This paper presents a three-dimensional, three-phase compositional model considering CO2 phase equilibrium between water and oil. In this model, CO2 is mutually soluble in aqueous and hydrocarbon phases, while other c...This paper presents a three-dimensional, three-phase compositional model considering CO2 phase equilibrium between water and oil. In this model, CO2 is mutually soluble in aqueous and hydrocarbon phases, while other components, except water,exist in hydrocarbon phase. The Peng–Robinson(PR) equation of state and the Wong–Sandler mixing rule with non-random two-liquid parameters are used to calculate CO2 fugacity in the aqueous phase. One-dimensional and three-dimensional CO2 flooding examples show that a significant amount of injected CO2 is dissolved in water. Our simulation shows 7% of injected CO2 can be dissolved in the aqueous phase, which delays oil recovery by 4%. The gas rate predicted by the model is smaller than the conventional model as long as water is undersaturated by CO2, which can be considered as 'lost' in the aqueous phase. The model also predicts that the delayed oil can be recovered after the gas breakthrough, indicating that delayed oil is hard to recover in field applications. A three-dimensional example reveals that a highly stratified reservoir causes uneven displacement and serious CO2 breakthrough. If mobility control measures like water alternating gas are undertaken, the solubility e ects will be more pronounced than this example.展开更多
The phase equilibrium data of CO2 hydrocarbon binary mixtures are important for the design and operation of CO 2 ood- ing, coal liquefaction, and supercritical extraction processes. Numerous pieces of binary phase equ...The phase equilibrium data of CO2 hydrocarbon binary mixtures are important for the design and operation of CO 2 ood- ing, coal liquefaction, and supercritical extraction processes. Numerous pieces of binary phase equilibrium data have been obtained. Thus, models for the accurate calculation of binary and multicomponent mixtures must be developed on the basis of existing data. In this work, 3578 vapor liquid phase equilibrium data points for 10 CO 2 hydrocarbon binary mixtures, including CO2 butane, CO 2 pentane, CO 2 isopentane, C O 2 hexane, CO 2 benzene, CO 2 heptane, CO 2 octane, C O 2 non- ane, CO 2 decane, and C O 2 undecane, were collected. The PR and PR-BM equations of state (EOS) in combination with relevant mixing rules were used to calculate the phase equilibrium data of the CO 2 hydrocarbon binary mixtures. The binary interaction parameter k ij in the PR EOS was temperature independent, whereas parameters in the PR-BM EOS were functions of temperature. Thus, the phase equilibrium data and other thermodynamic properties of the binary and multicomponent mixtures at di erent temperatures and pressures can be calculated by using the parameters obtained in this work. The PR-BM EOS performed better than the PR EOS, and the average absolute deviations over the temperature range of 255.98 408.15 K calculated by the PR EOS and PR-BM EOS were less than 5.74% and 3.36%, respectively. The results calculated by the two EOS were compared with those calculated by other models, such as PPR78, PR + LCVM + UNIFAC, KIE + PR EOS + HV, and PSRK. The phase equilibrium data of CO 2 butane decane, CO 2 hexane decane, and C O 2 octane decane ternary mixtures were calculated by the two EOS. The average overall deviations for the CO 2 mole fractions calculated by the two EOS were less than 7.66%.展开更多
In this paper, we find two formulas for the solutions of the following linear equation , where is a real matrix. This system has been well studied since the 1970s. It is known and simple proven that there is a solutio...In this paper, we find two formulas for the solutions of the following linear equation , where is a real matrix. This system has been well studied since the 1970s. It is known and simple proven that there is a solution for all if, and only if, the rows of A are linearly independent, and the minimum norm solution is given by the Moore-Penrose inverse formula, which is often denoted by;in this case, this solution is given by . Using this formula, Cramer’s Rule and Burgstahler’s Theorem (Theorem 2), we prove the following representation for this solution , where are the row vectors of the matrix A. To the best of our knowledge and looking in to many Linear Algebra books, there is not formula for this solution depending on determinants. Of course, this formula coincides with the one given by Cramer’s Rule when .展开更多
