溶液法是新型光电器件制备的重要手段,然而以钙钛矿半导体材料为代表的薄膜样品制备通常需要在手套箱环境下完成,传统的实验表征大多在空气环境下进行,这显然很难反映薄膜结构与器件性能间的真实关联,因此急需对溶液成膜过程的微结构演...溶液法是新型光电器件制备的重要手段,然而以钙钛矿半导体材料为代表的薄膜样品制备通常需要在手套箱环境下完成,传统的实验表征大多在空气环境下进行,这显然很难反映薄膜结构与器件性能间的真实关联,因此急需对溶液成膜过程的微结构演变开展原位实时研究.为了实现溶液法成膜中的结构与形貌的同步辐射掠入射广角散射实时观测,本文结合上海同步辐射光源线站布局,报道了一种基于手套箱的原位成膜观测装置,可实现标准手套箱环境(c(H_(2)O,O_(2))<1×10^(-6))下远程控制薄膜旋涂、涂布及样品后处理,并实时可视化监测微结构和形貌演变.基于该装置进行的钙钛矿薄膜狭缝涂布大面积成膜结晶过程的原位GIWAXS/GISAXS(gtrazing incidence wide and small angle X-ray scattering)可视化测试揭示了薄膜微结构转变的内在驱动力:钙钛矿薄膜沉积界面层的优化对提升钙钛矿成核速率、诱导结晶择优取向、形成晶粒有序堆叠等具有“共性作用”,同时在成膜过程中的新生中间相显著提升软晶格薄膜质量和稳定性.基于各层均采用卷对卷全溶液狭缝涂布方法制备的大面积全柔性三维钙钛矿薄膜太阳能电池转换效率提升至5.23%(单个器件面积约15 cm^(2)),为迄今报道的这一体系该尺寸的全溶液狭缝涂布柔性钙钛矿器件的最高器件效率之一.因而,基于该同步辐射原位GIWAXS/S/GISAXS装置可以获得控制薄膜生长界面特性和薄膜品质的关键工艺,指导优化制备薄膜的最佳工艺条件.展开更多
Using the force constants of bond length, bond angle and dibedral angle, the harmonicvibration equations are given for a cubic structure system consisting of n = N_1×N_2×N_3atoms of the same sort. Numerical ...Using the force constants of bond length, bond angle and dibedral angle, the harmonicvibration equations are given for a cubic structure system consisting of n = N_1×N_2×N_3atoms of the same sort. Numerical computation has been carried out for various systems withthe values of n increasing from 8 to 1728 and with every same value of n but different val-ues of N_j. The convergent properties of solutions and the transition processes ot dimensionsare obtained. The true harmonic vibration spectrum of systems from zero--dimension to one-and three--dimension, the pattern of several low frequency modes, and the possible region ofcritical value H_c of force constant are given. A crystallized soft mode is found, whichleads to instability of the structure at the value of H-c.The differences between solutionsusing cyclic and free boundary conditions arc discussed and their correlation is explained; theconcept of harmonon is introduced. Taking barium titanate crystal as an example, the vari-ation of rotation modes under cyclic boundary condition is explained.展开更多
Soft set theory has a rich potential application in several fields. A soft group is a parameterized family of subgroups and a fuzzy soft group is a parameterized family of fuzzy subgroups. The concept of fuzzy soft gr...Soft set theory has a rich potential application in several fields. A soft group is a parameterized family of subgroups and a fuzzy soft group is a parameterized family of fuzzy subgroups. The concept of fuzzy soft group is the generalization of soft group. Abdulkadir Aygunoglu and Halis Aygun introduced the notion of fuzzy soft groups in 2009[1]. In this paper, the concept of lattice ordered fuzzy soft groups and its duality has been introduced. Then distributive and modular lattice ordered fuzzy soft groups are analysed. The objective of this paper is to study the lattice theory over the collection of fuzzy soft group in a parametric manner. Some pertinent properties have been analysed and hence established duality principle.展开更多
Liquid foam is a dense random packing of gas or liquid bubbles in a small amount of immiscible liquid containing surfactants. The liquid within the Plateau borders, although small in volume, causes considerable diffic...Liquid foam is a dense random packing of gas or liquid bubbles in a small amount of immiscible liquid containing surfactants. The liquid within the Plateau borders, although small in volume, causes considerable difficulties to the investigation of the spatial structure and physical properties of foams, and the situation becomes even more com-plicated as the fluid flows. To solve these problems, a discrete model of two-dimensional liquid foams on the bubble scale is proposed in this work. The bubble surface is represented with finite number of nodes, and the liquid within Plateau borders is discretized into lattice particles. The gas in bubbles is treated as ideal gas at constant temperatures. This model is tested by choosing an arbitrary shape bubble as the initial condition. This then automatically evolves into a cir-cular shape, which indicates that the surface energy minimum routine is obeyed without calling external controlling con-ditions. Without inserting liquid particle among the bubble channels, periodic ordered and disordered dry foams are both simulated, and the fine foam structures are developed. Wet foams are also simulated by inserting fluid among bubble channels. The calculated coordination number, as a function of liquid fractions, agrees well with the standard values.展开更多
