This study investigated the regime-dependent predictability using convective-scale ensemble forecasts initialized with different initial condition perturbations in the Yangtze and Huai River basin(YHRB)of East China.T...This study investigated the regime-dependent predictability using convective-scale ensemble forecasts initialized with different initial condition perturbations in the Yangtze and Huai River basin(YHRB)of East China.The scale-dependent error growth(ensemble variability)and associated impact on precipitation forecasts(precipitation uncertainties)were quantitatively explored for 13 warm-season convective events that were categorized in terms of strong forcing and weak forcing.The forecast error growth in the strong-forcing regime shows a stepwise increase with increasing spatial scale,while the error growth shows a larger temporal variability with an afternoon peak appearing at smaller scales under weak forcing.This leads to the dissimilarity of precipitation uncertainty and shows a strong correlation between error growth and precipitation across spatial scales.The lateral boundary condition errors exert a quasi-linear increase on error growth with time at the larger scale,suggesting that the large-scale flow could govern the magnitude of error growth and associated precipitation uncertainties,especially for the strong-forcing regime.Further comparisons between scale-based initial error sensitivity experiments show evident scale interaction including upscale transfer of small-scale errors and downscale cascade of larger-scale errors.Specifically,small-scale errors are found to be more sensitive in the weak-forcing regime than those under strong forcing.Meanwhile,larger-scale initial errors are responsible for the error growth after 4 h and produce the precipitation uncertainties at the meso-β-scale.Consequently,these results can be used to explain underdispersion issues in convective-scale ensemble forecasts and provide feedback for ensemble design over the YHRB.展开更多
The studies on the mechanisms and performances of the mechanical seals in reactor coolant pumps are very important for the safe operations of the pressurized water reactor power plants. Based on the hydrostatic mechan...The studies on the mechanisms and performances of the mechanical seals in reactor coolant pumps are very important for the safe operations of the pressurized water reactor power plants. Based on the hydrostatic mechanical seal in reactor coolant pumps, an analytical fluid-solid strong-interaction model is proposed in this paper. According to the design features and operafional principles of the seal, an analytical method to calculate the mechanical deformation of the seal assembly is developed based on the ring deformation theory. A strong-interaction algorithm combining the analysis of the mechanical deformation of the seal assembly and flow field between the seal faceplates is utilized, in which the three kinds of equations including the fluid domain, solid domain and coupling action are constituted in the same equations set and all the variables are solved simul- taneously. So the analytical fluid-solid strong-interaction model used for the seal is built. Moreover, the model is verified by the experimental results. Based on the model, the design parameters of the seal are studied. Two different conditions of the general case and fixed seal leakage rate are discussed respectively, and the regularities that the seal behaviors are affected by the parameters of the holding screws on the clamp rings and seal faceplates are obtained. The research results can provide a theoretical basis for performance analysis, design and assemblage of the seal. Compared to the numerical methods, the proposed model has the unique advantages of high efficiency, convenience and easy application of constraints.展开更多
In this study,K_(x)-Mn-Ce catalysts prepared by sol-gel method were investigated for toluene oxidation.Compared with Mn-Ce,the catalytic performance of K_(x)-Mn-Ce was further improved.X-ray diffraction(XRD),high reso...In this study,K_(x)-Mn-Ce catalysts prepared by sol-gel method were investigated for toluene oxidation.Compared with Mn-Ce,the catalytic performance of K_(x)-Mn-Ce was further improved.X-ray diffraction(XRD),high resolution transmission electron microscopy(HRTEM)and Raman analyses demonstrate that K ions enter the lattice of CeO_(2) and disperse uniformly.The results of X-ray photoelectron spectroscopy(XPS),H_(2)-temperature programmed reduction(H_(2)-TPR).and O_(2)-temperature programmed desorption(O_(2)-TPD)analyses indicate that there is a strong interaction between K,Mn and Ce;the charge co mpensation effect would be induced when K ions enter the lattice of CeO_(2),which leads to more oxygen vacancies due to the generation of more Ce^(3+).Toluene-TPD shows that K-doping enhances the activation ability of toluene.Among all catalysts,K0.1-Mn-Ce shows the highest concentration of Mn^(4+),Ce^(3+),Osur,and redox ability,resulting in higher low-temperature catalytic activity.Additionally,the results of stability and water resistance also prove that K0.1-Mn-Ce catalyst possesses excellent stability and water resistance.展开更多