The cascade algorithm plays an important role in computer graphics and wavelet analysis. For any initial function φn, a cascade sequence (φn)n∞=1 constructed by the iteration φn=Cnφn-1=1,2.. where Cαis defined b...The cascade algorithm plays an important role in computer graphics and wavelet analysis. For any initial function φn, a cascade sequence (φn)n∞=1 constructed by the iteration φn=Cnφn-1=1,2.. where Cαis defined by g∈Lp(R) In this paper, we characterize the convergence of a cascade sequence in terms of a sequence of functions and in terms of joint spectral radius. As a consequence, it is proved that any convergent cascade sequence has a convergence rate of geometry, i.e., ||φ+1-φn||Lp(R)=O((?)n)for some (?)∈(0.1i). The condition of sum rules for the mask is not required. Finally, an example is presented to illustrate our theory.展开更多
A new excess Gibbs free energy/equation of state type mixing 0rule was derived byremoving the infinite pressure boundary condition imposed by Wong and Sandler.The mixing rulewas extensively tested in terms of a compre...A new excess Gibbs free energy/equation of state type mixing 0rule was derived byremoving the infinite pressure boundary condition imposed by Wong and Sandler.The mixing rulewas extensively tested in terms of a comprehensive data base,consisting of 52 simple nonpolar-nonpolar,carbon dioxide containing,hydrocarbon-hydrocarbon,CFC,polar-polar,nonpolar-polarbinary and multicomponent systems.Focused on the complete predictive capability,a comparisonbetween the Wong-Sandler and the mixing rule proposed was conducted.The results indicate that thenew mixing rule is in general superior to the Wong-Sandler’s,and the binary interaction parameteras required by the latter is removed,which reduces computing effort and is reliable in predictions ofvapor-liquid equilibria from low pressures to high pressures.展开更多
In this paper was extended the HV-type mixing rules to Harmens-Knapp cubic equation state(HK CEOS). The new HV-type mixing rule with HK CEOS was tested for Vapor-liquid equilibrium(VLE) of different polar and nonpolar...In this paper was extended the HV-type mixing rules to Harmens-Knapp cubic equation state(HK CEOS). The new HV-type mixing rule with HK CEOS was tested for Vapor-liquid equilibrium(VLE) of different polar and nonpolar systems. The tested results are in good agreement with existing experimental data within a wide range of temperatures and pressures. In comparison with the VDW mixing rule, the new mixing rule gives much better predictions for the VLE of nonpolar and polar systems.展开更多
Transient analysis of 33 KV power transmission line stability of Egi communi-ty is considered in this research work with the aim of reducing the frequency of fault occurrence and voltage collapse in the network. The s...Transient analysis of 33 KV power transmission line stability of Egi communi-ty is considered in this research work with the aim of reducing the frequency of fault occurrence and voltage collapse in the network. The supply is taken from Egi generating station located at Total Nigeria Limited Gas Plant Obite at voltage level of 33 KV to Egi communities. This work focuses on the transient nature of network stability since transient fault is the most dangerous in elec-trical systems. The swinging of the generator rotor in the event of transient three-phase short circuit fault can be monitored by the circuit breakers and the protective relays which causes mal-functioning of the circuit breakers and pro-tective relays leading to abnormal behavior of the network. Therefore, data obtained from the power station were used as a case study of Independent Power Producer (IPP) in Nigeria. For investigation of the power angle, angular velocity, rotor angle differential changes, and angular velocity differential changes, an electrical transient analyzer tool was employed (ETap version 16.00) for circuit breaker and protective relay time setting of (0.00, 0.05, 0.10, 0.15, 0.20, 0.25, 0.30, 0.35, 0.40, 0.45, 0.50, 0.55, 0.60). The work used the Trapezoidal numerical technique for data analysis. The graphs were plotted using Matlab R2015a and the results obtained showed that when a symmetrical three-phase short circuit fault occur at one or any of the feeders, the fault must be cleared as quick as possible through the coordination of the circuit breakers and protective relays. For this research work, 17 cycles corresponding to relay time setting of t = 0.34 s were recommended and at each cycle, changes in time with respect to changes in rotor angle, angular velocity, rotor differential and angular velocity differential were calculated on the power network simultaneously. The results demonstrated that the Trapezoidal method is numerically stable, accurate and has faster respond time when compared to Modified Euler and swing equat展开更多
