In order to expand the study on flow instability of supercritical circulating fluidized bed(CFB) boiler,a new numerical computational model considering the heat storage of the tube wall metal was presented in this pap...In order to expand the study on flow instability of supercritical circulating fluidized bed(CFB) boiler,a new numerical computational model considering the heat storage of the tube wall metal was presented in this paper.The lumped parameter method was proposed for wall temperature calculation and the single channel model was adopted for the analysis of flow instability.Based on the time-domain method,a new numerical computational program suitable for the analysis of flow instability in the water wall of supercritical CFB boiler with annular furnace was established.To verify the code,calculation results were respectively compared with data of commercial software.According to the comparisons,the new code was proved to be reasonable and accurate for practical engineering application in analysis of flow instability.Based on the new program,the flow instability of supercritical CFB boiler with annular furnace was simulated by time-domain method.When 1.2 times heat load disturbance was applied on the loop,results showed that the inlet flow rate,outlet flow rate and wall temperature fluctuated with time eventually remained at constant values,suggesting that the hydrodynamic flow was stable.The results also showed that in the case of considering the heat storage,the flow in the water wall is easier to return to stable state than without considering heat storage.展开更多
Hydrogen storage receives the worldwide attention due to its importance in sustainable energy and the solution of greenhouse effect.Adsorption provides an efficient way to compress gases and,therefore, has been applie...Hydrogen storage receives the worldwide attention due to its importance in sustainable energy and the solution of greenhouse effect.Adsorption provides an efficient way to compress gases and,therefore, has been applied to the development of hydrogen storage technology.However,hydrogen is a super- critical gas at the temperature of engineering interest and follows a different adsorption mechanism compared to the sub-critical gases.The present work shows why only monolayer coverage mechanism functions at above-critical temperatures and what consequences will result in the application study. Although there are pros and cons to this point of view,understanding the adsorption mechanism is,in- deed,essential for the research of hydrogen storage method since it claims that any storage material based on adsorption will not satisfy the practical need of on board storage no matter how novel the material is.展开更多
The commercial graphite(CG)is the conventional anode material for lithium ion batteries(LIBs)due to its low delithiation voltage plateau(below 0.5 V)and extraordinary durability.Nevertheless,the further promotion of e...The commercial graphite(CG)is the conventional anode material for lithium ion batteries(LIBs)due to its low delithiation voltage plateau(below 0.5 V)and extraordinary durability.Nevertheless,the further promotion of energy density of LIBs is restricted by the limited capacity below 0.5 V of CG.Here,based on the supercritical CO2 exfoliation technique,the production of multi-layered graphene(MLG)is achieved from the pilot scale production line.The great merit of the exfoliated MLG anode is that the voltage plateau below 0.5 V is broadened obviously as compared to those of natural graphite and CG.Additionally,no obvious lithium dendrites are observed for MLG during the lithiation process.The large delithiation capacity under the low voltage plateau of MLG is mainly benefited from the combination of Li intercalation and boundary storage mechanism,which is further confirmed by the density functional theory calculations.The LiFePO4/MLG full cell can afford the satisfactory electrochemical property with respect to the capacity,energy density and ultralong cycling stability(90%capacity retention after 500 cycles at 2 C),significantly better than that of LiFePO4/CG.Besides,this developed technique not only dedicates to producing the high-performance anode for LIBs but also opens a door for the mass production of MLG in the industrial scale.展开更多
基金supported by the "Strategic Priority Research Program" of the Chinese Academy of Sciences,Grant No.XDA07030100the National Key Technology R&D Program of China during the 12th Five-Year Plan Period No.2015BAA03B01-01
文摘In order to expand the study on flow instability of supercritical circulating fluidized bed(CFB) boiler,a new numerical computational model considering the heat storage of the tube wall metal was presented in this paper.The lumped parameter method was proposed for wall temperature calculation and the single channel model was adopted for the analysis of flow instability.Based on the time-domain method,a new numerical computational program suitable for the analysis of flow instability in the water wall of supercritical CFB boiler with annular furnace was established.To verify the code,calculation results were respectively compared with data of commercial software.According to the comparisons,the new code was proved to be reasonable and accurate for practical engineering application in analysis of flow instability.Based on the new program,the flow instability of supercritical CFB boiler with annular furnace was simulated by time-domain method.When 1.2 times heat load disturbance was applied on the loop,results showed that the inlet flow rate,outlet flow rate and wall temperature fluctuated with time eventually remained at constant values,suggesting that the hydrodynamic flow was stable.The results also showed that in the case of considering the heat storage,the flow in the water wall is easier to return to stable state than without considering heat storage.