Two-dimensional(2D)transition metal dichalcogenide(TMDC)semiconductors not only hold great promises for the development of ultra-thin optoelectronic devices with low-energy consumption,but also provide ideal platforms...Two-dimensional(2D)transition metal dichalcogenide(TMDC)semiconductors not only hold great promises for the development of ultra-thin optoelectronic devices with low-energy consumption,but also provide ideal platforms to explore and tailor light-matter interaction,e.g.,the exciton-photon interaction,at the atomic level,due to their atomic thickness,large exciton binding energy,and unique valley properties.In recent years,the exciton-photon interactions in TMDC semiconductor microcavities,including the strong exciton-photon coupling and lasing,have drawn increasing attention,which may open up new application prospects for transparent,on-chip coherent,and quantum light sources.Herein,we review the research progresses of strong exciton-photon interaction and lasing of TMDC semiconductors.First,we introduce the electronic structure,exciton,and emission properties of semiconducting TMDCs in the weak exciton-photon coupling regime.Next,the progresses on strong exciton-photon interaction and exciton-polaritons of these TMDCs are discussed from the aspects of photophysics,materials and fabrications,spectroscopies,and controls.Further,the progresses on TMDC lasers are introduced in the aspects of cavity types and materials,and finally,the challenges and prospects for these fields are discussed.展开更多
We propose the new field potential by maintaining both the symmetry of the scalar gauge and the conservation law keeping N?ether’s theorem, while disregarding the symmetry of the vector gauge. The new potential forms...We propose the new field potential by maintaining both the symmetry of the scalar gauge and the conservation law keeping N?ether’s theorem, while disregarding the symmetry of the vector gauge. The new potential forms like the well-type potential where a particle behaves almost freely but is very hard to escape without external energy, which can be interpreted as local confinement and asymptotic freedom. By assuming a 2-dimensional metric tensor in 4-dimensional space-time, we suggest the existence of 3 kinds of particles that resemble QCD with 3 color charges. We also show that the mass term exists but comes to zero and derive the charge and spin values. We can regard the particle with this new potential as a gluon, and the interaction in this well-type potential as a strong interaction for the properties of mass, charge, spin, and its behavior. We suggest the eight-fold way with this new particle, which is similar to the existing method based on SU (3) symmetry. Even though the strong interaction has been analyzed in the standard model and string theory, we build a new consistent model based on the theory of relativity including Riemann geometry, and show the unification of gravitational and strong interactional field.展开更多
Ordered mesoporous Mn2O3 (meso‐Mn2O3) and meso‐Mn2O3‐supported Pd, Pt, and Pd‐Pt alloy x(PdyPt)/meso‐Mn2O3; x = (0.10?1.50) wt%; Pd/Pt molar ratio (y) = 4.9?5.1 nanocatalysts were prepared using KIT‐6‐templated...Ordered mesoporous Mn2O3 (meso‐Mn2O3) and meso‐Mn2O3‐supported Pd, Pt, and Pd‐Pt alloy x(PdyPt)/meso‐Mn2O3; x = (0.10?1.50) wt%; Pd/Pt molar ratio (y) = 4.9?5.1 nanocatalysts were prepared using KIT‐6‐templated and poly(vinyl alcohol)‐protected reduction methods, respectively.The meso‐Mn2O3 had a high surface area, i.e., 106 m2/g, and a cubic crystal structure. Noble‐metalnanoparticles (NPs) of size 2.1?2.8 nm were uniformly dispersed on the meso‐Mn2O3 surfaces. AlloyingPd with Pt enhanced the catalytic activity in methane combustion; 1.41(Pd5.1Pt)/meso‐Mn2O3gave the best performance; T10%, T50%, and T90% (the temperatures required for achieving methaneconversions of 10%, 50%, and 90%) were 265, 345, and 425 °C, respectively, at a space velocity of20000 mL/(g?h). The effects of SO2, CO2, H2O, and NO on methane combustion over1.41(Pd5.1Pt)/meso‐Mn2O3 were also examined. We conclude that the good catalytic performance of1.41(Pd5.1Pt)/meso‐Mn2O3 is associated with its high‐quality porous structure, high adsorbed oxygen species concentration, good low‐temperature reducibility, and strong interactions between Pd‐Pt alloy NPs and the meso‐Mn2O3 support.展开更多
Recently,the LHCb experimental group found an exotic state T_(cc)^(+) from the pp→D^(0)D^(0)π^(+)+X process.A key question is whether it is just a molecule or may have a confined tetraquark ingredient.To investigate...Recently,the LHCb experimental group found an exotic state T_(cc)^(+) from the pp→D^(0)D^(0)π^(+)+X process.A key question is whether it is just a molecule or may have a confined tetraquark ingredient.To investigate this,different methods were used,including a two-channel(D^(∗)+D^(0) and D^(∗)0D^(+))K-matrix unitarization and a single-channel Flatté-like parametrization method analyzed utilizing the pole counting rule and spectral density function sum rule.These analyses demonstrated that T_(cc)^(+) is a molecular state,although the possibility that there may exist an elementary ingredient cannot be excluded,according to an approximate analysis of its production rate.展开更多
