Nowadays, energy shortage and environmental pollution issues are increasingly severe and urgent to be solved. The effective storage and use of environmentally friendly fuels and removal of harmful gases from the envir...Nowadays, energy shortage and environmental pollution issues are increasingly severe and urgent to be solved. The effective storage and use of environmentally friendly fuels and removal of harmful gases from the environment are great challenges and of great importance both for the environment protection and for human health. Porous met- al-organic frameworks （MOFs） are highly ordered crystalline materials formed by the self-assembly process of metal ions and organic ligands. Their good features such as ultrahigh porosity, large surface area, structural diversity and functionalities make them promising candidates for applications in energy and environmental fields. MOF thin films and MOF composites have also been investigated to further enhance the properties and introduce new func- tionalities. This review provides an overview of the synthesis methods of pristine MOFs, MOF thin films and MOF composites, and significant advances of MOFs in energy and environment applications such as energy storage （H2, CH4）, CO2 capture and separation, adsorption removal and sensing of harmful gases in the environment.展开更多
Liquid Air Energy Storage(LAES)is at pilot scale.Air cooling and liquefaction stores energy;reheating revaporises the air at pressure,powering a turbine or engine(Ameel et al.,2013).Liquefaction requires water&CO2...Liquid Air Energy Storage(LAES)is at pilot scale.Air cooling and liquefaction stores energy;reheating revaporises the air at pressure,powering a turbine or engine(Ameel et al.,2013).Liquefaction requires water&CO2 removal,preventing ice fouling.This paper proposes subsequent geological storage of this CO2–offering a novel Carbon Dioxide Removal(CDR)by-product,for the energy storage industry.It additionally assesses the scale constraint and economic opportunity offered by implementing this CDR approach.Similarly,established Compressed Air Energy Storage(CAES)uses air compression and subsequent expansion.CAES could also add CO2 scrubbing and subsequent storage,at extra cost.CAES stores fewer joules per kilogram of air than LAES–potentially scrubbing more CO2 per joule stored.Operational LAES/CAES technologies cannot offer full-scale CDR this century(Stocker et al.,2014),yet they could offer around 4%of projected CO2 disposals for LAES and<25%for current-technology CAES.LAES CDR could reach trillion-dollar scale this century(20 billion USD/year,to first order).A larger,less certain commercial CDR opportunity exists for modified conventional CAES,due to additional equipment requirements.CDR may be commercially critical for LAES/CAES usage growth,and the necessary infrastructure may influence plant scaling and placement.A suggested design for low-pressure CAES theoretically offers global-scale CDR potential within a century(ignoring siting constraints)–but this must be costed against competing CDR and energy storage technologies.展开更多
文摘Nowadays, energy shortage and environmental pollution issues are increasingly severe and urgent to be solved. The effective storage and use of environmentally friendly fuels and removal of harmful gases from the environment are great challenges and of great importance both for the environment protection and for human health. Porous met- al-organic frameworks （MOFs） are highly ordered crystalline materials formed by the self-assembly process of metal ions and organic ligands. Their good features such as ultrahigh porosity, large surface area, structural diversity and functionalities make them promising candidates for applications in energy and environmental fields. MOF thin films and MOF composites have also been investigated to further enhance the properties and introduce new func- tionalities. This review provides an overview of the synthesis methods of pristine MOFs, MOF thin films and MOF composites, and significant advances of MOFs in energy and environment applications such as energy storage （H2, CH4）, CO2 capture and separation, adsorption removal and sensing of harmful gases in the environment.
文摘Liquid Air Energy Storage(LAES)is at pilot scale.Air cooling and liquefaction stores energy;reheating revaporises the air at pressure,powering a turbine or engine(Ameel et al.,2013).Liquefaction requires water&CO2 removal,preventing ice fouling.This paper proposes subsequent geological storage of this CO2–offering a novel Carbon Dioxide Removal(CDR)by-product,for the energy storage industry.It additionally assesses the scale constraint and economic opportunity offered by implementing this CDR approach.Similarly,established Compressed Air Energy Storage(CAES)uses air compression and subsequent expansion.CAES could also add CO2 scrubbing and subsequent storage,at extra cost.CAES stores fewer joules per kilogram of air than LAES–potentially scrubbing more CO2 per joule stored.Operational LAES/CAES technologies cannot offer full-scale CDR this century(Stocker et al.,2014),yet they could offer around 4%of projected CO2 disposals for LAES and<25%for current-technology CAES.LAES CDR could reach trillion-dollar scale this century(20 billion USD/year,to first order).A larger,less certain commercial CDR opportunity exists for modified conventional CAES,due to additional equipment requirements.CDR may be commercially critical for LAES/CAES usage growth,and the necessary infrastructure may influence plant scaling and placement.A suggested design for low-pressure CAES theoretically offers global-scale CDR potential within a century(ignoring siting constraints)–but this must be costed against competing CDR and energy storage technologies.
