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一种硬质PVC用复合发泡剂的制备及热性能研究 被引量:3
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作者 谢祥林 黄碧玉 +1 位作者 苏胜培 冯建湘 《塑料助剂》 2009年第3期19-23,共5页
用碳酸氢钠(NaHCO3)、偶氮二甲酰胺(AC)及硬脂酸铅(PbSt)为原料制备吸放热复合发泡剂,通过差热与热重分析研究了发泡剂的热分解性能。结果表明:NaHCO3与AC之质量比为100∶20的发泡剂分解温度在170~188℃之间,且分解平稳,适合硬质PVC发... 用碳酸氢钠(NaHCO3)、偶氮二甲酰胺(AC)及硬脂酸铅(PbSt)为原料制备吸放热复合发泡剂,通过差热与热重分析研究了发泡剂的热分解性能。结果表明:NaHCO3与AC之质量比为100∶20的发泡剂分解温度在170~188℃之间,且分解平稳,适合硬质PVC发泡材料加工。PbSt含量超过10%会影响发泡剂的分解率。用自制的吸-放热复合发泡剂用于硬质PVC挤出制备发泡材料,其密度可达约0.8g/cm3,且发泡材料泡孔细密均匀。 展开更多
关键词 硬质pvc发泡材料 吸-放热复合发泡剂 偶氮二甲酰胺 碳酸氢钠 热性能
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Comparative Analysis of Rigid PVC Foam Reinforced with Class C and Class F Fly Ash 被引量:1
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作者 Parisa Khoshnoud Subhashini Gunashekar +1 位作者 Murtatha M. Jamel Nidal Abu-Zahra 《Journal of Minerals and Materials Characterization and Engineering》 2014年第6期554-565,共12页
Fly ash particles are usually spherical and based on their chemical composition;they are categorized into two classes: C and F. This study compares the microstructural, mechanical and thermal properties of extruded ri... Fly ash particles are usually spherical and based on their chemical composition;they are categorized into two classes: C and F. This study compares the microstructural, mechanical and thermal properties of extruded rigid PVC foam composites reinforced with class C and class F fly ash. The mechanical properties: such as tensile and flexural strength of composites containing class C fly ash were superior to the composites containing class F fly ash particles. Composites containing 6 phr class C fly ash showed a 24% improvement in the tensile strength in comparison to a mere 0.5% increase in composites reinforced with class F fly ash. Similarly, the addition of 6 phr of class F fly ash to the PVC foam matrix resulted in a 5.74% decrease in the flexural strength, while incorporating the same amount of class C fly ash led to a 95% increase in flexural strength. The impact strength of the composites decreased as the amount of either type of fly ash increased in the composites indicating that fly ash particles improve the rigidity of the PVC foam composites. No significant changes were observed in the thermal properties of the composites containing either type of fly ash particles. However, the thermo-mechanical properties measured by DMA indicated a steep increase in the viscoelastic properties of composites reinforced with class C flyash. The microstructural properties studied by Scanning Electron Microscopy (SEM) confirmed that fly ash particles were mechanically interlocked in the PVC matrix with good interfacial interaction with the matrix. However, particle agglomeration and debonding was observed in composites reinforced with higher amounts of fly ash. 展开更多
关键词 rigid pvc foam CLASS C FLY ASH CLASS F FLY ASH THERMO-MECHANICAL Properties Morphology
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