The surface properties of oxidic supports and their interaction with the supported metals play critical roles in governing the catalytic activities of oxide‐supported metal catalysts.When metals are supported on redu...The surface properties of oxidic supports and their interaction with the supported metals play critical roles in governing the catalytic activities of oxide‐supported metal catalysts.When metals are supported on reducible oxides,dynamic surface reconstruction phenomena,including strong metal–support interaction(SMSI)and oxygen vacancy formation,complicate the determination of the structural–functional relationship at the active sites.Here,we performed a systematic investigation of the dynamic behavior of Au nanocatalysts supported on flame‐synthesized TiO_(2),which takes predominantly a rutile phase,using CO oxidation above room temperature as a probe reaction.Our analysis conclusively elucidated a negative correlation between the catalytic activity of Au/TiO_(2) and the oxygen vacancy at the Au/TiO_(2) interface.Although the reversible formation and retracting of SMSI overlayers have been ubiquitously observed on Au/TiO_(2) samples,the catalytic consequence of SMSI remains inconclusive.Density functional theory suggests that the electron transfer from TiO_(2) to Au is correlated to the presence of the interfacial oxygen vacancies,retarding the catalytic activation of CO oxidation.展开更多
Ruthenium(Ru)has been regarded as one of the most promising alternatives to substitute Pt for catalyzing alkaline hydrogen evolution reaction(HER),owing to its inherent high activity and being the cheapest platinum-gr...Ruthenium(Ru)has been regarded as one of the most promising alternatives to substitute Pt for catalyzing alkaline hydrogen evolution reaction(HER),owing to its inherent high activity and being the cheapest platinum-group metal.Herein,based on the idea of strong metal–support interaction(SMSI)regulation,Ru/TiN catalysts with different degrees of TiN overlayer over Ru nanoparticles were fabricated,which were applied to the alkaline electrolytic water.Characterizations reveal that the TiN overlayer would gradually encapsulate the Ru nanoparticles and induce more electron transfer from Ru nanoparticles to TiN support by the Ru–N–Ti bond as the SMSI degree increased.Further study shows that the exposed Ru–TiN interfaces greatly promote the H_(2) desorption capacity.Thus,the Ru/TiN-300 with a moderate SMSI degree exhibits excellent HER performance,with an overpotential of 38 mV at 10 mA cm^(−2).Also,due to the encapsulation role of TiN overlayer on Ru nanoparticles,it displays super long-term stability with a very slight potential change after 24 h.This study provides a deep insight into the influence of the SMSI effect between Ru and TiN on HER and offers a novel approach for preparing efficient and stable HER electrocatalysts through SMSI engineering.展开更多
We study the coexistence of antiferromagnetism and unconventional superconductivity on the Creutz lattice which shows strictly flat bands in the noninteracting regime.The famous renormalized mean-field theory is used ...We study the coexistence of antiferromagnetism and unconventional superconductivity on the Creutz lattice which shows strictly flat bands in the noninteracting regime.The famous renormalized mean-field theory is used to deal with strong electron-electron repulsive Hubbard interaction in the effective low-energy t-J model,the superfluid weight of the unconventional superconducting state has been calculated via the linear response theory.An unconventional superconducting state with both spin-singlet and staggered spin-triplet pairs emerges beyond a critical antiferromagnetic coupling interaction,while antiferromagnetism accompanies this state.The superconducting state with only spin-singlet pairs is dominant with paramagnetic phase.The A phase is analogous to the pseudogap phase,which shows that electrons go to form pairs but do not cause a supercurrent.We also show the superfluid behavior of the unconventional superconducting state and its critical temperature.It is proven directly that the flat band can effectively raise the critical temperature of superconductivity.It is implementable to simulate and control strongly-correlated electrons'behavior on the Creutz lattice in the ultracold atoms experiment or other artificial structures.Our results may help the understanding of the interplay between unconventional superconductivity and magnetism.展开更多
