Enhanced oil recovery(EOR)by means of polymer flooding is an important technology for the strategic development of offshore oilfields in China.Hydrophobically associating polyacrylamide(HAPAM)has been recently propose...Enhanced oil recovery(EOR)by means of polymer flooding is an important technology for the strategic development of offshore oilfields in China.Hydrophobically associating polyacrylamide(HAPAM)has been recently proposed as a new flooding agent.The solubility of HAPAM is low,which is the bottleneck for further improving the oil recovery through polymer flooding in offshore oilfield.Stirred tanks have been used on offshore platforms to enhance HAPAM dissolving.But there is little literature on the study of HAPAM dissolving characteristics in stirred tanks.In this paper,effects of temperature,salinity,stirring speed,impeller type and stirring method on the dissolution of HAPAM are reported.The experimental results manifest that the dissolving rate of HAPAM increases with temperature and stirring speed,but the viscosity of the polymer solution decreases.There is an optimal range of salinity for polymer dissolving.Combining the operation mode of up-pumping with varying stirring speed,hydrofoil impeller can accelerate the dissolution of HAPAM and maintain a high solution viscosity.展开更多
Highly dispersed carbon microspheres(CMSs)derived from D-xylose were successfully synthesized under hydrothermal conditions and followed by further carbonization,in which F127 was used as a soft template.As-synthesize...Highly dispersed carbon microspheres(CMSs)derived from D-xylose were successfully synthesized under hydrothermal conditions and followed by further carbonization,in which F127 was used as a soft template.As-synthesized products were characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),flourier transform infrared spectroscopy(FT-IR),thermal gravimetric(TG)and X-ray diffraction(XRD).The results showed that the morphology and structure of the CMSs prominently depended on the stirring speed during hydrothermal reaction.The resultant CMSs principally had non-porous structure without stirring and had a very smooth surface.When the stirring speed increased to 200 rpm,the synthesized mesoporous carbon microspheres at 220?C for 24 h(CMSs-5)had a uniform size distribution of 1–1.4μm and a specific surface area of 452 m^2/g.Nevertheless,with further increasing to 400 rpm,as-fabricated carbon products were mostly amorphous with a low degree of sphericity.Results demonstrated that the diameter of the products decreased with the increase of stirring speed.Furthermore,the sphericity product yield of CMSs reduced with the increase of stirring speed.XRD result showed that all the obtained samples contained partial graphite phase.In addition,a formation mechanism was proposed that involved polymerization product as the precursors for microsphere formation.The controllable and green strategy may provide a great convenience to study properties and applications of carbon microspheres.展开更多
A volume averaged columnar solidification model,which couples the flow,temperature and solute concentration fields,is applied to simulate experimental continuous casting cases with and without vertical electromagnetic...A volume averaged columnar solidification model,which couples the flow,temperature and solute concentration fields,is applied to simulate experimental continuous casting cases with and without vertical electromagnetic stirring(V-EMS).The calculated distribution of magnetic induction intensity and final macrosegregation maps are consistent with the experimental results.Calculation results reveal that the V-EMS promotes longitudinal melt flow,accelerates heat dissipation and solidification and finally reduces the central segregation of carbon.However,when V-EMS is applied,the solute distribution becomes asymmetric because the melt flow shows opposite directions between the near and far sides from stirrer.An obvious positive segregation band is observed at about 1/4 width of the billet near the stirrer in both calculated and experimental results.The position and degree of such positive segregation could be affected by installation height of stirrer,as demonstrated by additional simulation cases.展开更多
Stirring-sampling method is a widely adopted method to measure sediment concentrations in collection tanks of runoff plots,but with high systematic measurement errors.This research aimed to advance an approach for bui...Stirring-sampling method is a widely adopted method to measure sediment concentrations in collection tanks of runoff plots,but with high systematic measurement errors.This research aimed to advance an approach for building correction equations to remove measurement errors in designed sediment concentration range.Experimental data of sediment measurement from the stirring-sampling method,with four representative soils,under the designed sediment concentrations(1,2,5,8,10,20,50,80,100,200,500,800,and 1000 kg/m^(3))were used to demonstrate the correction methodological process.Two correction methods(step-wise correction and universal correction)were suggested for the trial in this study based on the distribution of measurement errors.In the step-wise correction,the correction equations were made with a series of linear functions without intercept for the low concentration group(0-20 kg/m^(3)),a series of linear functions with intercept for the high(20-200 kg/m^(3))and extremely high(200-1000 kg/m^(3))concentration groups,consecutively.The correction equations were a series of power functions in the universal correction.For the step-wise correction,most of the relative errors of correction sediment concentrations were smaller than 15%and 10%under high and extremely high concentration groups,but the corrected accuracy was not good in the sediment concentration of 1,2,5 kg/m^(3)with the corrected relative errors of 0.20%-206.07%.For the universal correction,the corrected relative errors(0.19%-31.81%)of the four soils were low under the condition of extremely high sediment concentrations,but other corrected accuracies weren’t good with the corrected relative errors of 0.68%-1154.71%.The corrected accuracy of step-wise correction is higher than that of the universal correction,but the universal correction is more convenient.These results indicated that the correction equations could efficiently revise the measurement errors of the tested soils and that this method can be generalized to other soil types and was meaningf展开更多
文摘Enhanced oil recovery(EOR)by means of polymer flooding is an important technology for the strategic development of offshore oilfields in China.Hydrophobically associating polyacrylamide(HAPAM)has been recently proposed as a new flooding agent.The solubility of HAPAM is low,which is the bottleneck for further improving the oil recovery through polymer flooding in offshore oilfield.Stirred tanks have been used on offshore platforms to enhance HAPAM dissolving.But there is little literature on the study of HAPAM dissolving characteristics in stirred tanks.In this paper,effects of temperature,salinity,stirring speed,impeller type and stirring method on the dissolution of HAPAM are reported.The experimental results manifest that the dissolving rate of HAPAM increases with temperature and stirring speed,but the viscosity of the polymer solution decreases.There is an optimal range of salinity for polymer dissolving.Combining the operation mode of up-pumping with varying stirring speed,hydrofoil impeller can accelerate the dissolution of HAPAM and maintain a high solution viscosity.