A new non-cubic equation of state is proposed for calculation of the thermodynamic properties ofnonpolar and polar fluids and their mixtures,including,saturated vapor pressure,saturated liquid volume,saturated vapor v...A new non-cubic equation of state is proposed for calculation of the thermodynamic properties ofnonpolar and polar fluids and their mixtures,including,saturated vapor pressure,saturated liquid volume,saturated vapor volume,heats of vaporization and vapor-liquid equilibria.The new equation is derived from thegeneralized van der Waals partition function in which the repulsive terms are expressed with the Carnahan andStarling equation for hard spheres,and the attractive terms are made up of the dispersive energy and theChemical association energy. The rules of dependence of parameters α and σ and on temperature are considered broadly so that the newequation yields good agreement with experimental saturated properties of 20 nonpolar and 27 polar fluids in therange of reduced temperatures of 0.5 to 1.0 The new equation with parameters group-contributed generally givessatisfactory predictions on saturated properties. Correlations of vapor-liquid equilibrium data for alcohol-containing systems by using van展开更多
Cubic equations of state EOS have been combined with the absolute rate theory of Eyring to calculate viscosities of liquid mixtures. A modified Huron-Vidal gE-mixing rule is employed in the calculation and in com- par...Cubic equations of state EOS have been combined with the absolute rate theory of Eyring to calculate viscosities of liquid mixtures. A modified Huron-Vidal gE-mixing rule is employed in the calculation and in com- parison with the van Laar and the Redlich-Kister-type mixing rule. The EOS method gives an accurate correlation of liquid viscosities with an overall average deviation less than 1% for 67 binary systems including aqueous solu- tions. It is also successful in extrapolating viscosity data over a certain temperature range using parameters obtained from the isotherm at a given temperature and in predicting viscosities of ternary solutions from binary parameters for either polar or associated systems.展开更多
The simple equation relating the activity coefficient of each solute in mixed electrolyte solution to its value in binary solutions under isopiestic equilibrium was tested by comparison with the experimental data for ...The simple equation relating the activity coefficient of each solute in mixed electrolyte solution to its value in binary solutions under isopiestic equilibrium was tested by comparison with the experimental data for the 18 electrolyte solutions consisting of 1：1, 1：2, and 1：3 electrolytes. The isopiestic measurements were made on the quaternary system BaCl2-NH4Br-NaI-H2O and its ternary subsystems NaI-NH4Br-H2O, NaI-BaCl2-H2O, and NH4Br-BaCl2-H2O at 298.15K. The results were used to test the applicability of the Zdanovskii＇s rule to the mixed electrolyte solutions which contain no common ions, and the agreement is excellent. The activity coefficients of the solutes in the above quaternary and ternary systems calculated from the above-mentioned simple equation are in good agreement with the Pitzer＇s equation.展开更多
基金financially supported by National Natural Science Foundation of China(U1762101)National Science and Technology Major Projects(2017ZX05069)
文摘This paper presents a three-dimensional, three-phase compositional model considering CO2 phase equilibrium between water and oil. In this model, CO2 is mutually soluble in aqueous and hydrocarbon phases, while other components, except water,exist in hydrocarbon phase. The Peng–Robinson(PR) equation of state and the Wong–Sandler mixing rule with non-random two-liquid parameters are used to calculate CO2 fugacity in the aqueous phase. One-dimensional and three-dimensional CO2 flooding examples show that a significant amount of injected CO2 is dissolved in water. Our simulation shows 7% of injected CO2 can be dissolved in the aqueous phase, which delays oil recovery by 4%. The gas rate predicted by the model is smaller than the conventional model as long as water is undersaturated by CO2, which can be considered as 'lost' in the aqueous phase. The model also predicts that the delayed oil can be recovered after the gas breakthrough, indicating that delayed oil is hard to recover in field applications. A three-dimensional example reveals that a highly stratified reservoir causes uneven displacement and serious CO2 breakthrough. If mobility control measures like water alternating gas are undertaken, the solubility e ects will be more pronounced than this example.