Tuning Strong Metal-support Interactions(SMSI)is a key strategy to obtain highly active catalysts,but conventional methods usually enable TiO_(x) encapsulation of noble metal components to minimize the exposure of nob...Tuning Strong Metal-support Interactions(SMSI)is a key strategy to obtain highly active catalysts,but conventional methods usually enable TiO_(x) encapsulation of noble metal components to minimize the exposure of noble metals.This study demonstrates a catalyst preparation method to modulate a weak encapsulation of Pt metal nanoparticles(NPs)with the supported TiO_(2),achieving the moderate suppression of SMSI effects.The introduction of silica inhibits this encapsulation,as reflected in the characterization results such as XPS and HRTEM,while the Ti^(4+) to Ti^(3+) conversion due to SMSI can still be found on the support surface.Furthermore,the hydrogenation of cinnamaldehyde(CAL)as a probe reaction revealed that once this encapsulation behavior was suppressed,the adsorption capacity of the catalyst for small molecules like H_(2) and CO was enhanced,which thereby improved the catalytic activity and facilitated the hydrogenation of CAL.Meanwhile,the introduction of SiO_(2) also changed the surface structure of the catalyst,which inhibited the occurrence of the acetal reaction and improved the conversion efficiency of C=O and C=C hydrogenation.Systematic manipulation of SMSI formation and its consequence on the performance in catalytic hydrogenation reactions are discussed.展开更多
The phenomenon of strong metal-support interaction(SMSI)observed in supported metal catalysts,usually accompanied by the formation of the encapsulation layer on metal nanoparticles,has attracted extensive research att...The phenomenon of strong metal-support interaction(SMSI)observed in supported metal catalysts,usually accompanied by the formation of the encapsulation layer on metal nanoparticles,has attracted extensive research attention due to its significance in heterogeneous catalysis.Notably,great progress has been made in recent years in investigating SMSI by in situ transmission electron microscopy(TEM),along with an enhanced comprehension of the underlying mechanisms governing SMSI formation.This emerging topic summarizes recent progress utilizing in situ TEM to study the interaction between metal and support and the relationship between the structure and performance of the supported catalyst under reaction conditions.A brief perspective about the use of in situ TEM for further study of SMSI is also presented,showing prospects in this field that will stimulate further upsurging research in promoting the catalytic efficiency of supported catalysts.展开更多
In this paper we consider nucleons as tori, rotating with a constant angular velocity around the straight line passing through their mass centre (geometric centre) and perpendicular to their plane of rotation. We theo...In this paper we consider nucleons as tori, rotating with a constant angular velocity around the straight line passing through their mass centre (geometric centre) and perpendicular to their plane of rotation. We theoretically determine the corresponding potential energy and the force of interaction between pairs of nucleons, using our precise analytical formulas for the electrostatic interaction between two spheres with arbitrary radii and charges, which we derive using experimentally obtained results for the radii and the masses of the nucleons. From the values for binding energy found through our method, it follows that nuclear forces are electromagnetic in nature. In terms of magnitude of the force of interaction between proton and neutron, we obtain that Coulomb's forces are short-range. Our toroid model explains the experimental results not only for binding energy, but also for the radius, magnetic moment and the spin of the nuclei of atoms.展开更多
基金supported by the National Key Research and Development Program of China(Grant No.2017YFC1502103)the National Natural Science Foundation of China(Grant Nos.41430427 and 41705035)+1 种基金the China Scholarship Councilthe Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX17_0876)。
文摘This study investigated the regime-dependent predictability using convective-scale ensemble forecasts initialized with different initial condition perturbations in the Yangtze and Huai River basin(YHRB)of East China.The scale-dependent error growth(ensemble variability)and associated impact on precipitation forecasts(precipitation uncertainties)were quantitatively explored for 13 warm-season convective events that were categorized in terms of strong forcing and weak forcing.The forecast error growth in the strong-forcing regime shows a stepwise increase with increasing spatial scale,while the error growth shows a larger temporal variability with an afternoon peak appearing at smaller scales under weak forcing.This leads to the dissimilarity of precipitation uncertainty and shows a strong correlation between error growth and precipitation across spatial scales.The lateral boundary condition errors exert a quasi-linear increase on error growth with time at the larger scale,suggesting that the large-scale flow could govern the magnitude of error growth and associated precipitation uncertainties,especially for the strong-forcing regime.Further comparisons between scale-based initial error sensitivity experiments show evident scale interaction including upscale transfer of small-scale errors and downscale cascade of larger-scale errors.Specifically,small-scale errors are found to be more sensitive in the weak-forcing regime than those under strong forcing.Meanwhile,larger-scale initial errors are responsible for the error growth after 4 h and produce the precipitation uncertainties at the meso-β-scale.Consequently,these results can be used to explain underdispersion issues in convective-scale ensemble forecasts and provide feedback for ensemble design over the YHRB.