文摘溶液法是新型光电器件制备的重要手段,然而以钙钛矿半导体材料为代表的薄膜样品制备通常需要在手套箱环境下完成,传统的实验表征大多在空气环境下进行,这显然很难反映薄膜结构与器件性能间的真实关联,因此急需对溶液成膜过程的微结构演变开展原位实时研究.为了实现溶液法成膜中的结构与形貌的同步辐射掠入射广角散射实时观测,本文结合上海同步辐射光源线站布局,报道了一种基于手套箱的原位成膜观测装置,可实现标准手套箱环境(c(H_(2)O,O_(2))<1×10^(-6))下远程控制薄膜旋涂、涂布及样品后处理,并实时可视化监测微结构和形貌演变.基于该装置进行的钙钛矿薄膜狭缝涂布大面积成膜结晶过程的原位GIWAXS/GISAXS(gtrazing incidence wide and small angle X-ray scattering)可视化测试揭示了薄膜微结构转变的内在驱动力:钙钛矿薄膜沉积界面层的优化对提升钙钛矿成核速率、诱导结晶择优取向、形成晶粒有序堆叠等具有“共性作用”,同时在成膜过程中的新生中间相显著提升软晶格薄膜质量和稳定性.基于各层均采用卷对卷全溶液狭缝涂布方法制备的大面积全柔性三维钙钛矿薄膜太阳能电池转换效率提升至5.23%(单个器件面积约15 cm^(2)),为迄今报道的这一体系该尺寸的全溶液狭缝涂布柔性钙钛矿器件的最高器件效率之一.因而,基于该同步辐射原位GIWAXS/S/GISAXS装置可以获得控制薄膜生长界面特性和薄膜品质的关键工艺,指导优化制备薄膜的最佳工艺条件.
基金Project supported by the Doctor Education Foundation, the State Education Commission, PRC.
文摘Using the force constants of bond length, bond angle and dibedral angle, the harmonicvibration equations are given for a cubic structure system consisting of n = N_1×N_2×N_3atoms of the same sort. Numerical computation has been carried out for various systems withthe values of n increasing from 8 to 1728 and with every same value of n but different val-ues of N_j. The convergent properties of solutions and the transition processes ot dimensionsare obtained. The true harmonic vibration spectrum of systems from zero--dimension to one-and three--dimension, the pattern of several low frequency modes, and the possible region ofcritical value H_c of force constant are given. A crystallized soft mode is found, whichleads to instability of the structure at the value of H-c.The differences between solutionsusing cyclic and free boundary conditions arc discussed and their correlation is explained; theconcept of harmonon is introduced. Taking barium titanate crystal as an example, the vari-ation of rotation modes under cyclic boundary condition is explained.
文摘Soft set theory has a rich potential application in several fields. A soft group is a parameterized family of subgroups and a fuzzy soft group is a parameterized family of fuzzy subgroups. The concept of fuzzy soft group is the generalization of soft group. Abdulkadir Aygunoglu and Halis Aygun introduced the notion of fuzzy soft groups in 2009[1]. In this paper, the concept of lattice ordered fuzzy soft groups and its duality has been introduced. Then distributive and modular lattice ordered fuzzy soft groups are analysed. The objective of this paper is to study the lattice theory over the collection of fuzzy soft group in a parametric manner. Some pertinent properties have been analysed and hence established duality principle.
文摘Liquid foam is a dense random packing of gas or liquid bubbles in a small amount of immiscible liquid containing surfactants. The liquid within the Plateau borders, although small in volume, causes considerable difficulties to the investigation of the spatial structure and physical properties of foams, and the situation becomes even more com-plicated as the fluid flows. To solve these problems, a discrete model of two-dimensional liquid foams on the bubble scale is proposed in this work. The bubble surface is represented with finite number of nodes, and the liquid within Plateau borders is discretized into lattice particles. The gas in bubbles is treated as ideal gas at constant temperatures. This model is tested by choosing an arbitrary shape bubble as the initial condition. This then automatically evolves into a cir-cular shape, which indicates that the surface energy minimum routine is obeyed without calling external controlling con-ditions. Without inserting liquid particle among the bubble channels, periodic ordered and disordered dry foams are both simulated, and the fine foam structures are developed. Wet foams are also simulated by inserting fluid among bubble channels. The calculated coordination number, as a function of liquid fractions, agrees well with the standard values.
