The Sinian Dengying Formation gas pool in Weiyuan is the oldest large-scale sulfur-bearing gas field in China, which has a H2S content ranging from 0.8% to 1.4%. The Cambrian Xixiangchi Formation gas pool discovered r...The Sinian Dengying Formation gas pool in Weiyuan is the oldest large-scale sulfur-bearing gas field in China, which has a H2S content ranging from 0.8% to 1.4%. The Cambrian Xixiangchi Formation gas pool discovered recently above the Dengying Formation contains gas geochemical behaviors similar to those of Dengying Formation but different in sulfur isotopes of H2S. Investigations show that though these two Sinian and Cambrian gas pools are separate ones, they share the same Cambrian source rock. The higher dry coefficient, heavier carbon isotopes, sulfur isotopes of sulfide, lower filling of gas pools, formation water characteristics, reservoir properties and H2S distribution, indicate that H2S in both the Sinian and Cambrian gas pools originates from TSR. The sulfur isotopes of sulfates have shown that H2S was formed in respective pools, namely hydrocarbons charged into the pools reacted with the Dengying Formation and the Xixiangchi Formation gypsum (TSR), respectively, to form H2S. Compared with sulfur isotopes of sulfates in each pool, δ34S values of H2S are 8‰ lighter for the Dengying Formation pool and 12‰ lighter for the Xixiangchi Formation pool, respectively, which is attributed to the difference in temperatures of TSR occurrence. The reservoir temperature of the Xixiangchi Formation pool is about 40℃ lower than that of the Dengying Formation pool. Temperature plays a controlling role in both the sulfur isotopic fractionation and amounts of H2S generation during TSR.展开更多
Environmental risk of high sulfur gas field exploitation has become one of the hot spots of environmental management studies.Severe gas H_(2)S blowout accidents in recent years have shown that poor understanding and e...Environmental risk of high sulfur gas field exploitation has become one of the hot spots of environmental management studies.Severe gas H_(2)S blowout accidents in recent years have shown that poor understanding and estimates of the poisonous gas movement could lead to dangerous evacuation delays.It is important to evaluate the real concentration of H_(2)S,especially in complex terrain.Traditional experiential models are not valid in the case of rough terrain,especially in low-lying areas where the gas accumulates.This study,using high sulfur content gas field of Sichuan“Pu Guang gas field”as study object and adopting objective diagnosis of wind field of land following coordinate three dimensions,applied Lagrangian Puff Model and breaking up technique of puffs to simulate the H_(2)S diffusion condition of blowout accidents produced in the high sulfur content gas field of complex terrain area.The results showed that the H_(2)S distribution did not occur mainly in low wind direction,and due to the obstruction of the mountain’s body,it accumulated in front of mountain on produced turn over,flowed around submitted jumping type distribution.The mountain waist near the hilltop and low hollow river valley site rapture points simulating contrast showed that the higher the rapture point,the better the diffusing condition of pollutant,the distribution of risk sensitive point decided piping rupture environmental risk size combining the H_(2)S diffusion result and residential area dispersing in the study area,synthetic judge located in the high rapture point environmental risk was smaller than the low hollow point,thus it was suggested to carryout laying of lining build of equal high line of higher terrain.According to simulation results,the environmental risk management measures aimed at putting down adverse effects were worked out.展开更多
基金Supported by the National Natural Science Foundation of China (Grant No. 40602016)the National Basic Research Project (Grant No. 2001CB209100)
文摘The Sinian Dengying Formation gas pool in Weiyuan is the oldest large-scale sulfur-bearing gas field in China, which has a H2S content ranging from 0.8% to 1.4%. The Cambrian Xixiangchi Formation gas pool discovered recently above the Dengying Formation contains gas geochemical behaviors similar to those of Dengying Formation but different in sulfur isotopes of H2S. Investigations show that though these two Sinian and Cambrian gas pools are separate ones, they share the same Cambrian source rock. The higher dry coefficient, heavier carbon isotopes, sulfur isotopes of sulfide, lower filling of gas pools, formation water characteristics, reservoir properties and H2S distribution, indicate that H2S in both the Sinian and Cambrian gas pools originates from TSR. The sulfur isotopes of sulfates have shown that H2S was formed in respective pools, namely hydrocarbons charged into the pools reacted with the Dengying Formation and the Xixiangchi Formation gypsum (TSR), respectively, to form H2S. Compared with sulfur isotopes of sulfates in each pool, δ34S values of H2S are 8‰ lighter for the Dengying Formation pool and 12‰ lighter for the Xixiangchi Formation pool, respectively, which is attributed to the difference in temperatures of TSR occurrence. The reservoir temperature of the Xixiangchi Formation pool is about 40℃ lower than that of the Dengying Formation pool. Temperature plays a controlling role in both the sulfur isotopic fractionation and amounts of H2S generation during TSR.
文摘Environmental risk of high sulfur gas field exploitation has become one of the hot spots of environmental management studies.Severe gas H_(2)S blowout accidents in recent years have shown that poor understanding and estimates of the poisonous gas movement could lead to dangerous evacuation delays.It is important to evaluate the real concentration of H_(2)S,especially in complex terrain.Traditional experiential models are not valid in the case of rough terrain,especially in low-lying areas where the gas accumulates.This study,using high sulfur content gas field of Sichuan“Pu Guang gas field”as study object and adopting objective diagnosis of wind field of land following coordinate three dimensions,applied Lagrangian Puff Model and breaking up technique of puffs to simulate the H_(2)S diffusion condition of blowout accidents produced in the high sulfur content gas field of complex terrain area.The results showed that the H_(2)S distribution did not occur mainly in low wind direction,and due to the obstruction of the mountain’s body,it accumulated in front of mountain on produced turn over,flowed around submitted jumping type distribution.The mountain waist near the hilltop and low hollow river valley site rapture points simulating contrast showed that the higher the rapture point,the better the diffusing condition of pollutant,the distribution of risk sensitive point decided piping rupture environmental risk size combining the H_(2)S diffusion result and residential area dispersing in the study area,synthetic judge located in the high rapture point environmental risk was smaller than the low hollow point,thus it was suggested to carryout laying of lining build of equal high line of higher terrain.According to simulation results,the environmental risk management measures aimed at putting down adverse effects were worked out.