基金supported by the National Basic Research Program of China(Grant No.2009CB724304)the Key Research Program of the State Key Laboratory of Tribology of Tsinghua University(Grant No.SKLT08A06)the National Natural Science Foundation of China(Grant No.50975157)
文摘The studies on the mechanisms and performances of the mechanical seals in reactor coolant pumps are very important for the safe operations of the pressurized water reactor power plants. Based on the hydrostatic mechanical seal in reactor coolant pumps, an analytical fluid-solid strong-interaction model is proposed in this paper. According to the design features and operafional principles of the seal, an analytical method to calculate the mechanical deformation of the seal assembly is developed based on the ring deformation theory. A strong-interaction algorithm combining the analysis of the mechanical deformation of the seal assembly and flow field between the seal faceplates is utilized, in which the three kinds of equations including the fluid domain, solid domain and coupling action are constituted in the same equations set and all the variables are solved simul- taneously. So the analytical fluid-solid strong-interaction model used for the seal is built. Moreover, the model is verified by the experimental results. Based on the model, the design parameters of the seal are studied. Two different conditions of the general case and fixed seal leakage rate are discussed respectively, and the regularities that the seal behaviors are affected by the parameters of the holding screws on the clamp rings and seal faceplates are obtained. The research results can provide a theoretical basis for performance analysis, design and assemblage of the seal. Compared to the numerical methods, the proposed model has the unique advantages of high efficiency, convenience and easy application of constraints.
基金Project supported by the Fundamental Research Funds for the Cornell University(30919011220)the Key Project of Jiangsu Province Programs for Research and Development(BE2019115)+1 种基金Top-notch Academic Programs Project of Jiangsu Higher Education InstitutionsChina-Finland Industrial R&D Program(BZ2018015)。
文摘In this study,K_(x)-Mn-Ce catalysts prepared by sol-gel method were investigated for toluene oxidation.Compared with Mn-Ce,the catalytic performance of K_(x)-Mn-Ce was further improved.X-ray diffraction(XRD),high resolution transmission electron microscopy(HRTEM)and Raman analyses demonstrate that K ions enter the lattice of CeO_(2) and disperse uniformly.The results of X-ray photoelectron spectroscopy(XPS),H_(2)-temperature programmed reduction(H_(2)-TPR).and O_(2)-temperature programmed desorption(O_(2)-TPD)analyses indicate that there is a strong interaction between K,Mn and Ce;the charge co mpensation effect would be induced when K ions enter the lattice of CeO_(2),which leads to more oxygen vacancies due to the generation of more Ce^(3+).Toluene-TPD shows that K-doping enhances the activation ability of toluene.Among all catalysts,K0.1-Mn-Ce shows the highest concentration of Mn^(4+),Ce^(3+),Osur,and redox ability,resulting in higher low-temperature catalytic activity.Additionally,the results of stability and water resistance also prove that K0.1-Mn-Ce catalyst possesses excellent stability and water resistance.
