It is the first time in experiment that we have found that the ionic strength effects on E(%)-pH curves of the systems with clay minerals as solid particles and those systems with hydrous oxides as solid particles, ar...It is the first time in experiment that we have found that the ionic strength effects on E(%)-pH curves of the systems with clay minerals as solid particles and those systems with hydrous oxides as solid particles, are 'right-left shift phenomenon' and 'left monodirectional shift phenomenon', respectively.The corresponding ionic strength effects on isotherms are 'downward-upward shift phenomenon' and 'upward monodirectional shift phenomenon', respectively.All the four phenomena are consistent with each other.In order to explain the above phenomena, the composite model of interracial ion/coordination particle exchange-electrostatic exchange is put forward to make a unified explanation and quantitative treatment.From the structures of the two kinds of materials——clay minerals and hydrous oxides, we know that the former has two kinds of exchange actions, i.e. when one increases,the other decreases, which makes the position of curves shift didirectionally,while the latter only has interfacial stepwise ion/coordin ation particle exchange,the curves of which shift therefore monodirectionally.The calculated results of the model accord with the experimental.展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘It is the first time in experiment that we have found that the ionic strength effects on E(%)-pH curves of the systems with clay minerals as solid particles and those systems with hydrous oxides as solid particles, are 'right-left shift phenomenon' and 'left monodirectional shift phenomenon', respectively.The corresponding ionic strength effects on isotherms are 'downward-upward shift phenomenon' and 'upward monodirectional shift phenomenon', respectively.All the four phenomena are consistent with each other.In order to explain the above phenomena, the composite model of interracial ion/coordination particle exchange-electrostatic exchange is put forward to make a unified explanation and quantitative treatment.From the structures of the two kinds of materials——clay minerals and hydrous oxides, we know that the former has two kinds of exchange actions, i.e. when one increases,the other decreases, which makes the position of curves shift didirectionally,while the latter only has interfacial stepwise ion/coordin ation particle exchange,the curves of which shift therefore monodirectionally.The calculated results of the model accord with the experimental.
