A novel phenolic rigid organic filler （named KD） with a high melting point was dispersed in an isotactic polypropylene （iPP） matrix by solution-mixing and/or melt-mixing. A series of KD/iPP blends was prepared wit...A novel phenolic rigid organic filler （named KD） with a high melting point was dispersed in an isotactic polypropylene （iPP） matrix by solution-mixing and/or melt-mixing. A series of KD/iPP blends was prepared with or without addition of maleic anhydride-grafted polypro- pylene （MAPP） as a compatibilizer. Influences of MAPP and mixing methods on the filler dispersion were studied using polaried optical microscope （POM）, scanning electron microscope （SEM） and tensile test. The filler particles are always inclined to form large irregular aggregates in the iPP matrix due to their significant differences in polarity and solubility in solvent. However, an iPP/MAPP/KD （PMK） blend containing filler particles with a quasi-spherical shape （-97.8 nm in diameter） and narrow particle size distribution （polydispersity index = 1.076） was successfully prepared by incorporating MAPP to reduce the interfacial tension and surface free energy between the dispersion phase and the continuous phase, and adopting a spray-drying method after solution-mixing to suppress the increase of the size of the dispersed phase during the removal of solvent.展开更多
文摘A novel phenolic rigid organic filler （named KD） with a high melting point was dispersed in an isotactic polypropylene （iPP） matrix by solution-mixing and/or melt-mixing. A series of KD/iPP blends was prepared with or without addition of maleic anhydride-grafted polypro- pylene （MAPP） as a compatibilizer. Influences of MAPP and mixing methods on the filler dispersion were studied using polaried optical microscope （POM）, scanning electron microscope （SEM） and tensile test. The filler particles are always inclined to form large irregular aggregates in the iPP matrix due to their significant differences in polarity and solubility in solvent. However, an iPP/MAPP/KD （PMK） blend containing filler particles with a quasi-spherical shape （-97.8 nm in diameter） and narrow particle size distribution （polydispersity index = 1.076） was successfully prepared by incorporating MAPP to reduce the interfacial tension and surface free energy between the dispersion phase and the continuous phase, and adopting a spray-drying method after solution-mixing to suppress the increase of the size of the dispersed phase during the removal of solvent.
