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硅钛摩尔比对熔盐电化学制备硅钛合金的影响 被引量:2
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作者 周忠仁 华一新 +4 位作者 张英杰 董鹏 杨宗洋 乔靖函 马久辉 《有色金属(冶炼部分)》 CAS 北大核心 2020年第4期37-40,共4页
为研究硅/钛摩尔比对熔盐电解制备硅钛合金组分及形貌的影响,以等摩尔比的CaCl2-NaCl熔盐为电解质,通过改变电解原料中硅/钛摩尔比,在槽电压2.4 V、电解温度700℃下电解5 h获得电解产物。结果表明,当硅/钛摩尔比分别为20、25和50时,电... 为研究硅/钛摩尔比对熔盐电解制备硅钛合金组分及形貌的影响,以等摩尔比的CaCl2-NaCl熔盐为电解质,通过改变电解原料中硅/钛摩尔比,在槽电压2.4 V、电解温度700℃下电解5 h获得电解产物。结果表明,当硅/钛摩尔比分别为20、25和50时,电解产物均为单质Si和TiSi2合金,微观形貌分别为50~100 nm纳米线和50~200 nm微粒混合、30~50 nm纳米线和100~250 nm微粒以及粒径0.2~2.5μm的块状颗粒。 展开更多
关键词 硅钛合金 硅钛摩尔比 熔盐电化学
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Preparation of Al-Si-Ti Master Alloys by Electrolysis of Silica and Titania in Cryolite-Alumina Melts
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作者 卢惠民 邹兴 +2 位作者 方克明 洪彦若 邱竹贤 《Rare Metals》 SCIE EI CAS CSCD 2000年第2期141-146,136,共6页
Aluminum silicon titanium master alloys were prepared in the laboratory by electrolysis of silica and titania dissolved in cryolite alumina melts. Alloys containing up to 12 mass% Si and 2.6 mass% Ti were formed af... Aluminum silicon titanium master alloys were prepared in the laboratory by electrolysis of silica and titania dissolved in cryolite alumina melts. Alloys containing up to 12 mass% Si and 2.6 mass% Ti were formed after about 90 min of electrolysis at 950℃. The current efficiency for the preparation of the Al Si Ti alloys varied with time, temperature and cathodic current density. It is concluded that this electrolytic method may be an interesting alternative to the direct metal mixing process for formation of Al Si Ti master alloys. 展开更多
关键词 Aluminum silicon titanium alloys Molten salt electrolysis method Cryolite alumina melts
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