基金supported by the National Key Research and Development Program of China (2016YFB0600804-3)Shandong Natural Science Foundation (ZR2017BB076)
文摘The phase equilibrium data of CO2 hydrocarbon binary mixtures are important for the design and operation of CO 2 ood- ing, coal liquefaction, and supercritical extraction processes. Numerous pieces of binary phase equilibrium data have been obtained. Thus, models for the accurate calculation of binary and multicomponent mixtures must be developed on the basis of existing data. In this work, 3578 vapor liquid phase equilibrium data points for 10 CO 2 hydrocarbon binary mixtures, including CO2 butane, CO 2 pentane, CO 2 isopentane, C O 2 hexane, CO 2 benzene, CO 2 heptane, CO 2 octane, C O 2 non- ane, CO 2 decane, and C O 2 undecane, were collected. The PR and PR-BM equations of state (EOS) in combination with relevant mixing rules were used to calculate the phase equilibrium data of the CO 2 hydrocarbon binary mixtures. The binary interaction parameter k ij in the PR EOS was temperature independent, whereas parameters in the PR-BM EOS were functions of temperature. Thus, the phase equilibrium data and other thermodynamic properties of the binary and multicomponent mixtures at di erent temperatures and pressures can be calculated by using the parameters obtained in this work. The PR-BM EOS performed better than the PR EOS, and the average absolute deviations over the temperature range of 255.98 408.15 K calculated by the PR EOS and PR-BM EOS were less than 5.74% and 3.36%, respectively. The results calculated by the two EOS were compared with those calculated by other models, such as PPR78, PR + LCVM + UNIFAC, KIE + PR EOS + HV, and PSRK. The phase equilibrium data of CO 2 butane decane, CO 2 hexane decane, and C O 2 octane decane ternary mixtures were calculated by the two EOS. The average overall deviations for the CO 2 mole fractions calculated by the two EOS were less than 7.66%.
文摘In this paper, we find two formulas for the solutions of the following linear equation , where is a real matrix. This system has been well studied since the 1970s. It is known and simple proven that there is a solution for all if, and only if, the rows of A are linearly independent, and the minimum norm solution is given by the Moore-Penrose inverse formula, which is often denoted by;in this case, this solution is given by . Using this formula, Cramer’s Rule and Burgstahler’s Theorem (Theorem 2), we prove the following representation for this solution , where are the row vectors of the matrix A. To the best of our knowledge and looking in to many Linear Algebra books, there is not formula for this solution depending on determinants. Of course, this formula coincides with the one given by Cramer’s Rule when .
基金This work was supported by the National Natural Science Foundation of China(Grant No.10171007).
文摘The cascade algorithm plays an important role in computer graphics and wavelet analysis. For any initial function φn, a cascade sequence (φn)n∞=1 constructed by the iteration φn=Cnφn-1=1,2.. where Cαis defined by g∈Lp(R) In this paper, we characterize the convergence of a cascade sequence in terms of a sequence of functions and in terms of joint spectral radius. As a consequence, it is proved that any convergent cascade sequence has a convergence rate of geometry, i.e., ||φ+1-φn||Lp(R)=O((?)n)for some (?)∈(0.1i). The condition of sum rules for the mask is not required. Finally, an example is presented to illustrate our theory.
基金Supported by the National Natural Science Foundation of China(No.29676003)and China Petro-chemical.Corporation.
文摘A new excess Gibbs free energy/equation of state type mixing 0rule was derived byremoving the infinite pressure boundary condition imposed by Wong and Sandler.The mixing rulewas extensively tested in terms of a comprehensive data base,consisting of 52 simple nonpolar-nonpolar,carbon dioxide containing,hydrocarbon-hydrocarbon,CFC,polar-polar,nonpolar-polarbinary and multicomponent systems.Focused on the complete predictive capability,a comparisonbetween the Wong-Sandler and the mixing rule proposed was conducted.The results indicate that thenew mixing rule is in general superior to the Wong-Sandler’s,and the binary interaction parameteras required by the latter is removed,which reduces computing effort and is reliable in predictions ofvapor-liquid equilibria from low pressures to high pressures.
文摘In this paper was extended the HV-type mixing rules to Harmens-Knapp cubic equation state(HK CEOS). The new HV-type mixing rule with HK CEOS was tested for Vapor-liquid equilibrium(VLE) of different polar and nonpolar systems. The tested results are in good agreement with existing experimental data within a wide range of temperatures and pressures. In comparison with the VDW mixing rule, the new mixing rule gives much better predictions for the VLE of nonpolar and polar systems.