基金supported financially by the Outstanding Youth Science Fund of Shaanxi Province(No.2018JC-028)the fund of Beijing Key Laboratory of Quality Evaluation Technology for Hygiene and Safety of Plastics,Beijing Technology and Business University(No.51772243)+1 种基金the Innovation Team Plan of Shaanxi Province(No.2017KCT-17)the National Natural Science Foundation of China(No.51772243).
文摘Highly dispersed carbon microspheres(CMSs)derived from D-xylose were successfully synthesized under hydrothermal conditions and followed by further carbonization,in which F127 was used as a soft template.As-synthesized products were characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),flourier transform infrared spectroscopy(FT-IR),thermal gravimetric(TG)and X-ray diffraction(XRD).The results showed that the morphology and structure of the CMSs prominently depended on the stirring speed during hydrothermal reaction.The resultant CMSs principally had non-porous structure without stirring and had a very smooth surface.When the stirring speed increased to 200 rpm,the synthesized mesoporous carbon microspheres at 220?C for 24 h(CMSs-5)had a uniform size distribution of 1–1.4μm and a specific surface area of 452 m^2/g.Nevertheless,with further increasing to 400 rpm,as-fabricated carbon products were mostly amorphous with a low degree of sphericity.Results demonstrated that the diameter of the products decreased with the increase of stirring speed.Furthermore,the sphericity product yield of CMSs reduced with the increase of stirring speed.XRD result showed that all the obtained samples contained partial graphite phase.In addition,a formation mechanism was proposed that involved polymerization product as the precursors for microsphere formation.The controllable and green strategy may provide a great convenience to study properties and applications of carbon microspheres.
基金financial support from the National Natural Science Foundation of China(Grant No.U1760206)the National Key R&D Program of China(Grant No.2017YFE0107900)+1 种基金the 111 Project 2.0 of China(Grant No.BP0719037)the financial support provided by the ESA-MAP MICAST project contract 14347/01/NL/SH.
文摘A volume averaged columnar solidification model,which couples the flow,temperature and solute concentration fields,is applied to simulate experimental continuous casting cases with and without vertical electromagnetic stirring(V-EMS).The calculated distribution of magnetic induction intensity and final macrosegregation maps are consistent with the experimental results.Calculation results reveal that the V-EMS promotes longitudinal melt flow,accelerates heat dissipation and solidification and finally reduces the central segregation of carbon.However,when V-EMS is applied,the solute distribution becomes asymmetric because the melt flow shows opposite directions between the near and far sides from stirrer.An obvious positive segregation band is observed at about 1/4 width of the billet near the stirrer in both calculated and experimental results.The position and degree of such positive segregation could be affected by installation height of stirrer,as demonstrated by additional simulation cases.
基金supported by the“National Key Research and Development Program of China”under Project No.2016YFC0502403the“National Natural Science Foundation of China”under Project No.41230746,No.51621061.
文摘Stirring-sampling method is a widely adopted method to measure sediment concentrations in collection tanks of runoff plots,but with high systematic measurement errors.This research aimed to advance an approach for building correction equations to remove measurement errors in designed sediment concentration range.Experimental data of sediment measurement from the stirring-sampling method,with four representative soils,under the designed sediment concentrations(1,2,5,8,10,20,50,80,100,200,500,800,and 1000 kg/m^(3))were used to demonstrate the correction methodological process.Two correction methods(step-wise correction and universal correction)were suggested for the trial in this study based on the distribution of measurement errors.In the step-wise correction,the correction equations were made with a series of linear functions without intercept for the low concentration group(0-20 kg/m^(3)),a series of linear functions with intercept for the high(20-200 kg/m^(3))and extremely high(200-1000 kg/m^(3))concentration groups,consecutively.The correction equations were a series of power functions in the universal correction.For the step-wise correction,most of the relative errors of correction sediment concentrations were smaller than 15%and 10%under high and extremely high concentration groups,but the corrected accuracy was not good in the sediment concentration of 1,2,5 kg/m^(3)with the corrected relative errors of 0.20%-206.07%.For the universal correction,the corrected relative errors(0.19%-31.81%)of the four soils were low under the condition of extremely high sediment concentrations,but other corrected accuracies weren’t good with the corrected relative errors of 0.68%-1154.71%.The corrected accuracy of step-wise correction is higher than that of the universal correction,but the universal correction is more convenient.These results indicated that the correction equations could efficiently revise the measurement errors of the tested soils and that this method can be generalized to other soil types and was meaningf