基金Supported by the National Natural Science Foundation of China(Grant Nos.90510013,20336020,50376047 and 29936100)
文摘Hydrogen storage receives the worldwide attention due to its importance in sustainable energy and the solution of greenhouse effect.Adsorption provides an efficient way to compress gases and,therefore, has been applied to the development of hydrogen storage technology.However,hydrogen is a super- critical gas at the temperature of engineering interest and follows a different adsorption mechanism compared to the sub-critical gases.The present work shows why only monolayer coverage mechanism functions at above-critical temperatures and what consequences will result in the application study. Although there are pros and cons to this point of view,understanding the adsorption mechanism is,in- deed,essential for the research of hydrogen storage method since it claims that any storage material based on adsorption will not satisfy the practical need of on board storage no matter how novel the material is.
基金supported by the National Natural Science Foundation of China(Nos.21706283 and 21776308)Beijing Talents Foundation(No.2017000020124G010)+1 种基金Science Foundation of China University of Petroleum,Beijing(No.2462017YJRC003)the Joint Open Fund of Jiangsu Collaborative Innovation Center for Ecological Building Material and Environmental Protection Equipment and Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province(No.JH201812)。
文摘The commercial graphite(CG)is the conventional anode material for lithium ion batteries(LIBs)due to its low delithiation voltage plateau(below 0.5 V)and extraordinary durability.Nevertheless,the further promotion of energy density of LIBs is restricted by the limited capacity below 0.5 V of CG.Here,based on the supercritical CO2 exfoliation technique,the production of multi-layered graphene(MLG)is achieved from the pilot scale production line.The great merit of the exfoliated MLG anode is that the voltage plateau below 0.5 V is broadened obviously as compared to those of natural graphite and CG.Additionally,no obvious lithium dendrites are observed for MLG during the lithiation process.The large delithiation capacity under the low voltage plateau of MLG is mainly benefited from the combination of Li intercalation and boundary storage mechanism,which is further confirmed by the density functional theory calculations.The LiFePO4/MLG full cell can afford the satisfactory electrochemical property with respect to the capacity,energy density and ultralong cycling stability(90%capacity retention after 500 cycles at 2 C),significantly better than that of LiFePO4/CG.Besides,this developed technique not only dedicates to producing the high-performance anode for LIBs but also opens a door for the mass production of MLG in the industrial scale.
文摘从我国的能源结构和CO2排放及气候变化的现实出发,分析了我国燃煤火电技术的发展方向,即在不可能短期内改变我国能源和电源结构的情况下,我国火电应当怎样应对减排CO2的压力和挑战。虽然现在正在开发的碳捕获和封存技术(carbon capture and storage,CCS)有可能达到CO2接近零排放,但在CCS技术能够得到大规模推广应用之前的一个相当长的时期,目前最可行、经济、可靠的燃煤机组CO2减排的途径是坚持"上大压小"政策大力发展大容量高效率超临界/超超临界机组,通过技术创新提高现有火电厂效率,提高现有600℃超超临界机组的净效率,开发先进的37.5MPa/700℃/720℃/720℃双再热机组,将1000～1500MW超超临界机组净效率提高至53%以上。
