Hua 《Journal of Applied Mathematics and Physics》 2020年第3期507-518,共12页
In this paper, an extended car-following model is proposed based on an optimal velocity model (OVM), which takes the speed limit into consideration. The model is analyzed by using the linear stability theory and nonli... In this paper, an extended car-following model is proposed based on an optimal velocity model (OVM), which takes the speed limit into consideration. The model is analyzed by using the linear stability theory and nonlinear analysis method. The linear stability condition shows that the speed limit can enlarge the stable region of traffic flow. By applying the reductive perturbation method, the time-dependent Ginzburg-Landau (TDGL) equation and the modified Korteweg-de Vries (mKdV) equation are derived to describe the traffic flow near the critical point. Furthermore, the relation between TDGL and mKdV equations is also given. It is clarified that the speed limit is essentially equivalent to the parameter adjusting of the driver’s sensitivity. 展开更多
关键词 Optimal VELOCITY Model (OVM) SPEED LIMIT tdgl equation MKDV equation
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柔性高分子/液晶共混体系的相分离初期动力学 被引量:2
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作者 林志群 张红东 杨玉良 《复旦学报(自然科学版)》 CAS CSCD 北大核心 1997年第4期370-378,共9页
由Flory-Huggins的柔性高分子溶液的格子模型和Lebwohl-Lasher液晶模型结合起来导出的高分子/液晶复合体系的混合自由能泛函,并引入TDGL方程以用描述体系的相分离动力学.线性化理论的计算结果表明.高分子/液晶复合体系的相分离... 由Flory-Huggins的柔性高分子溶液的格子模型和Lebwohl-Lasher液晶模型结合起来导出的高分子/液晶复合体系的混合自由能泛函,并引入TDGL方程以用描述体系的相分离动力学.线性化理论的计算结果表明.高分子/液晶复合体系的相分离初期行为与描述普通两元熔体的相分离初期的Cahn-Hilliard理论结果十分相似,即在Spinodal区域内,浓度涨落(即散射光强)随时间变化呈指数式增长,而散射函数的峰值位置(qm),则不随时间而改变.另外,高分子/液晶体系有两个Spinodal相区域,即各向异性Spinodal相区域和各向同性Spinodal相区域.而且,处在各向异性态的液晶能强烈地排斥柔性高分子,因而在各向异性相区域的相分离初期速度要比各向同性区域快得多,散射光强也要强得多. 展开更多
关键词 tdgl方程 相分离 高聚物 液晶 动力学 共混
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The time-dependent Ginzburg-Landau equation for the two-velocity difference model
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作者 吴淑贞 程荣军 葛红霞 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第8期130-135,共6页
A thermodynamic theory is formulated to describe the phase transition and critical phenomenon in traffic flow. Based on the two-velocity difference model, the time-dependent Ginzburg-Landau (TDGL) equation under cer... A thermodynamic theory is formulated to describe the phase transition and critical phenomenon in traffic flow. Based on the two-velocity difference model, the time-dependent Ginzburg-Landau (TDGL) equation under certain condition is derived to describe the traffic flow near the critical point through the nonlinear analytical method. The corresponding two solutions, the uniform and the kink solutions, are given. The coexisting curve, spinodal line and critical point are obtained by the first and second derivatives of the thermodynamic potential. The modified Korteweg- de Vries (mKdV) equation around the critical point is derived by using the reductive perturbation method and its kink antikink solution is also obtained. The relation between the TDGL equation and the mKdV equation is shown. The simulation result is consistent with the nonlinear analytical result. 展开更多
关键词 traffic flow two-velocity difference model tdgl equation mKdV equation
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ENERGY STABLE NUMERICAL METHOD FOR THE TDGL EQUATION WITH THE RETICULAR FREE ENERGY IN HYDROGEL
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作者 Dong Liao Hui Zhang Zhengru Zhang 《Journal of Computational Mathematics》 SCIE CSCD 2017年第1期37-51,共15页
Here we focus on the numerical simulation of the phase separation about macromolecule microsphere composite (MMC) hydrogel. The model is based on time-dependent Ginzburg- Landau (TDGL) equation with the reticular ... Here we focus on the numerical simulation of the phase separation about macromolecule microsphere composite (MMC) hydrogel. The model is based on time-dependent Ginzburg- Landau (TDGL) equation with the reticular free energy. An unconditionally energy stable difference scheme is proposed based on the convex splitting of the corresponding energy functional. In the numerical experiments, we observe that simulating the whole process of the phase separation requires a considerably long time. We also notice that the total free energy changes significantly in initial stage and varies slightly in the following time. Based on these properties, we apply the adaptive time stepping strategy to improve the computational efficiency. It is found that the application of time step adaptivity can not only resolve the dynamical changes of the solution accurately but also significantly save CPU time for the long time simulation. 展开更多
关键词 tdgl equation Unconditionally energy stable scheme Adaptive time-steppingmethod Phase transition.
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BCS-BEC过渡区原子费米气体的动态性研究
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作者 官金兰 房少梅 《佛山科学技术学院学报(自然科学版)》 CAS 2014年第4期5-12,共8页
研究BCS-BEC过渡区原子费米气体依赖时间的Ginzburg-Landau方程的平面波解及其动态性。主要研究该方程各个系数a、b、c、d之间的关系,以及原子费米气体的化学势?和能量阀值2v,温度T和极化率h之间的关系。
关键词 tdgl方程 GL系数 平面波解 化学势 能量阀值
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Nonlinear density wave and energy consumption investigation of traffic flow on a curved road 被引量:1
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作者 金智展 程荣军 葛红霞 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第11期135-143,共9页
A new car-following model is proposed based on the full velocity difference model(FVDM) taking the influence of the friction coefficient and the road curvature into account. Through the control theory, the stability... A new car-following model is proposed based on the full velocity difference model(FVDM) taking the influence of the friction coefficient and the road curvature into account. Through the control theory, the stability conditions are obtained,and by using nonlinear analysis, the time-dependent Ginzburg-Landau(TDGL) equation and the modified Korteweg-de Vries(mKdV) equation are derived. Furthermore, the connection between TDGL and mKdV equations is also given. The numerical simulation is consistent with the theoretical analysis. The evolution of a traffic jam and the corresponding energy consumption are explored. The numerical results show that the control scheme is effective not only to suppress the traffic jam but also to reduce the energy consumption. 展开更多
关键词 car-following model curved road energy consumption time-dependent Ginzburg-Landau(tdgl equation
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