Sustainable design, green architecture and sustainable construction are new methods for design and construction that are employed for environmental and economic challenges. Clay and bricks proved as sustainable buildi...Sustainable design, green architecture and sustainable construction are new methods for design and construction that are employed for environmental and economic challenges. Clay and bricks proved as sustainable building materials. In this paper, crush brick in the concrete mixture instead of normal coarse aggregate will be used. STAAD Prov8i software was applied for the designed of a hypothetical building in different sites of the three locations in Iraq (Mosul at the north, Baghdad at the center and Basrah at the south). The input model data used in the software were depending on the field and laboratory tests done for twenty three sites in the three locations of Iraq. Concrete properties values were used in the software for concrete mixture with crushed bricks. The results values of base pressure obtained from the software were low for the three locations. The maximum values of base pressure under the foundation for both the average and the minimum bearing capacity values for Mosul region for the normal strength concrete and air-entrained were (94, 84) kPa and (91, 82) kPa respectively, for Baghdad region were (89, 82) kPa and (86, 81) kPa respectively. Finally, for Basrah, the results for the base pressure were (84, 77) kPa and (82, 76) kPa, respectively. The results values of the base pressure were less for all locations compared with the base pressure values obtained from a previous work for the same locations. The use of crushed brick as aggregate in the concrete mixture is economical due to its availability as local material and it is durable materials with low weight.展开更多
Eggshells are among the emerging hazardous waste from the food processing industry. This work sought to valorize waste guinea fowl eggshells. Guinea fowl eggshells (GFEs) were evaluated in the production of CaO for ch...Eggshells are among the emerging hazardous waste from the food processing industry. This work sought to valorize waste guinea fowl eggshells. Guinea fowl eggshells (GFEs) were evaluated in the production of CaO for chemical and industrial application. The functionality, thermal stability, elemental composition, phase distribution and surface morphology properties of uncalcined GFEs and GFEs calcined at 700°C, 800°C, 900°C, 1000°C and 1100°C were systematically studied by FTIR, TGA, XRF, XRD and SEM-EDX respectively. The elemental analysis revealed Ca as the main element in the GFEs. The uncalcined GFEs showed intense peaks that corresponded to calcite (CaCO3) phases. These transformed into Ca(OH)2 as the temperature of calcination increased and finally to CaO in the FTIR analysis. In the XRD diffractograms, the main peaks at 2θ values were 29.466° for the uncalcined GFESs and at 37.377° for the sample treated at 1100°C. The phases were confirmed as CaO when compared with JCPDS files. Using the Scherer equation, the CaO crystallite size for the sample calcined at 1100°C was found to be 50.68 nm along the (2 0 0) orientation. All the samples showed multi-step decomposition patterns in the thermogravimetric analyses (TGA), with weight loss of up to 47% for the uncalcined GFEs sample, which was mainly due to the transformation of the calcite (CaCO3) phase to CaO by removal of bound water, organic components, and CO2. Samples calcined at 1100°C showed mainly CaO phases in XRD analyses and fairly stable with 7% loss in weight after treatment at 800°C. SEM images of samples calcined at 900°C were irregular compared to samples treated at 1100°C. EDX data revealed that the surface structure was 100% calcium and oxygen. GFEs are a potential source of pure calcium oxide for various industrial uses.展开更多
文摘Sustainable design, green architecture and sustainable construction are new methods for design and construction that are employed for environmental and economic challenges. Clay and bricks proved as sustainable building materials. In this paper, crush brick in the concrete mixture instead of normal coarse aggregate will be used. STAAD Prov8i software was applied for the designed of a hypothetical building in different sites of the three locations in Iraq (Mosul at the north, Baghdad at the center and Basrah at the south). The input model data used in the software were depending on the field and laboratory tests done for twenty three sites in the three locations of Iraq. Concrete properties values were used in the software for concrete mixture with crushed bricks. The results values of base pressure obtained from the software were low for the three locations. The maximum values of base pressure under the foundation for both the average and the minimum bearing capacity values for Mosul region for the normal strength concrete and air-entrained were (94, 84) kPa and (91, 82) kPa respectively, for Baghdad region were (89, 82) kPa and (86, 81) kPa respectively. Finally, for Basrah, the results for the base pressure were (84, 77) kPa and (82, 76) kPa, respectively. The results values of the base pressure were less for all locations compared with the base pressure values obtained from a previous work for the same locations. The use of crushed brick as aggregate in the concrete mixture is economical due to its availability as local material and it is durable materials with low weight.
文摘Eggshells are among the emerging hazardous waste from the food processing industry. This work sought to valorize waste guinea fowl eggshells. Guinea fowl eggshells (GFEs) were evaluated in the production of CaO for chemical and industrial application. The functionality, thermal stability, elemental composition, phase distribution and surface morphology properties of uncalcined GFEs and GFEs calcined at 700°C, 800°C, 900°C, 1000°C and 1100°C were systematically studied by FTIR, TGA, XRF, XRD and SEM-EDX respectively. The elemental analysis revealed Ca as the main element in the GFEs. The uncalcined GFEs showed intense peaks that corresponded to calcite (CaCO3) phases. These transformed into Ca(OH)2 as the temperature of calcination increased and finally to CaO in the FTIR analysis. In the XRD diffractograms, the main peaks at 2θ values were 29.466° for the uncalcined GFESs and at 37.377° for the sample treated at 1100°C. The phases were confirmed as CaO when compared with JCPDS files. Using the Scherer equation, the CaO crystallite size for the sample calcined at 1100°C was found to be 50.68 nm along the (2 0 0) orientation. All the samples showed multi-step decomposition patterns in the thermogravimetric analyses (TGA), with weight loss of up to 47% for the uncalcined GFEs sample, which was mainly due to the transformation of the calcite (CaCO3) phase to CaO by removal of bound water, organic components, and CO2. Samples calcined at 1100°C showed mainly CaO phases in XRD analyses and fairly stable with 7% loss in weight after treatment at 800°C. SEM images of samples calcined at 900°C were irregular compared to samples treated at 1100°C. EDX data revealed that the surface structure was 100% calcium and oxygen. GFEs are a potential source of pure calcium oxide for various industrial uses.
