In order to use organic light emitting devices (OLEDs) in display application , it is very important to obtain red emitting light. There are two methods for obtaining red emitting light: doping high fluorescent dyes i...In order to use organic light emitting devices (OLEDs) in display application , it is very important to obtain red emitting light. There are two methods for obtaining red emitting light: doping high fluorescent dyes in host or using metal complexes. Phosphorescent dyes has been used efficiently recently. In this letter, we demonstrate red organic light emitting devices (OLED) with the electroluminescent layers consisting of aluminum tris(8 hydroxyquinoline) (Alq 3) doped with the dye DCM and DCJTB, which the emission color depends on the concentration of DCM and DCJTB. The typical cell structure is as follows: [ITO/ hole transport layer (60nm, TPD) /emitting layer(60nm, Alq 3 + red dopant) /LiF(0.5～2nm) /Al(150nm)]. For DCM doped devices, the maximum luminance of 148000cd/m 2 (chromaticity coordinates: x =0.51, y =0.47) and 5730cd/m 2 (chromaticity coordinates: x =0.58, y =0.42) are measured for DCM concentration of 0.2% and 2% in Alq 3, respectively; and for DCJTB doped devices, 17400 cd/m 2 (chromaticity coordinates : x =0.51, y =0.46) and 3846cd/m 2 (chromaticity coordinates: x =0. 63, y =0. 37) are obtained for DCJTB concentration of 0. 2 % and 2% in Alq 3, respectively.展开更多
采用高温固相法合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)单掺杂和双掺杂荧光粉,并通过X射线衍射、扫描电镜、荧光光谱等测试方法对荧光粉的物相结构、形貌和发光特性进行了表征及...采用高温固相法合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)单掺杂和双掺杂荧光粉,并通过X射线衍射、扫描电镜、荧光光谱等测试方法对荧光粉的物相结构、形貌和发光特性进行了表征及分析。结果表明:成功合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)荧光粉且均为纯相;样品的粒径为1~2μm;La_(2)MgTiO_(6)∶Mn^(4+)在650~750 nm的红光发射是来自Mn^(4+)的2 E 1→4 A 2跃迁,La_(2)MgTiO_(6)∶Pr^(3+)在红光区域600~660 nm具有强烈的发射,归属为Pr^(3+)的3 P 0→3 H 6和3 P 0→3 F 2跃迁。当Mn^(4+)与Pr^(3+)共同掺杂于La_(2)MgTiO_(6)时,来自Mn^(4+)、Pr^(3+)不同波段的红光发射使荧光粉的发射光谱与植物光敏色素P r与P fr吸收光谱的重叠程度大幅增加,表明Mn^(4+)、Pr^(3+)共掺有效拓宽了La_(2)MgTiO_(6)荧光粉的红光发射区域,更符合植物照明的需求,在LED植物照明领域具有更明显的潜在应用价值。展开更多
文摘In order to use organic light emitting devices (OLEDs) in display application , it is very important to obtain red emitting light. There are two methods for obtaining red emitting light: doping high fluorescent dyes in host or using metal complexes. Phosphorescent dyes has been used efficiently recently. In this letter, we demonstrate red organic light emitting devices (OLED) with the electroluminescent layers consisting of aluminum tris(8 hydroxyquinoline) (Alq 3) doped with the dye DCM and DCJTB, which the emission color depends on the concentration of DCM and DCJTB. The typical cell structure is as follows: [ITO/ hole transport layer (60nm, TPD) /emitting layer(60nm, Alq 3 + red dopant) /LiF(0.5～2nm) /Al(150nm)]. For DCM doped devices, the maximum luminance of 148000cd/m 2 (chromaticity coordinates: x =0.51, y =0.47) and 5730cd/m 2 (chromaticity coordinates: x =0.58, y =0.42) are measured for DCM concentration of 0.2% and 2% in Alq 3, respectively; and for DCJTB doped devices, 17400 cd/m 2 (chromaticity coordinates : x =0.51, y =0.46) and 3846cd/m 2 (chromaticity coordinates: x =0. 63, y =0. 37) are obtained for DCJTB concentration of 0. 2 % and 2% in Alq 3, respectively.
文摘采用高温固相法合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)单掺杂和双掺杂荧光粉,并通过X射线衍射、扫描电镜、荧光光谱等测试方法对荧光粉的物相结构、形貌和发光特性进行了表征及分析。结果表明:成功合成了La_(2)MgTiO_(6)∶Mn^(4+)、La_(2)MgTiO_(6)∶Pr^(3+)、La_(2)MgTiO_(6)∶Pr^(3+),Mn^(4+)荧光粉且均为纯相;样品的粒径为1~2μm;La_(2)MgTiO_(6)∶Mn^(4+)在650~750 nm的红光发射是来自Mn^(4+)的2 E 1→4 A 2跃迁,La_(2)MgTiO_(6)∶Pr^(3+)在红光区域600~660 nm具有强烈的发射,归属为Pr^(3+)的3 P 0→3 H 6和3 P 0→3 F 2跃迁。当Mn^(4+)与Pr^(3+)共同掺杂于La_(2)MgTiO_(6)时,来自Mn^(4+)、Pr^(3+)不同波段的红光发射使荧光粉的发射光谱与植物光敏色素P r与P fr吸收光谱的重叠程度大幅增加,表明Mn^(4+)、Pr^(3+)共掺有效拓宽了La_(2)MgTiO_(6)荧光粉的红光发射区域,更符合植物照明的需求,在LED植物照明领域具有更明显的潜在应用价值。
