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蒙脱石红移、蓝移及水化特征的谱学分析 被引量:10
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作者 孙红娟 彭同江 刘颖 《矿物岩石》 CAS CSCD 北大核心 2006年第3期20-25,共6页
对提纯蒙脱石、钠化蒙脱石、有机插层蒙脱石进行紫外-可见光学吸收谱分析、红外光谱分析,发现蒙脱石随着粒度的变化产生红移和蓝移现象。1631插层样品较钠化样品红移20 nm以上,而提纯的胶体粒子样品较1631插层样品SM G-1631红移80 nm;... 对提纯蒙脱石、钠化蒙脱石、有机插层蒙脱石进行紫外-可见光学吸收谱分析、红外光谱分析,发现蒙脱石随着粒度的变化产生红移和蓝移现象。1631插层样品较钠化样品红移20 nm以上,而提纯的胶体粒子样品较1631插层样品SM G-1631红移80 nm;由于提纯蒙脱石样品粒度变细羟基伸缩振动吸收峰向高波数移动了1.69 cm-1,即蓝移了1.69cm-1。蒙脱石水化性能的XRD分析表明,蒙脱石吸水后晶层发生膨胀、剥离,脱水时分散后的晶层发生凝聚作用,即面-面结合作用,形成蒙脱石“定向性层状集合体”衍射峰的d值产生了相应的变化,这种凝聚作用是蒙脱石分散剥离的逆作用,但凝聚后形成的凝聚蒙脱石的衍射谱特征与原始蒙脱石的大不相同。蒙脱石红移、蓝移及水化特征的谱学分析研究丰富了天然纳米蒙脱石矿物材料晶体化学研究的内容,具有重要的理论意义。 展开更多
关键词 蒙脱石 光吸收边红移 光吸收边蓝移 水化性能
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Non-parabolic effect for femtosecond laser-induced ultrafast electro-absorption in solids
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作者 Li-Bo Liu Hong-Xiang Deng +2 位作者 Xiao-Tao Zu Xiao-Dong Yuan Wan-Guo Zheng 《Chinese Physics B》 SCIE EI CAS CSCD 2020年第1期446-451,共6页
A theoretical study for femtosecond laser-induced ultrafast electro-absorption of bulk solids is presented.Our numerical results show that,in the case of low intensity of the pump laser where the interaction between t... A theoretical study for femtosecond laser-induced ultrafast electro-absorption of bulk solids is presented.Our numerical results show that,in the case of low intensity of the pump laser where the interaction between the pump laser and solids is in the multi-photon regime,the energy band of solids can be approximately taken as a parabolic band and electro-absorption spectrums from the parabolic band and real band are nearly the same.While,in the case of high intensity where the interaction is in the tunneling regime,spectrums from the parabolic band and real band are quite different.The physical mechanism for the difference in the tunneling regime is found.We find that the non-parabolic parts of the real energy band and Bragger scattering of electrons near the first Brillouin zone boundaries,which are neglected in previous studies,strongly influence the electro-absorption spectrum in the tunneling regime.These two physical processes cause the difference of spectrums.Our theoretical results are in accordance with the experiment result. 展开更多
关键词 ultrafast electro-absorption red-shift of absorption edge Bragger scattering effect multi-photon process
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Red-shift law of intense laser-induced electro-absorption in solids
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作者 邓洪祥 祖皓月 +2 位作者 邬邵轶 孙凯 祖小涛 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第2期499-502,共4页
A theoretical study on the red-shift of laser-induced electro-absorption is presented. It is found that laser-induced red-shift scales with the cube root of the pump laser intensity in the optical tunneling regime and... A theoretical study on the red-shift of laser-induced electro-absorption is presented. It is found that laser-induced red-shift scales with the cube root of the pump laser intensity in the optical tunneling regime and has an obvious deviation from this scale in the multi-photon regime. Our results show that in the optical tunneling regime, the laser-induced red shift has the same law as that in the direct current (DC) approximation. Though the scales are the same in the optical tunneling regime, the physical pictures in the two cases are quite different. The electro-absorption in the DC case is a tunneling-assisted transition process, while the laser-induced electro-absorption is a mixed multi-photon process. 展开更多
关键词 laser-induced electro-absorption red shift of absorption edge in solids multi-photon process pump-probe technology
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粒径对表面包覆硬脂酸的TiO_2超微粒光学性质的影响 被引量:3
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作者 鲍新努 邹炳锁 +6 位作者 张岩 肖良质 李铁津 赵家龙 虞家琪 赖祖猷 顾世洧 《发光学报》 EI CAS CSCD 北大核心 1993年第4期361-365,共5页
制备了一系列表面包覆硬脂酸的TiO_2超微粒,发现表面包覆硬脂酸的TiO_2超微粒随着超微粒粒径减小,其表观光学带隙(E_g)降低,即吸收光谱带边红移加大.
关键词 超微粒 氧化钛 光学性质 尺度效应
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