In this study,we developed a facile one-step hydrothermal process that allows to synthesize high-purity V0_(2)(M/R)nanoparticles with various morphologies such as nanorods,nanogranules,nanoblocks,and nanospheres.W dop...In this study,we developed a facile one-step hydrothermal process that allows to synthesize high-purity V0_(2)(M/R)nanoparticles with various morphologies such as nanorods,nanogranules,nanoblocks,and nanospheres.W dopants are successfully implanted in V02(M/R)unit cells with high doping efficiency,which allows to regulate the size,morphology,and phase of obtained nanoparticles.The underlying regulation mechanism is presented in detail to reveal how hydrothermal products vary with W doping contents,which provides a synthetic strategy for the preparation of shape-controlling V02(M/R)nanoparticles with high purity to satisfy different specific demands for corresponding applications in the field of thermochromic smart windows.展开更多
文摘In this study,we developed a facile one-step hydrothermal process that allows to synthesize high-purity V0_(2)(M/R)nanoparticles with various morphologies such as nanorods,nanogranules,nanoblocks,and nanospheres.W dopants are successfully implanted in V02(M/R)unit cells with high doping efficiency,which allows to regulate the size,morphology,and phase of obtained nanoparticles.The underlying regulation mechanism is presented in detail to reveal how hydrothermal products vary with W doping contents,which provides a synthetic strategy for the preparation of shape-controlling V02(M/R)nanoparticles with high purity to satisfy different specific demands for corresponding applications in the field of thermochromic smart windows.