As a rare and valuable wood and herbal material, Dalbergia odorifera is often counterfeited by Dalbergia stevensonii in the market. For the confident chemical identification of D. odorifera and D. stevensonii, the eth...As a rare and valuable wood and herbal material, Dalbergia odorifera is often counterfeited by Dalbergia stevensonii in the market. For the confident chemical identification of D. odorifera and D. stevensonii, the ethanol-benzene extractives are characterized by multiple metabolomics tools, including Fourier transform infrared （FTIR） spectroscopy, nuclear magnetic resonance （NMR）, and gas chromatography- mass spectrometry （GC/MS）. Conventional FTIR spectroscopy, second derivative infrared （SD-IR） spectroscopy and two-dimensional correlation infrared （2D-IR） spectroscopy are combined to interpret the functional groups of the ethanol-benzene extractives. Fingerprint-like characteristics make FTIR a rapid and accurate method to distinguish D. odor/fera from D. stevensonii. Chemical differences of the extractives revealed by FrIR methods can be further confirmed by ^1H NMR and ^13C NMR. Meanwhile, the volatile compounds in the extractives can be identified by GC/MS. The combination of FTIR, NMR and GC/ MS makes it possible to obtain the multiple profiles of the ethanol-benzene extractives, which is essential for the confident chemical identification of D. odorifera and D. stevensonii.展开更多
基金supported by the National Natural Science Foundation of China(No.31670564)
文摘As a rare and valuable wood and herbal material, Dalbergia odorifera is often counterfeited by Dalbergia stevensonii in the market. For the confident chemical identification of D. odorifera and D. stevensonii, the ethanol-benzene extractives are characterized by multiple metabolomics tools, including Fourier transform infrared （FTIR） spectroscopy, nuclear magnetic resonance （NMR）, and gas chromatography- mass spectrometry （GC/MS）. Conventional FTIR spectroscopy, second derivative infrared （SD-IR） spectroscopy and two-dimensional correlation infrared （2D-IR） spectroscopy are combined to interpret the functional groups of the ethanol-benzene extractives. Fingerprint-like characteristics make FTIR a rapid and accurate method to distinguish D. odor/fera from D. stevensonii. Chemical differences of the extractives revealed by FrIR methods can be further confirmed by ^1H NMR and ^13C NMR. Meanwhile, the volatile compounds in the extractives can be identified by GC/MS. The combination of FTIR, NMR and GC/ MS makes it possible to obtain the multiple profiles of the ethanol-benzene extractives, which is essential for the confident chemical identification of D. odorifera and D. stevensonii.