基金the Natural Science Foundation of China(Nos.51991340 and 51991344)the National Key Research and Development Program of China(Nos.2017YFA0205700 and 2017YFA0304600)the Open Research Fund Program of the State Key Laboratory of Low-dimensional Quantum Physics(No.KF201907).
文摘Two-dimensional(2D)transition metal dichalcogenide(TMDC)semiconductors not only hold great promises for the development of ultra-thin optoelectronic devices with low-energy consumption,but also provide ideal platforms to explore and tailor light-matter interaction,e.g.,the exciton-photon interaction,at the atomic level,due to their atomic thickness,large exciton binding energy,and unique valley properties.In recent years,the exciton-photon interactions in TMDC semiconductor microcavities,including the strong exciton-photon coupling and lasing,have drawn increasing attention,which may open up new application prospects for transparent,on-chip coherent,and quantum light sources.Herein,we review the research progresses of strong exciton-photon interaction and lasing of TMDC semiconductors.First,we introduce the electronic structure,exciton,and emission properties of semiconducting TMDCs in the weak exciton-photon coupling regime.Next,the progresses on strong exciton-photon interaction and exciton-polaritons of these TMDCs are discussed from the aspects of photophysics,materials and fabrications,spectroscopies,and controls.Further,the progresses on TMDC lasers are introduced in the aspects of cavity types and materials,and finally,the challenges and prospects for these fields are discussed.
文摘We propose the new field potential by maintaining both the symmetry of the scalar gauge and the conservation law keeping N?ether’s theorem, while disregarding the symmetry of the vector gauge. The new potential forms like the well-type potential where a particle behaves almost freely but is very hard to escape without external energy, which can be interpreted as local confinement and asymptotic freedom. By assuming a 2-dimensional metric tensor in 4-dimensional space-time, we suggest the existence of 3 kinds of particles that resemble QCD with 3 color charges. We also show that the mass term exists but comes to zero and derive the charge and spin values. We can regard the particle with this new potential as a gluon, and the interaction in this well-type potential as a strong interaction for the properties of mass, charge, spin, and its behavior. We suggest the eight-fold way with this new particle, which is similar to the existing method based on SU (3) symmetry. Even though the strong interaction has been analyzed in the standard model and string theory, we build a new consistent model based on the theory of relativity including Riemann geometry, and show the unification of gravitational and strong interactional field.
基金supported by the Ph.D.Program Foundation of Ministry of Education of China(20131103110002)the NNSF of China(21377008)+2 种基金National High Technology Research and Development Program(863 Program,2015AA034603)Foundation on the Creative Research Team Con-struction Promotion Project of Beijing Municipal InstitutionsScientific Research Base Construction-Science and Technology Creation Plat-form-National Materials Research Base Construction~~
文摘Ordered mesoporous Mn2O3 (meso‐Mn2O3) and meso‐Mn2O3‐supported Pd, Pt, and Pd‐Pt alloy x(PdyPt)/meso‐Mn2O3; x = (0.10?1.50) wt%; Pd/Pt molar ratio (y) = 4.9?5.1 nanocatalysts were prepared using KIT‐6‐templated and poly(vinyl alcohol)‐protected reduction methods, respectively.The meso‐Mn2O3 had a high surface area, i.e., 106 m2/g, and a cubic crystal structure. Noble‐metalnanoparticles (NPs) of size 2.1?2.8 nm were uniformly dispersed on the meso‐Mn2O3 surfaces. AlloyingPd with Pt enhanced the catalytic activity in methane combustion; 1.41(Pd5.1Pt)/meso‐Mn2O3gave the best performance; T10%, T50%, and T90% (the temperatures required for achieving methaneconversions of 10%, 50%, and 90%) were 265, 345, and 425 °C, respectively, at a space velocity of20000 mL/(g?h). The effects of SO2, CO2, H2O, and NO on methane combustion over1.41(Pd5.1Pt)/meso‐Mn2O3 were also examined. We conclude that the good catalytic performance of1.41(Pd5.1Pt)/meso‐Mn2O3 is associated with its high‐quality porous structure, high adsorbed oxygen species concentration, good low‐temperature reducibility, and strong interactions between Pd‐Pt alloy NPs and the meso‐Mn2O3 support.
