The effect of copper concentration on the performance of the catalytic reaction between silicon and methyl chloride was investigated using online gas chromatogram. The catalyst concentration greatly influences various...The effect of copper concentration on the performance of the catalytic reaction between silicon and methyl chloride was investigated using online gas chromatogram. The catalyst concentration greatly influences various aspects of the direct organosilane synthesis process, including the reaction rate, the selec- tivity, and the silicon conversion. The reaction activity and the silicon conversion increase as the catalyst concentration increases. However, the reaction selectivity decreases for the catalyst concentrations more .than 9 wt.%. The cross-sections of deactivated contact mass particles were observed by optical microscopy and analyzed by scanning electron microscope combined with energy dispersive X-ray detector （SEM-EDX） The observations showed that a textured substance formed on the original flat surface of the silicon particles after deactivation with copper only in a shallow surface layer of the contact mass. This indicates that the copper diffusion is the rate limiting step which causes the reaction deactivation.展开更多
The microstructural changes of Fe83Si4B13 amorphous mother alloy during the heating process were investigated by Laser Scanning Confocal Microscopy （LSCM） ,and the phase transformation was determined by the Thermo-C...The microstructural changes of Fe83Si4B13 amorphous mother alloy during the heating process were investigated by Laser Scanning Confocal Microscopy （LSCM） ,and the phase transformation was determined by the Thermo-Calc calculations. The differences in the melting points measured by Differential Scanning Calorimetry （DSC） and LSCM, and those obtained by Thermo-Calc calculations were also discussed. It is found that the melting points measured by DSC and LSCM are relatively similar, whereas the onset and end of the melting temperatures calculated by Thermo-Calc software are higher than those measured by DSC and observed by LSCM.展开更多
Recycled aggregates(RA)are frequently obtained from various unknown sources,which caused variation in properties among recycled aggregates concrete(RAC).This paper investigated the macro and microscopic properties o...Recycled aggregates(RA)are frequently obtained from various unknown sources,which caused variation in properties among recycled aggregates concrete(RAC).This paper investigated the macro and microscopic properties of RAC prepared with RAs originated from different parent concretes with 90-day strength ranging from 30 MPa to 100 MPa.These parent concretes were prepared in advance and crushed to produce RA of distinct qualities.The attached mortar content can reach up to 69%in the concrete with highest strength grade.The microscopic investigation on different RAC was conducted with the X-ray Micro-Computed Tomography scanning technique and image process.Experimental results showed that the properties of RA derived from various parent concrete varied because of the amount of residual mortar.The development of mechanical properties and chloride-ion penetration of RACs all followed a binomial trend with the strength grades of the parent concrete because of the different quantity and quality of RAs.展开更多
文摘The effect of copper concentration on the performance of the catalytic reaction between silicon and methyl chloride was investigated using online gas chromatogram. The catalyst concentration greatly influences various aspects of the direct organosilane synthesis process, including the reaction rate, the selec- tivity, and the silicon conversion. The reaction activity and the silicon conversion increase as the catalyst concentration increases. However, the reaction selectivity decreases for the catalyst concentrations more .than 9 wt.%. The cross-sections of deactivated contact mass particles were observed by optical microscopy and analyzed by scanning electron microscope combined with energy dispersive X-ray detector （SEM-EDX） The observations showed that a textured substance formed on the original flat surface of the silicon particles after deactivation with copper only in a shallow surface layer of the contact mass. This indicates that the copper diffusion is the rate limiting step which causes the reaction deactivation.
文摘The microstructural changes of Fe83Si4B13 amorphous mother alloy during the heating process were investigated by Laser Scanning Confocal Microscopy （LSCM） ,and the phase transformation was determined by the Thermo-Calc calculations. The differences in the melting points measured by Differential Scanning Calorimetry （DSC） and LSCM, and those obtained by Thermo-Calc calculations were also discussed. It is found that the melting points measured by DSC and LSCM are relatively similar, whereas the onset and end of the melting temperatures calculated by Thermo-Calc software are higher than those measured by DSC and observed by LSCM.
基金This research was funded by the National Natural Science Foundation of China[Grant Number 51708419].
文摘Recycled aggregates(RA)are frequently obtained from various unknown sources,which caused variation in properties among recycled aggregates concrete(RAC).This paper investigated the macro and microscopic properties of RAC prepared with RAs originated from different parent concretes with 90-day strength ranging from 30 MPa to 100 MPa.These parent concretes were prepared in advance and crushed to produce RA of distinct qualities.The attached mortar content can reach up to 69%in the concrete with highest strength grade.The microscopic investigation on different RAC was conducted with the X-ray Micro-Computed Tomography scanning technique and image process.Experimental results showed that the properties of RA derived from various parent concrete varied because of the amount of residual mortar.The development of mechanical properties and chloride-ion penetration of RACs all followed a binomial trend with the strength grades of the parent concrete because of the different quantity and quality of RAs.