文摘Transient analysis of 33 KV power transmission line stability of Egi communi-ty is considered in this research work with the aim of reducing the frequency of fault occurrence and voltage collapse in the network. The supply is taken from Egi generating station located at Total Nigeria Limited Gas Plant Obite at voltage level of 33 KV to Egi communities. This work focuses on the transient nature of network stability since transient fault is the most dangerous in elec-trical systems. The swinging of the generator rotor in the event of transient three-phase short circuit fault can be monitored by the circuit breakers and the protective relays which causes mal-functioning of the circuit breakers and pro-tective relays leading to abnormal behavior of the network. Therefore, data obtained from the power station were used as a case study of Independent Power Producer (IPP) in Nigeria. For investigation of the power angle, angular velocity, rotor angle differential changes, and angular velocity differential changes, an electrical transient analyzer tool was employed (ETap version 16.00) for circuit breaker and protective relay time setting of (0.00, 0.05, 0.10, 0.15, 0.20, 0.25, 0.30, 0.35, 0.40, 0.45, 0.50, 0.55, 0.60). The work used the Trapezoidal numerical technique for data analysis. The graphs were plotted using Matlab R2015a and the results obtained showed that when a symmetrical three-phase short circuit fault occur at one or any of the feeders, the fault must be cleared as quick as possible through the coordination of the circuit breakers and protective relays. For this research work, 17 cycles corresponding to relay time setting of t = 0.34 s were recommended and at each cycle, changes in time with respect to changes in rotor angle, angular velocity, rotor differential and angular velocity differential were calculated on the power network simultaneously. The results demonstrated that the Trapezoidal method is numerically stable, accurate and has faster respond time when compared to Modified Euler and swing equat
文摘A new non-cubic equation of state is proposed for calculation of the thermodynamic properties ofnonpolar and polar fluids and their mixtures,including,saturated vapor pressure,saturated liquid volume,saturated vapor volume,heats of vaporization and vapor-liquid equilibria.The new equation is derived from thegeneralized van der Waals partition function in which the repulsive terms are expressed with the Carnahan andStarling equation for hard spheres,and the attractive terms are made up of the dispersive energy and theChemical association energy. The rules of dependence of parameters α and σ and on temperature are considered broadly so that the newequation yields good agreement with experimental saturated properties of 20 nonpolar and 27 polar fluids in therange of reduced temperatures of 0.5 to 1.0 The new equation with parameters group-contributed generally givessatisfactory predictions on saturated properties. Correlations of vapor-liquid equilibrium data for alcohol-containing systems by using van
基金the Deutsche Forschungsgemeinschaft (LE 886/4-1) the Foundation of Zhejiang Province for ScholarsReturned from Abroad
文摘Cubic equations of state EOS have been combined with the absolute rate theory of Eyring to calculate viscosities of liquid mixtures. A modified Huron-Vidal gE-mixing rule is employed in the calculation and in com- parison with the van Laar and the Redlich-Kister-type mixing rule. The EOS method gives an accurate correlation of liquid viscosities with an overall average deviation less than 1% for 67 binary systems including aqueous solu- tions. It is also successful in extrapolating viscosity data over a certain temperature range using parameters obtained from the isotherm at a given temperature and in predicting viscosities of ternary solutions from binary parameters for either polar or associated systems.
基金the National-Natural Science Foundation of China （No.20476059, No.20276037） and 863 Hi-Technology Research and Development Program of China （2004 AA616040）.
文摘The simple equation relating the activity coefficient of each solute in mixed electrolyte solution to its value in binary solutions under isopiestic equilibrium was tested by comparison with the experimental data for the 18 electrolyte solutions consisting of 1：1, 1：2, and 1：3 electrolytes. The isopiestic measurements were made on the quaternary system BaCl2-NH4Br-NaI-H2O and its ternary subsystems NaI-NH4Br-H2O, NaI-BaCl2-H2O, and NH4Br-BaCl2-H2O at 298.15K. The results were used to test the applicability of the Zdanovskii＇s rule to the mixed electrolyte solutions which contain no common ions, and the agreement is excellent. The activity coefficients of the solutes in the above quaternary and ternary systems calculated from the above-mentioned simple equation are in good agreement with the Pitzer＇s equation.