基金the National Nature Science Foundations of China(12335002,12375078,11975028)H.Q.Zheng and Z.Xiao are also Supported by"the Fundamental Research Funds for the Central Universities"。
文摘Recently,the LHCb experimental group found an exotic state T_(cc)^(+) from the pp→D^(0)D^(0)π^(+)+X process.A key question is whether it is just a molecule or may have a confined tetraquark ingredient.To investigate this,different methods were used,including a two-channel(D^(∗)+D^(0) and D^(∗)0D^(+))K-matrix unitarization and a single-channel Flatté-like parametrization method analyzed utilizing the pole counting rule and spectral density function sum rule.These analyses demonstrated that T_(cc)^(+) is a molecular state,although the possibility that there may exist an elementary ingredient cannot be excluded,according to an approximate analysis of its production rate.
基金Science and Technology Innovation Program of Hunan Province,Grant/Award Numbers:2020GK2070,2021RC4006Innovation‐Driven Project of Central South University,Grant/Award Number:2020CX008+3 种基金China Scholarship Council(CSC)National Key R&D Program of China,Grant/Award Number:2022YFE0105900National Natural Science Foundation of China,Grant/Award Number:52276093National Research Foundation Singapore,Grant/Award Number:CREATE。
文摘The surface properties of oxidic supports and their interaction with the supported metals play critical roles in governing the catalytic activities of oxide‐supported metal catalysts.When metals are supported on reducible oxides,dynamic surface reconstruction phenomena,including strong metal–support interaction(SMSI)and oxygen vacancy formation,complicate the determination of the structural–functional relationship at the active sites.Here,we performed a systematic investigation of the dynamic behavior of Au nanocatalysts supported on flame‐synthesized TiO_(2),which takes predominantly a rutile phase,using CO oxidation above room temperature as a probe reaction.Our analysis conclusively elucidated a negative correlation between the catalytic activity of Au/TiO_(2) and the oxygen vacancy at the Au/TiO_(2) interface.Although the reversible formation and retracting of SMSI overlayers have been ubiquitously observed on Au/TiO_(2) samples,the catalytic consequence of SMSI remains inconclusive.Density functional theory suggests that the electron transfer from TiO_(2) to Au is correlated to the presence of the interfacial oxygen vacancies,retarding the catalytic activation of CO oxidation.
基金supported by the National Natural Science Foundation of China(Grant Nos.22075159,22002066)Shandong Taishan Scholars Project(Grant Nos.ts20190932,tsqn202103058)+1 种基金Open Fund of Hubei Key Laboratory of Processing and Application of Catalytic Materials(Grant No.202203404)Postdoctoral Applied Research Project in Qingdao,and the Youth Innovation Team Project of Shandong Provincial Education Department(Grant No.2019KJC023).
文摘Ruthenium(Ru)has been regarded as one of the most promising alternatives to substitute Pt for catalyzing alkaline hydrogen evolution reaction(HER),owing to its inherent high activity and being the cheapest platinum-group metal.Herein,based on the idea of strong metal–support interaction(SMSI)regulation,Ru/TiN catalysts with different degrees of TiN overlayer over Ru nanoparticles were fabricated,which were applied to the alkaline electrolytic water.Characterizations reveal that the TiN overlayer would gradually encapsulate the Ru nanoparticles and induce more electron transfer from Ru nanoparticles to TiN support by the Ru–N–Ti bond as the SMSI degree increased.Further study shows that the exposed Ru–TiN interfaces greatly promote the H_(2) desorption capacity.Thus,the Ru/TiN-300 with a moderate SMSI degree exhibits excellent HER performance,with an overpotential of 38 mV at 10 mA cm^(−2).Also,due to the encapsulation role of TiN overlayer on Ru nanoparticles,it displays super long-term stability with a very slight potential change after 24 h.This study provides a deep insight into the influence of the SMSI effect between Ru and TiN on HER and offers a novel approach for preparing efficient and stable HER electrocatalysts through SMSI engineering.
基金Project supported by the Natural Science Basic Research Program of Shaanxi(Program Nos.2023KJXX-064 and 2021JQ-748)the National Natural Science Foundation of China(Grant Nos.11804213 and 12174238)Scientific Research Foundation of Shaanxi University of Technology(Grant No.SLGRCQD2006).
文摘We study the coexistence of antiferromagnetism and unconventional superconductivity on the Creutz lattice which shows strictly flat bands in the noninteracting regime.The famous renormalized mean-field theory is used to deal with strong electron-electron repulsive Hubbard interaction in the effective low-energy t-J model,the superfluid weight of the unconventional superconducting state has been calculated via the linear response theory.An unconventional superconducting state with both spin-singlet and staggered spin-triplet pairs emerges beyond a critical antiferromagnetic coupling interaction,while antiferromagnetism accompanies this state.The superconducting state with only spin-singlet pairs is dominant with paramagnetic phase.The A phase is analogous to the pseudogap phase,which shows that electrons go to form pairs but do not cause a supercurrent.We also show the superfluid behavior of the unconventional superconducting state and its critical temperature.It is proven directly that the flat band can effectively raise the critical temperature of superconductivity.It is implementable to simulate and control strongly-correlated electrons'behavior on the Creutz lattice in the ultracold atoms experiment or other artificial structures.Our results may help the understanding of the interplay between unconventional superconductivity and magnetism.
基金the National Natural Science Foundation of China(21576291,22003076)National Natural Science Foundation of China-Outstanding Youth foundation(22322814)the Fundamental Research Funds for the Central Universities(23CX03007A,22CX06012A)are gratefully acknowledge。
文摘Tuning Strong Metal-support Interactions(SMSI)is a key strategy to obtain highly active catalysts,but conventional methods usually enable TiO_(x) encapsulation of noble metal components to minimize the exposure of noble metals.This study demonstrates a catalyst preparation method to modulate a weak encapsulation of Pt metal nanoparticles(NPs)with the supported TiO_(2),achieving the moderate suppression of SMSI effects.The introduction of silica inhibits this encapsulation,as reflected in the characterization results such as XPS and HRTEM,while the Ti^(4+) to Ti^(3+) conversion due to SMSI can still be found on the support surface.Furthermore,the hydrogenation of cinnamaldehyde(CAL)as a probe reaction revealed that once this encapsulation behavior was suppressed,the adsorption capacity of the catalyst for small molecules like H_(2) and CO was enhanced,which thereby improved the catalytic activity and facilitated the hydrogenation of CAL.Meanwhile,the introduction of SiO_(2) also changed the surface structure of the catalyst,which inhibited the occurrence of the acetal reaction and improved the conversion efficiency of C=O and C=C hydrogenation.Systematic manipulation of SMSI formation and its consequence on the performance in catalytic hydrogenation reactions are discussed.
基金the support from the National Natural Science Foundation of China(22376062)the Science and Technology Commission of Shanghai Municipality(22ZR1415700)+1 种基金Shanghai Rising-star Program(20QA1402400)and the Fundamental Research Funds for the Central Universities,Additional support was provided by the Frontiers Science Center for Materiobiology and Dynamic Chemistry and the Feringa Nobel Prize Scientist Joint Research Center at East China University of Science and Technology。
文摘The phenomenon of strong metal-support interaction(SMSI)observed in supported metal catalysts,usually accompanied by the formation of the encapsulation layer on metal nanoparticles,has attracted extensive research attention due to its significance in heterogeneous catalysis.Notably,great progress has been made in recent years in investigating SMSI by in situ transmission electron microscopy(TEM),along with an enhanced comprehension of the underlying mechanisms governing SMSI formation.This emerging topic summarizes recent progress utilizing in situ TEM to study the interaction between metal and support and the relationship between the structure and performance of the supported catalyst under reaction conditions.A brief perspective about the use of in situ TEM for further study of SMSI is also presented,showing prospects in this field that will stimulate further upsurging research in promoting the catalytic efficiency of supported catalysts.
文摘In this paper we consider nucleons as tori, rotating with a constant angular velocity around the straight line passing through their mass centre (geometric centre) and perpendicular to their plane of rotation. We theoretically determine the corresponding potential energy and the force of interaction between pairs of nucleons, using our precise analytical formulas for the electrostatic interaction between two spheres with arbitrary radii and charges, which we derive using experimentally obtained results for the radii and the masses of the nucleons. From the values for binding energy found through our method, it follows that nuclear forces are electromagnetic in nature. In terms of magnitude of the force of interaction between proton and neutron, we obtain that Coulomb's forces are short-range. Our toroid model explains the experimental results not only for binding energy, but also for the radius, magnetic moment and the spin of the nuclei of atoms.
